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51.
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Madhuri Mukhopadhyay Debi Banerjee Aleksander Koll Aleksander Filarowski Samaresh Mukherjee 《Chemical physics letters》2006,420(4-6):316-320
The effect of neutral, cationic and anionic micellar environments on the ground and excited state proton transfer reactions of salicylidine-3,4,7-methyl amine (SMA) in water has been studied by steady state and time resolved fluorescence spectroscopy. In the ground state, the formation of the primary form of SMA is enhanced at the expense of the zwitterionic species due to micellization. In the excited state, anion formation decreases both in the presence of Triton-X and cetyl trimethyl ammonium bromide (CTAB). However, in the presence of sodium dodecyl sulphate (SDS), the anionic emission increases after reaching a certain micellar concentration. The lifetime of the anion is significantly reduced in CTAB compared to that in the bulk water and also in the presence of Triton-X. It is proposed that the destabilization and modification of SMA anion occurs due to the different electrostatic environments produced by micellization. 相似文献
53.
In the first part of the paper we give a construction of a topological degree theory for set-valued tangent vector fields with convex and nonconvex values defined on nonsmooth closed subsets of a Banach space. The obtained homotopy invariant is an extension of the classical degree for vector fields on manifolds. In the second part we propose a fixed-point index for inward maps on arbitrary closed convex sets. 相似文献
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Aleksander Jablonski 《Surface science》1985,151(1):166-182
A Monte Carlo algorithm is proposed for calculating the elastic reflection coefficient, ηE, for elements. The algorithm accounts for the multiple elastic scattering of electrons in solids. The calculated values of ηE compare well with the literature data for elements with atomic number up to 47 and at primary energies above 2 keV. The proposed Monte Carlo method makes it possible to determine the functional relation between ηE and the inelastic mean free path, λ. This relation turned out to be non-linear, arid it deviates from a similar relation based on published earlier single elastic scattering model. The deviation is especially pronounced for elements with medium atomic numbers. The calculated function offers a convenient method for determining the inelastic mean free path. The values of λ derived in the present work from published experimental values of ηE compare very well with the literature data. 相似文献
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Aleksander Glikson 《Archive for Rational Mechanics and Analysis》1972,45(1):35-46
We consider a Boltzmann gas which fills all of space and is under the influence of a field of conservative external force whose potential is bounded from below.Assuming the intermolecular force has a cut-off, we prove existence and uniqueness for the general solution of the nonlinear Maxwell-Boltzmann equation at least in a finite interval of time. The solution can be constructed by the method of successive approximations in corresponding complete spaces. Definitions of these spaces are connected with an exponential function of the total energy of the molecule.Some indications of future generalizations and investigations are given. 相似文献
59.
Aleksander GRYTCZUK Jarostaw GRYTCZUK 《数学学报(英文版)》2005,21(5):1107-1112
We investigate arithmetic properties of certain subsets of square-free positive integers and obtain in this way some results concerning the class number h(d) of the real quadratic field Q(√d). In particular, we give a new proof of the result of Hasse, asserting that in this case h(d) = 1 is possible only if d is of the form p, 2q or qr. where p.q. r are primes and q≡r≡3(mod 4). 相似文献
60.
The acid-catalysed (HCl or SnCl4) reaction of alkyl 2,3 dideoxy-glyc-2-enopyranosides or 3,4,6-tri-O-acetyl-D-glycals with thiols leads to mixtures of alkyl 2,3-dideoxy-1-thio-glyc-2-enopyranosides and 3-S-alkyl-3-thioglycals. Under equilibrium conditions the latter are the preponderant products of the reaction. Cross experiments have confirmed the intermediacy of the allylic carbocation in the reaction. A rationalization of the substitution reactions of 1,2- and 2,3-unsaturated sugars based on HSAB principle has been proposed. 相似文献