全文获取类型
收费全文 | 374篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
化学 | 204篇 |
晶体学 | 3篇 |
力学 | 15篇 |
数学 | 125篇 |
物理学 | 43篇 |
出版年
2023年 | 3篇 |
2022年 | 15篇 |
2021年 | 9篇 |
2020年 | 9篇 |
2019年 | 12篇 |
2018年 | 11篇 |
2017年 | 9篇 |
2016年 | 23篇 |
2015年 | 7篇 |
2014年 | 23篇 |
2013年 | 25篇 |
2012年 | 37篇 |
2011年 | 27篇 |
2010年 | 21篇 |
2009年 | 22篇 |
2008年 | 16篇 |
2007年 | 17篇 |
2006年 | 13篇 |
2005年 | 23篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有390条查询结果,搜索用时 0 毫秒
11.
Evgenija A. Djurendić Olivera R. Klisurić Mihály Szécsi Marija N. Sakač Suzana S. Jovanović-Šanta Imre Ignáth Vesna V. Kojić Aleksandar M. Oklješa Marina P. Savić Katarina M. Penov-Gaši 《Structural chemistry》2014,25(6):1747-1758
Tetrakis-, tris-, bis-, and mono salicylic acid derivatives 1–4 were synthesized by reaction of methyl 2-hydroxy benzoate (methyl salicylate) with 2,2-bis (hydroxymethyl) propane-1,3-diol (pentaerythritol) in the presence of sodium. Yields of different salicyloyloxy derivatives were changed by varying the molar ratios of reactants. For compounds 2 and 3, X-ray structure analysis was performed, as well as molecular energy minimization, to define their conformation in terms of their energy minima. Comparison of crystal and energy minimized structures for these two compounds (2 and 3) revealed that the intramolecular hydrogen bonds play an important role, stabilizing conformation of the most part of the molecule. The antioxidant activity and cytotoxicity of the synthesized derivatives were evaluated in a series of in vitro tests, as well as 17β-hydroxysteroid dehydrogenase type 2 inhibition potency. Tetrakis salicyloyloxy derivative 1 expressed the highest antioxidant potency, tris salicyloyloxy derivative 2 was the best inhibitor of 17βHSD2 enzyme, while bis salicyloyloxy derivative 3 showed strong cytotoxicity against prostate and breast cancer cells with no cytotoxicity against healthy cells. 相似文献
12.
Todorović Danijel Tomić Mladen Bojanić Ranko Bajatović Dušan Anđelković Aleksandar S. 《Journal of Thermal Analysis and Calorimetry》2020,141(1):559-572
Journal of Thermal Analysis and Calorimetry - System for domestic hot water (DHW) preparation generally represents a considerable portion of the energy and water consumption in hotels worldwide. As... 相似文献
13.
Miloš Dubajić Aleksandar Daničić Nikola Vuković Vitomir Milanović Jelena Radovanović 《Optical and Quantum Electronics》2018,50(10):373
In this work we theoretically investigate a possibility to use cubic nitride based multi-layer periodic nanostructure as a semiconductor metamaterial. The structure design is based on an active region of a quantum cascade laser optimized to achieve optical gain in the Terahertz (THz) spectral range. In particular, we test the GaN/AlGaN quantum well configurations, which should exhibit important advantages compared to GaAs-based structures, namely room temperature operation without the assistance of magnetic field and lower doping densities. Our numerical rate-equations model is solved self-consistently and it takes into account electron-longitudinal optical phonon scattering between all the relevant states among the adjacent periods of the structure. A global optimization routine, specifically genetic algorithm is then used to generate new gain-optimized structures. This work confirms the advantages of cubic GaN designs over GaAs ones, namely feasibility of negative refraction at room temperature without the assistance of magnetic field while keeping the doping densities of the same order of magnitude. 相似文献
14.
15.
Let be a graph with diameter d 2. Recall is 1-homogeneous (in the sense of Nomura) whenever for every edge xy of the distance partition{{z V() | (z, y) = i, (x, z) = j} | 0 i, j d}is equitable and its parameters do not depend on the edge xy. Let be 1-homogeneous. Then is distance-regular and also locally strongly regular with parameters (v,k,,), where v = k, k = a
1, (v – k – 1) = k(k – 1 – ) and c
2 + 1, since a -graph is a regular graph with valency . If c
2 = + 1 and c
2 1, then is a Terwilliger graph, i.e., all the -graphs of are complete. In [11] we classified the Terwilliger 1-homogeneous graphs with c
2 2 and obtained that there are only three such examples. In this article we consider the case c
2 = + 2 3, i.e., the case when the -graphs of are the Cocktail Party graphs, and obtain that either = 0, = 2 or is one of the following graphs: (i) a Johnson graph J(2m, m) with m 2, (ii) a folded Johnson graph J¯(4m, 2m) with m 3, (iii) a halved m-cube with m 4, (iv) a folded halved (2m)-cube with m 5, (v) a Cocktail Party graph K
m × 2 with m 3, (vi) the Schläfli graph, (vii) the Gosset graph. 相似文献
16.
Dušan Lj. Djukić Aleksandar V. Pejčev Miodrag M. Spalević 《Numerical Algorithms》2018,77(4):1003-1028
We consider the Gauss-Kronrod quadrature formulae for the Bernstein-Szeg? weight functions consisting of any one of the four Chebyshev weights divided by the polynomial \(\rho (t)=1-\frac {4\gamma }{(1+\gamma )^{2}}\,t^{2},\quad t\in (-1,1),\ -1<\gamma \le 0\). For analytic functions, the remainder term of this quadrature formula can be represented as a contour integral with a complex kernel. We study the kernel, on elliptic contours with foci at the points ? 1 and sum of semi-axes ρ > 1, for the given quadrature formula. Starting from the explicit expression of the kernel, we determine the locations on the ellipses where maximum modulus of the kernel is attained. So we derive effective error bounds for this quadrature formula. An alternative approach, which has initiated this research, has been proposed by S. Notaris (Numer. Math. 103, 99–127, 2006). 相似文献
17.
18.
19.
Kristina Butkovi? Kristijan Lovrekovi? Aleksandar Višnjevac Marija Šindler-Kulyk 《Tetrahedron letters》2004,45(49):9057-9060
New cis- and trans-3-aryl-4-[2-(2-vinylphenyl)ethenyl]sydnones 2, aryl = phenyl, p-tolyl were prepared and transformed on irradiation in the presence of acrolein to a pyrazoline derivative that aromatized during isolation to trans-1-tolyl-3-[2-(2-vinylphenyl)ethenyl]pyrazole 7 and trans-5-formyl-1-tolyl-3-[2-(2-vinylphenyl)ethenyl]pyrazole 8. 相似文献
20.
Skorić I Basarić N Marinić Z Visnjevac A Kojić-Prodić B Sindler-Kulyk M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(2):543-551
New heteroaryl-substituted o-divinylbenzenes, 2,2'-(1,2-phenylenedivinylene)difuran (9), 2,2'-(1,2-phenylenedivinylene)bisbenzo[b]furan (10), and 2,2'-(1,2-phenylenedivinylene)bisnaphtho[2,1-b]furan (11), were prepared and irradiated at various concentrations; intramolecular photocycloaddition and intermolecular [2+2] twofold photoaddition reactions took place to give bicyclo[3.2.1]octadiene derivatives 12-14 and cyclophane derivatives 15-17, respectively. Compound 11 was the most selective of these o-divinylbenzenes, which, owing to pi-pi intra- or intermolecular complexation, gave only the exo-bicyclo[3.2.1]octadiene derivative 14 at low concentrations, and only the cyclophane derivative 17 at high concentrations. 相似文献