The new orotate complex of cadmium(II) with quinoxaline, mer‐[Cd(HOr)(H2O)3(QX)]·2H2O, was synthesized and characterized by elemental analysis, FT–IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the triclinic system, space group . The Cd2+ ion exhibits a distorted octahedral coordination by one bidentate orotate, one monodentate quinoxaline and three aqua ligands. The uncoordinated water molecules link the orotate, quinoxaline and aqua ligands via O–H···O, O–H···N hydrogen bonds. Thus, an extensive network of hydrogen bonds stabilizes the crystal structure and form an infinitive three dimensional lattice. The decomposition reaction takes place in the temperature range 20–700 °C in the static air atmosphere. 相似文献
The problem of the brachistochronic motion of a holonomic scleronomic mechanical system is analyzed. The system moves in an arbitrary field of known potential forces. The problem is formulated as an optimal control task, where generalized speeds are taken as control variables. The problem considered is reduced to solving the corresponding two-point boundary-value problem (TPBVP). In order to determine the global minimal solution of the TPBVP, an appropriate numerical procedure based on the shooting method is presented. The global minimal solution represents the solution with the minimum time of motion. The procedure is illustrated by an example of determining the brachistochronic motion of a disk that performs plane motion in a vertical plane in a homogeneous field of gravity. 相似文献
The amplitudes of terahertz pulses emitted from the surfaces of InAs, InSb, InGaAs, GaAs and Ge after their excitation by femtosecond 1 μm laser pulses was compared. It has been found that this effect is most efficient in p-type InAs. The mechanisms leading to the terahertz emission are investigated and discussed. It has been concluded that in the majority of the investigated semiconductors the main contribution to THz pulse emission comes from the electrical-field-induced optical rectification effect. 相似文献
I discuss E. J. Lowe’s conception of criteria of identity and sketch a different and, I think, more adequate conception. On my view, criteria of identity are some of the things we can do. They are what we do when distinguishing between single entities of the kind in question and pairs of entities of the relevant domain. And they enable us to make such distinctions because they are applicable to all single and to all pairs of entities of the relevant domain but fulfilled only by all single entities of the kind in question. This feature of criteria of identity allows us to define these criteria, to explain how to identify a particular criterion of identity and to determine the logical form in which to express such identifications. 相似文献
The paper considers brachistochronic motion of a particle along a curve y=y(x) in an arbitrary force field in the vertical plane of Cartesian coordinate system. The curve is treated as a bilateral or unilateral constraint that can be smooth or rough. The projection of the reaction force of the curve onto the normal to the curve is confined to the fixed limits. A control variable u is given as the second derivative of the function y(x) relative to the horizontal coordinate?x of the particle, i.e., u=d2y/dx2. Applying Pontryagin??s maximum principle and singular optimal control theory, the problem is reduced to numerical solving of the corresponding two-point boundary value problem. The procedure based on the shooting method is used to solve the boundary value problem. Two examples with friction forces of the viscous friction and Coulomb friction type have been solved. 相似文献
We provide the initial performance evaluation of a 21 Tesla Fourier transform ion cyclotron resonance mass spectrometer operating at the Environmental Molecular Sciences Laboratory at the Pacific Northwest National Laboratory. The spectrometer constructed for the 21T system employs a commercial dual linear ion trap mass spectrometer coupled to a FTICR spectrometer designed and built in-house. Performance gains from moving to higher magnetic field strength are exemplified by the measurement of peptide isotopic fine structure, complex natural organic matter mixtures, and large proteins. Accurate determination of isotopic fine structure was demonstrated for doubly charged Substance P with minimal spectral averaging, and 8158 molecular formulas assigned to Suwannee River Fulvic Acid standard with root-mean-square (RMS) error of 10 ppb. We also demonstrated superior performance for intact proteins; namely, broadband isotopic resolution of the entire charge state distribution of apo-transferrin (78 kDa) and facile isotopic resolution of monoclonal antibody under a variety of acquisition parameters (e.g., 6 s time-domains with absorption mode processing yielded resolution of approximately 1 M at m/z?=?2700).
The ability to visualize biochemical interactions between microbial communities using MALDI MSI has provided tremendous insights into a variety of biological fields. Matrix application using a sieve proved to be incredibly useful, but it has many limitations that include uneven matrix coverage and limitation in the types of matrices that could be employed in studies. Recently, there has been a concerted effort to improve matrix application for studying agar plated microbial cultures, many of which utilized automated matrix sprayers. Here, we describe the usefulness of using a robotic sprayer for matrix application. The robotic sprayer has two-dimensional control over where matrix is applied, and a heated capillary that allows for rapid drying of the applied matrix. This method provided a significant increase in MALDI sensitivity over the sieve method, as demonstrated by FT-ICR MS analysis, facilitating the ability to gain higher lateral resolution MS images of Bacillus subtilis than previously reported. This method also allowed for the use of different matrices to be applied to the culture surfaces.
