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41.
Analytical and Bioanalytical Chemistry - 相似文献
42.
J. A. Muller C. Reinhardt C. Fischbach A. Siebenschub V. Stanek N. M. Randall K. Bogoluboff H. Wdowiszewski F. Garrat D. J. Demorest J. R. Cain H. E. Walters F. C. T. Daniels A. J. Field A. Terni P. Malaguti B. S. Evans L. W. Winkler O. L. Barnebey G. L. Kelley J. A. Wiley E. Little J. Costa M. Gröger H. O. Ward P. Slawik W. Hild und F. Simion 《Fresenius' Journal of Analytical Chemistry》1923,63(9):348-359
Ohne Zusammenfassung 相似文献
43.
Reinhardt J. Heuer Robert Thayer Sataloff Kate Emerich Rhonda Rulnick Margaret Baroody Joseph R. Spiegel Gursel Durson John Butler 《Journal of voice》1997,11(1):88-94
This preliminary retrospective study of 19 female patients and 22male patients with unilateral recurrent nerve lesions demonstrated the promise of objective measurements in predicting the need for surgery, the efficacy of voice therapy in ameliorating vocal symptoms, and the effects of therapy in conjunction with surgery. Sixty-eight percent (68%) of the female patients and 64% of the male patients did not elect to have surgery. Outcome satisfaction of nonsurgical and surgical patients appeared to be similar. The data from this study support the importance of preoperative therapy for patients with unilateral vocal fold paralysis. 相似文献
44.
45.
Zou Y Wang D Wurst K Kühnel C Reinhardt I Decker U Gurram V Camadanli S Buchmeiser MR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(49):13832-13846
Two novel Zr(IV)- and Hf(IV)-based bisamido complexes bearing the 6-[2-(diethylboryl)phenyl]pyrid-2-yl motif, that is, [ZrCl(2){Me(2)Si(DbppN)(2)}(thf)] (9) and [HfCl(2){Me(2)Si(DbppN)(2)}(thf)(2)] (10) (DbppN=6-[2-(diethylboryl)phenyl]pyridine-2-amido) have been prepared. Their reactivities have been compared with that of a model precatalyst that does not bear the aminoborane motif. Upon activation with methylalumoxane, precatalysts 9 and 10 are active in the homopolymerization of ethylene (E) yielding high-density polyethylene (HDPE). In the copolymerization of E with cyclopentene (CPE), for example by the action of 9, the presence of CPE resulted in a dramatic increase in the polymerization activity of E, while CPE incorporation remained close to or at zero. In the vinyl-insertion copolymerization of norborn-2-ene (NBE) with E by the action of 9, statistical cyclic olefin copolymers of these two monomers were obtained. At higher NBE concentrations, however, 9 gave rise to reversible ring-opening metathesis (ROMP)/vinyl-insertion polymerization (VIP) of NBE with E, resulting in the formation of multi-block copolymers of the general formula poly(NBE)(ROMP)-co-poly(NBE)(VIP)-co-poly(E). This particular feature of precatalyst 9, that is, the ability to induce a reversible α-H elimination/α-H addition reaction, is attributed to the unique role of the 6-[2-(diethylboryl)phenyl]pyrid-2-yl ligand. Accordingly, a model precatalyst lacking this ligand does not have the ability to induce α-H elimination/α-H addition reactions. The different (11)B NMR shifts of various diethylborylphenylpyrid-2-ylamines and -amides permit a ranking of the strengths of the B-N bonds in these compounds. This strength of the B-N bond is correlated with the propensity of 9/MAO to produce poly(NBE)(ROMP)-co-poly(NBE)(VIP)-co-poly(E) at different temperatures. 相似文献
46.
Reinhardt A Williamson AJ Doye JP Carrete J Varela LM Louis AA 《The Journal of chemical physics》2011,134(10):104905
In patchy particle systems where there is a competition between the self-assembly of finite clusters and liquid-vapor phase separation, re-entrant phase behavior can be observed, with the system passing from a monomeric vapor phase to a region of liquid-vapor phase coexistence and then to a vapor phase of clusters as the temperature is decreased at constant density. Here, we present a classical statistical mechanical approach to the determination of the complete phase diagram of such a system. We model the system as a van der Waals fluid, but one where the monomers can assemble into monodisperse clusters that have no attractive interactions with any of the other species. The resulting phase diagrams show a clear region of re-entrance. However, for the most physically reasonable parameter values of the model, this behavior is restricted to a certain range of density, with phase separation still persisting at high densities. 相似文献
47.
Joško Ožbolt Akanshu Sharma Hans-Wolf Reinhardt 《International Journal of Solids and Structures》2011,48(10):1534-1543
The behavior of concrete structures is strongly influenced by the loading rate. Compared to quasi-static loading concrete loaded by impact loading acts in a different way. First, there is a strain-rate influence on strength, stiffness, and ductility, and, second, there are inertia forces activated. Both influences are clearly demonstrated in experiments. Moreover, for concrete structures, which exhibit damage and fracture phenomena, the failure mode and cracking pattern depend on loading rate. In general, there is a tendency that with the increase of loading rate the failure mode changes from mode-I to mixed mode. Furthermore, theoretical and experimental investigations indicate that after the crack reaches critical speed of propagation there is crack branching. The present paper focuses on 3D finite-element study of the crack propagation of the concrete compact tension specimen. The rate sensitive microplane model is used as a constitutive law for concrete. The strain-rate influence is captured by the activation energy theory. Inertia forces are implicitly accounted for through dynamic finite element analysis. The results of the study show that the fracture of the specimen strongly depends on the loading rate. For relatively low loading rates there is a single crack due to the mode-I fracture. However, with the increase of loading rate crack branching is observed. Up to certain threshold (critical) loading rate the maximal crack velocity increases with increase of loading rate, however, for higher loading rates maximal velocity of the crack propagation becomes independent of the loading rate. The critical crack velocity at the onset of crack branching is found to be approximately 500 m/s. 相似文献
48.
Influence of the carrier gas on HfCl4-H2O and ZrCl4-H2O atomic layer processes was investigated. The growth rates of HfO2 and ZrO2 decreased with increasing flow rate and pressure of the N2 carrier gas. Data of real-time quartz crystal microbalance measurements demonstrated that the effect observed was mainly due to influence of carrier gas on surface reactions and the role of overlapping the precursor pulses was negligible. At the same increase of the carrier gas mass flow, the increase of the linear flow rate led to more significant changes of thin-film properties than the increase of the carrier gas pressure did. Thin films with higher density, higher refractive index and, particularly, lower concentration of residual chlorine were obtained at higher carrier gas flow rates. Increase of the carrier gas flow rate also resulted in a higher concentration of a metastable phase in HfO2 thin films deposited at 300 °C. 相似文献
49.
W. Hempel C. Paal W. Hartmann G. A. Burrell G. G. Oberfell O. Brunck Mathers J. E. Lee J. W. Robertson F. M. Seibert P. Lebeau A. Damiens O. Brunck L. A. Levy F. St. Sinnatt B. J. Cramer E. H. Weiskopf J. I. Graham Th. F. Winmill F. Haber F. Löwe O. Mohr R. L. von Klemperer O. Wolft E. Müller E. Reinhardt J. N. Pring Juan Calafat y Leon M. Guichard R. Nowicki John J. Griffin A. Sons L. Hamburger H. Filippo Izn Ch. Moureau G. Lunge und A. Rittener 《Fresenius' Journal of Analytical Chemistry》1915,54(10):504-509
Ohne Zusammenfassung 相似文献
50.
The kinetics of the oxygen exchange reaction and the reduction of NO at La0.8Sr0.2CoO3−, La0.8Sr0.2MnO3− and Ag-electrodes on stabilized zirconia (8mol% Y203=YSZ) has been studied by means of electrochemical methods (impedance, I-U characteristics). For La0.8Sr0.2CoO3 electrodes the oxygen exchange was found to proceed via the bulk of the electrode with a rate limiting oxygen exchange at
the electrode surface. Electrodes based on La0.8Sr0.2MnO3 change their electrode characteristics with the applied potential. At low cathodic polarization the electrode reaction is
limited to the three-phase boundary electrode/YSZ/gas. At high cathodic potentials oxygen vacancies are created and consequently
additional oxygen is exchanged via the electrode bulk. Furthermore, a significant NO reduction was observed which indicate
a reaction with the oxygen vacancies at the electrode surface. For Ag a rate limiting transport of oxygen atoms through the
bulk of the electrode was found. As a consequence the oxygen concentration at the electrode surface remains nearly constant.
In this context, the observed inactivity for the NO reduction of Ag-electrodes may be explained.
Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995 相似文献