Dielectric relaxation spectroscopy in the frequency range from 10−2 Hz to 106 Hz and electron spin resonance (ESR) experiments are employed to study the dynamics in chemically and physically crosslinked networks. As examples for physically crosslinked networks ortho- and para-cresol novolacs were investigated. Dielectrically these materials show low-temperature β- and high-temperature α-relaxation. Both relaxation regions differ for both types of novolacs. This is also reflected by the ESR measurements and is discussed in terms of different hydrogen bonds found to be stronger in para-cresol novolac. For the chemically crosslinked poly(triallyl isocyanurate) only a β-peak is found by the dielectric measurements. Also in the ESR experiment the slow motion regime is characterized up to high temperatures. This means that the segmental motion is strongly suppressed by chemical crosslinking. Nevertheless the obtained change in the formal T50G value can be used to characterize the glass transition in highly crosslinked systems by the ESR method. 相似文献
The polarographic behaviour of hydrolyzed propene-maleic anhydride copolymers in the interval pH 2.0–11.0 has been investigated by differential pulse polarography in aqueous lithium chloride solution at 25°C. In dependence on the pH-value, one, two or three signals, belonging to the acid groups in the copolymer, appear in the polarograms. Three apparent polarographic acid constants have been determined graphically from the changes in the half-wave potential of the separate peaks in correlation with pH. 相似文献
In rock grouting, idealized 2D-radial laminar flow of yield stress fluids (YSF) is a fundamental flow configuration that is used for cement grout spread estimation. A limited amount of works have presented analytical and numerical solutions on the radial velocity profiles between parallel disks. However, to the best of our knowledge, there has been no experimental work that has presented measured velocity profiles for this geometry. In this paper, we present velocity profiles of Carbopol (a simple YSF), measured by pulsed ultrasound velocimetry within a radial flow model. We describe the design of the physical model and then present the measured velocity profiles while highlighting the plug-flow region and slip effects observed for three different apertures and volumetric flow rates. Although the measured velocity profiles exhibited wall slip, there was a reasonably good agreement with the analytical solution. We then discuss the major implications of our work on radial flow.
. Investigations of the efficient generation of powerful coherent radiation at 82.8 nm by frequency tripling of short-pulse
KrF laser radiation are presented. Argon gas is selected as nonlinear medium due to the resonantly enhanced 3rd-order susceptibility
χ(3)(-3ω,ω,ω,ω). Pulse energies of 100 μJ at 82.8 nm have been measured for a pump pulse energy of 14 mJ. An upscaling to more
than 500 μJ is expected with available more powerful pump lasers. Features of this XUV source and possible applications are
discussed.
Received: 26 July 2002 / Published online: 15 November 2002
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ID="*"Corresponding author. Fax: +49-511/7622211, E-mail: reinhardt@iqo.uni-hannover.de 相似文献
Superior laryngeal nerve paresis and paralysis are relatively common but often difficult to diagnose with certainty. They are most commonly caused by viral infections, though other etiologies must be considered. A thorough history and physical examination, including strobovideolaryngoscopy and laryngeal electromyography, are needed for definitive diagnosis. It is essential to establish the diagnosis accurately to differentiate an apparent superior laryngeal nerve paresis from other conditions, such as myasthenia gravis. Laryngeal electromyography is used to confirm clinical impressions, as a guide for therapy, and as one measure of recovery. In our experience, accurate and early diagnosis assure the best phonatory outcome by directing therapy that will prevent or eliminate compensatory vocal abuses, which may themselves lead to even more serious vocal injury. 相似文献
To elucidate the spirit of the recently developed time-dependent mean-field S-matrix theory we apply it to low-energy elastic collisions and solve the corresponding temporally non-local mean-field equation under the assumption that the relative motion proceeds adiabatically. Neglecting the exchange processes this assumption leads to a pure potential scattering picture. The phase shift extracted from the corresponding mean-field S-matrix coincides with the WKB result of potential scattering. 相似文献
For singularly perturbed one-dimensional convection-diffusion equations, finite element approximations are constructed based on a so-called approximate symmetrization of the given unsymmetric problem. Local a-posteriori error estimates are established with respect to an appropriate energy norm where the bounds are proved to be realistic. The local bounds, called error indicators, provide a basis for a self-adaptive mesh refinement. For a model problem numerical results are presented showing that the adaptive method detects and resolves the boundary layer. 相似文献
By using the method of center projection, the center vortex part of the gauge field is isolated and its propagator is evaluated in the center Landau gauge, which minimizes the open 3-dimensional Dirac volumes of nontrivial center links bounded by the closed 2-dimensional center vortex surfaces. The center field propagator is found to dominate the gluon propagator (in the Landau gauge) in the low momentum regime and to give rise to a power-law correction proportional to p(-2.9(1)) at high momentum. The screening mass of the center vortex field vanishes above the critical temperature of the deconfinement phase transition, which naturally explains the second order nature of this transition consistent with the vortex picture. Finally, the ghost propagator of the maximal center gauge is found to be infrared finite and, thus, shows that the coset fields play no role for confinement. 相似文献