Electrostatic charging of micro- and nano-particles for use with highly energetic applications

Electrostatically charging spherical and cylindrical conducting particles against an electrode with an applied electric field is investigated both theoretically and experimentally as a method of charging micro- and nano-particles for use with a variety of high energy and high velocity applications, which include nano-particle electrostatic space propulsion systems, materials processing, and nano-printing. Increasing the particles' charge-to-mass ratios is critical for maximizing their velocities when accelerated with applied electric fields, which requires minimizing the particles' sizes down to the micro- and nano-meter ranges for some applications. An analysis reveals that the charge-to-mass ratio is maximized with low aspect ratio particles when the maximum electric field strength, which is at the top of the particles, is held constant. Experimental results of charging titanium and aluminum spherical and cylindrical particles are presented, which suggest that under appropriate conditions, the particles are charged as predicted by theory. But that electrical contact resistance between the particles and electrode can influence the charging time. An analysis of the expected particle charging times is presented, which shows a strong dependence on the conductivity and thickness of the oxide layer coating the particles.     

Design and performance of an ultra‐high‐vacuum‐compatible artificial channel‐cut monochromator

The design and performance of a novel ultra‐high‐vacuum‐compatible artificial channel‐cut monochromator that has been commissioned at undulator beamline 8‐ID‐I at the Advanced Photon Source are presented. Details of the mechanical and optical design, control system implementation and performance of the new device are given. The monochromator was designed to meet the challenging stability and optical requirements of the X‐ray photon correlation spectroscopy program hosted at this beamline. In particular, the device incorporates a novel in‐vacuum sine‐bar drive mechanism for the combined pitch motion of the two crystals and a flexure‐based high‐stiffness weak‐link mechanism for fine‐tuning the pitch and roll of the second crystal relative to the first crystal. The monochromator delivers an exceptionally uniform and stable beam and thereby improved brilliance preservation.     

Unusually strong space-charge-limited current in thin wires

The current-voltage characteristics of thin wires are often observed to be nonlinear, and this behavior has been ascribed to Schottky barriers at the contacts. We present electronic transport measurements on GaN nanorods and demonstrate that the nonlinear behavior originates instead from space-charge-limited current. A theory of space-charge-limited current in thin wires corroborates the experiments and shows that poor screening in high-aspect ratio materials leads to a dramatic enhancement of space-charge limited current, resulting in new scaling in terms of the aspect ratio.     

Ballistic electron emission microscopy studies of Au/molecule/n-GaAs diodes

We present nanometer-scale resolution, ballistic electron emission microscopy (BEEM) studies of Au/octanedithiol/n-GaAs (001) diodes. The presence of the molecule dramatically increases the BEEM threshold voltage and displays an unusual transport signature as compared to reference Au/GaAs diodes. Furthermore, BEEM images indicate laterally inhomogeneous interfacial structure. We present calculations that address the role of the molecular layer at the interface. Our results indicate that spatially resolved measurements add new insight to studies using conventional spatial-averaging techniques.     

The backward shift on the space of Cauchy transforms

This note examines the subspaces of the space of Cauchy transforms of measures on the unit circle that are invariant under the backward shift operator . We examine this question when the space of Cauchy transforms is endowed with both the norm and weak topologies.

     

Evidence for entangled states of two coupled flux qubits

We have studied the low-frequency magnetic susceptibility of two inductively coupled flux qubits using the impedance measurement technique (IMT), through their influence on the resonant properties of a weakly coupled high-quality tank circuit. In a single qubit, an IMT dip in the tank's current-voltage phase angle at the level anticrossing yields the amplitude of coherent flux tunneling. For two qubits, the difference (IMT deficit) between the sum of single-qubit dips and the dip amplitude when both qubits are at degeneracy shows that the system is in a mixture of entangled states (a necessary condition for entanglement). The dependence on temperature and relative bias between the qubits allows one to determine all the parameters of the effective Hamiltonian and equilibrium density matrix, and confirms the formation of entangled eigenstates.     

Communication: Bubbles, crystals, and laser-induced nucleation

Short intense laser pulses of visible and infrared light can dramatically accelerate crystal nucleation from transparent solutions; previous studies invoke mechanisms that are only applicable for nucleation of ordered phases or high dielectric phases. However, we show that similar laser pulses induce CO(2) bubble nucleation in carbonated water. Additionally, in water that is cosupersaturated with argon and glycine, argon bubbles escaping from the water can induce crystal nucleation without a laser. Our findings suggest a possible link between laser-induced nucleation of bubbles and crystals.     

Many Overlapping Peptides for Protein Hydrogen Exchange Experiments by the Fragment Separation-Mass Spectrometry Method

Measurement of the naturally occurring hydrogen exchange (HX) behavior of proteins can in principle provide highly resolved thermodynamic and kinetic information on protein structure, dynamics, and interactions. The HX fragment separation-mass spectrometry method (HX-MS) is able to measure hydrogen exchange in biologically important protein systems that are not accessible to NMR methods. In order to achieve high structural resolution in HX-MS experiments, it will be necessary to obtain many sequentially overlapping peptide fragments and be able to identify and analyze them efficiently and accurately by mass spectrometry. This paper describes operations which, when applied to four different proteins ranging in size from 140 to 908 residues, routinely provides hundreds of useful unique peptides, covering the entire protein length many times over. Coverage in terms of the average number of peptide fragments that span each amino acid exceeds 10. The ability to achieve these results required the integrated application of experimental methods that are described here and a computer analysis program, called ExMS, described in a following paper.     

Electron kinetic energies from vibrationally promoted surface exoemission: evidence for a vibrational autodetachment mechanism

We report kinetic energy distributions of exoelectrons produced by collisions of highly vibrationally excited NO molecules with a low work function Cs dosed Au(111) surface. These measurements show that energy dissipation pathways involving nonadiabatic conversion of vibrational energy to electronic energy can result in electronic excitation of more than 3 eV, consistent with the available vibrational energy. We measured the dependence of the electron energy distributions on the translational and vibrational energy of the incident NO and find a clear positive correlation between final electron kinetic energy and initial vibrational excitation and a weak but observable inverse dependence of electron kinetic energy on initial translational energy. These observations are consistent with a vibrational autodetachment mechanism, where an electron is transferred to NO near its outer vibrational turning point and ejected near its inner vibrational turning point. Within the context of this model, we estimate the NO-to-surface distance for electron transfer.