Plasma-assisted oxidation of Cu(100) and Cu(111)

Oxidized copper surfaces have attracted significant attention in recent years due to their unique catalytic properties, including their enhanced hydrocarbon selectivity during the electrochemical reduction of CO₂. Although oxygen plasma has been used to create highly active copper oxide electrodes for CO₂RR, how such treatment alters the copper surface is still poorly understood. Here, we study the oxidation of Cu(100) and Cu(111) surfaces by sequential exposure to a low-pressure oxygen plasma at room temperature. We used scanning tunnelling microscopy (STM), low energy electron microscopy (LEEM), X-ray photoelectron spectroscopy (XPS), near edge X-ray absorption fine structure spectroscopy (NEXAFS) and low energy electron diffraction (LEED) for the comprehensive characterization of the resulting oxide films. O₂-plasma exposure initially induces the growth of 3-dimensional oxide islands surrounded by an O-covered Cu surface. With ongoing plasma exposure, the islands coalesce and form a closed oxide film. Utilizing spectroscopy, we traced the evolution of metallic Cu, Cu₂O and CuO species upon oxygen plasma exposure and found a dependence of the surface structure and chemical state on the substrate''s orientation. On Cu(100) the oxide islands grow with a lower rate than on the (111) surface. Furthermore, while on Cu(100) only Cu₂O is formed during the initial growth phase, both Cu₂O and CuO species are simultaneously generated on Cu(111). Finally, prolonged oxygen plasma exposure results in a sandwiched film structure with CuO at the surface and Cu₂O at the interface to the metallic support. A stable CuO(111) surface orientation is identified in both cases, aligned to the Cu(111) support, but with two coexisting rotational domains on Cu(100). These findings illustrate the possibility of tailoring the oxidation state, structure and morphology of metallic surfaces for a wide range of applications through oxygen plasma treatments.

A low-pressure oxygen plasma oxidized Cu(100) and Cu(111) surfaces at room temperature. The time-dependent evolution of surface structure and chemical composition is reported in detail for a range of exposure times up to 30 min.     

Thermal stability of glycerol containing compounds from the biodiesel production chain

Journal of Thermal Analysis and Calorimetry - Glycerol is a by-product from transesterification for biodiesel production. Due to the presence of hydroxyl groups (–OH), glycerol is pointed as...     

Inverse semigroup actions as groupoid actions

To an inverse semigroup, we associate an étale groupoid such that its actions on topological spaces are equivalent to actions of the inverse semigroup. Both the object and the arrow space of this groupoid are non-Hausdorff. We show that this construction provides an adjoint functor to the functor that maps a groupoid to its inverse semigroup of bisections, where we turn étale groupoids into a category using algebraic morphisms. We also discuss how to recover a groupoid from this inverse semigroup.     

Fibers of the Baum-Bott map for foliations of degree two on ?2

The Baum-Bott map associates to a foliation the Baum-Bott indexes of their singularities. In this paper we study the fibers of the Baum-Bott map in the space of foliations of degree two on the projective plane ℙ². In the main result we prove that its generic fiber contains exactly 240 orbits of the natural action of Aut(ℙ²) onthespace of foliations.     

Bioactivities of the Genus <em>Combretum</em> (Combretaceae): A Review

The Combretaceae is a large family of herbs, shrubs and trees, comprising about 20 genera and 600 species with tropical distribution around the globe and centers of diversity in Africa and Asia. Some Combretum species are extensively used in traditional medicine against inflammation, infections, diabetes, malaria, bleeding, diarrhea and digestive disorders and others as a diuretic. The present work is a literature survey of Combretum species that have been evaluated for their ability to exert biological activities. A total number of 36 Combretum species are discussed with regard to plant parts used, component tested and bioassay models. This review is of fundamental importance to promoting studies on Combretum species, thereby contributing to the development of new therapeutic alternatives that may improve the health of people suffering from various health problems.     

Dynamical analysis of turbulence in fusion plasmas and nonlinear waves

Turbulence is one of the key problems of classical physics, and it has been the object of intense research in the last decades in a large spectrum of problems involving fluids, plasmas, and waves. In order to review some advances in theoretical and experimental investigations on turbulence a mini-symposium on this subject was organized in the Dynamics Days South America 2010 Conference. The main goal of this mini-symposium was to present recent developments in both fundamental aspects and dynamical analysis of turbulence in nonlinear waves and fusion plasmas. In this paper we present a summary of the works presented at this mini-symposium. Among the questions to be addressed were the onset and control of turbulence and spatio-temporal chaos.     

Characterizations of ΛΘ-R 0 and ΛΘ-R 1 topological spaces

We introduce and study two new weak separation axioms called Λ_Θ-R ₀ and Λ_Θ-R ₁ by using the notions of (Λ,Θ)-open sets and (Λ,Θ)-closure operators.     

Optical Fiber Sensing System Based on Long-Period Gratings for Remote Refractive Index Measurement in Aqueous Environments

Abstract

In the field of aqueous environment studies, long-period fiber gratings are very attractive for the real-time monitoring of physical parameters, such as temperature and salinity. However, due to the fiber jacket removal, these are fragile devices when applied in real conditions, where mechanical loads and contamination with algae and other organic materials must be taken into account. This work describes a refractive index sensing head that has been developed and characterized for in situ measurement of water salinity and resistance to hard conditions.     

Beam evolution equation with variable coefficients in non‐cylindrical domains

In this article, we present results concerning with the existence of global solutions and a rate decay estimate for energy associated with an initial and boundary value problem for a beam evolution equation with variable coefficients in non‐cylindrical domains. Copyright © 2007 John Wiley & Sons, Ltd.