全文获取类型
收费全文 | 29249篇 |
免费 | 950篇 |
国内免费 | 194篇 |
专业分类
化学 | 19130篇 |
晶体学 | 214篇 |
力学 | 593篇 |
综合类 | 4篇 |
数学 | 5219篇 |
物理学 | 5233篇 |
出版年
2023年 | 177篇 |
2022年 | 477篇 |
2021年 | 565篇 |
2020年 | 476篇 |
2019年 | 537篇 |
2018年 | 504篇 |
2017年 | 477篇 |
2016年 | 974篇 |
2015年 | 820篇 |
2014年 | 911篇 |
2013年 | 1685篇 |
2012年 | 1783篇 |
2011年 | 2532篇 |
2010年 | 1224篇 |
2009年 | 1220篇 |
2008年 | 1760篇 |
2007年 | 1667篇 |
2006年 | 1525篇 |
2005年 | 1417篇 |
2004年 | 1176篇 |
2003年 | 972篇 |
2002年 | 801篇 |
2001年 | 552篇 |
2000年 | 477篇 |
1999年 | 398篇 |
1998年 | 318篇 |
1997年 | 317篇 |
1996年 | 390篇 |
1995年 | 265篇 |
1994年 | 281篇 |
1993年 | 257篇 |
1992年 | 262篇 |
1991年 | 209篇 |
1990年 | 204篇 |
1989年 | 160篇 |
1988年 | 151篇 |
1987年 | 165篇 |
1986年 | 154篇 |
1985年 | 197篇 |
1984年 | 200篇 |
1983年 | 144篇 |
1982年 | 164篇 |
1981年 | 127篇 |
1980年 | 134篇 |
1979年 | 98篇 |
1978年 | 94篇 |
1977年 | 88篇 |
1976年 | 82篇 |
1974年 | 57篇 |
1973年 | 67篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
941.
The ‘normal’ reaction of α-lactams (aziridinones) is mcleophilic ring ening,1 which can occur with fission of either one of the three bonds (a-b-c), depending on the reagent, to yield and acyclic addition prodnct (I,II,III).2 相似文献
942.
Silvia Dulanská Boris Remenec Ján Bilohuštin Miroslav Labaška Dušan Galanda 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):2189-2192
This paper describes the use of IBC’s AnaLig® Sr-01 molecular recognition technology product to effectively and selectively pre-concentrate, separate, and recover strontium from urine samples. This method uses two-stage columns separation consisting of two different commercial products Eichrom’s Pre-filter Material and AnaLig® Sr-01 column from IBC Advanced Technologies. This method does not involve co-precipitation of strontium as phosphates and oxalates from urine samples. The new rapid method separates strontium-90 with high chemical recovery. 相似文献
943.
944.
Luis Martín Azucena González-Coloma Jesús Burillo Antonio M. F. Palavra José S. Urieta Ana M. Mainar 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1837-1844
The aim of this study is to develop a method and to determine by means of isothermal microcalorimetry the activity of supercritical extracts obtained from growth-controlled wormwood (Artemisia absinthium L.) over Spodoptera littoralis L. (S. littoralis), a polyphagous pest of the Mediterranean crops. In order to achieve this goal, a three-step microcalorimetric method has been developed to insure the quality of the measurements and the validity of the results. Once optimized, different extracts of wormwood obtained by means of supercritical fluid extraction and by traditional methods have been used to investigate their effects over S. littoralis. The microcalorimetric method serves as a tool to complement other bioassays found in the literature. Several extracts from supercritical extractions with solvent density ranging from 485.5 to 819.5 kg m?3 have been tested. The influence of an entrainer addition to the supercritical fluid has also been investigated. The traditional extracts were obtained by hydrodistillation and organic Soxhlet extraction. The supercritical extracts were more efficient against S. littoralis than the traditionally obtained extracts. 相似文献
945.
946.
Jaime Muñoz-Flores Alberto Herrera-Gomez 《Journal of Electron Spectroscopy and Related Phenomena》2012,184(11-12):533-541
Peak-fitting of X-ray photoelectron spectroscopy (XPS) data can be very sensitive to noise when the difference on the binding energy among the peaks is smaller than the width of the peaks. This sensitivity depends on the fitting algorithm. Angle-resolved XPS (ARXPS) analysis offers the opportunity of employing the combined information contained in the data at the various angles to reduce the sensitivity to noise. The assumption of shared peak parameters (center and width) among the spectra for the different angles, and how it is introduced into the analysis, plays a basic role. Sequential fitting is the usual practice in ARXPS data peak-fitting. It consist on first estimating the center and width of the peaks from the data acquired at one of the angles, and then using those parameters as a starting approximation for fitting the data for each of the rest of the angles. An improvement of this method consists of averaging the centers and widths of the peaks obtained at the different angles, and then employing these values to assess the areas of the peaks for each angle. Another strategy for using the combined information is by assessing the peak parameters from the sum of the experimental data. The complete use of the combined information contained in the data-set is optimized by the simultaneous fitting method. It consists of the assessment of the center and width of the peaks by fitting the data at all the angles simultaneously. Computer-generated data was employed to compare the sensitivity with respect to noise between the sequential, averaged-sequential, sum, and simultaneous fitting methods. It is shown that the latter is significantly more robust and could provide reliable results even for noisy data and small peak separation. The fundamentals for the robustness of the simultaneous method are discussed, as well as the possibility of fitting many parameters at the same time. As an added feature of ARXPS, it was found that the estimation of the error intervals on the peak parameters is done remarkably more precisely by employing XPS data at various angles. 相似文献
947.
The sesquiterpene (+)-gossonorol is prepared in only three synthetic steps in 60% overall yield and 82% ee from commercially available reagents. The key asymmetric step is the catalytic enantioselective addition of dimethylzinc to 5-methyl-1-(2-methylphenyl)hex-4-en-1-one catalyzed by chiral isoborneolsulfonamide ligands in the presence of titanium tetraisopropoxide. The modular approach allows the synthesis not only of the aforementioned natural product but also other products arising from the corresponding processes of ethylation, phenylation, and ethynylation, just by changing the final nucleophilic reagent and using the same isoborneol type ligand. 相似文献
948.
Ultra‐high pressure LC for astaxanthin determination in shrimp by‐products and active food packaging
A. Sanches‐Silva T. Ribeiro T. G. Albuquerque P. Paseiro R. Sendón A. Bernaldo de Quirós J. López‐Cervantes D. I. Sánchez‐Machado H. Soto Valdez I. Angulo G. P. Aurrekoetxea H. S. Costa 《Biomedical chromatography : BMC》2013,27(6):757-764
Nowadays, there is increasing interest in natural antioxidants from food by‐products. Astaxanthin is a potent antioxidant and one of the major carotenoids in crustaceans and salmonids. An ultra‐high pressure liquid chromatographic method was developed and validated for the determination of astaxanthin in shrimp by‐products, and its migration from new packaging materials to food simulants was also studied. The method uses an UPLC® BEH guard‐column (2.1 × 5 mm, 1.7 µm particle size) and an UPLC® BEH analytical column (2.1 × 50 mm, 1.7 µm particle size). Chromatographic separation was achieved using a programmed gradient mobile phase consisting of (A) acetonitrile–methanol (containing 0.05 m ammonium acetate)–dichloromethane (75:20:5, v/v/v) and (B) ultrapure water. This method was evaluated with respect to validation parameters such as linearity, precision, limit of detection, limit of quantification and recovery. Low‐density polyethylene films were prepared with different amounts of the lipid fraction of fermented shrimp waste by extrusion, and migration was evaluated into food simulants (isooctane and ethanol 95%, v/v). Migration was not detected under the tested conditions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
949.
Nitrones 1 undergo addition of vinyl organomagnesium bromide to give the allyl hydroxylamines 3 which are easily reduced to the corresponding N-benzyl allyl amines 2. 相似文献
950.
Maria Michaela Porzio Flavia Smarrazzo Alberto Tesei 《Archive for Rational Mechanics and Analysis》2013,210(3):713-772
Initial value problems for quasilinear parabolic equations having Radon measures as initial data have been widely investigated, looking for solutions which for positive times take values in some function space. In contrast, it is the purpose of this paper to define and investigate solutions that for positive times take values in the space of the Radon measures of the initial data. We call such solutions measure-valued, in contrast to function-valued solutionspreviously considered in the literature. We first show that there is a natural notion of measure-valued solution of problem (P) below, in spite of its nonlinear character. A major consequence of our definition is that, if the space dimension is greater than one, the concentrated part of the solution with respect to the Newtonian capacity is constant in time. Subsequently, we prove that there exists exactly one solution of the problem, such that the diffuse part with respect to the Newtonian capacity of the singular part of the solution (with respect to the Lebesgue measure) is concentrated for almost every positive time on the set where “the regular part (with respect to the Lebesgue measure) is large”. Moreover, using a family of entropy inequalities we demonstrate that the singular part of the solution is nonincreasing in time. Finally, the regularity problem is addressed, as we give conditions (depending on the space dimension, the initial data and the rate of convergence at infinity of the nonlinearity ψ) to ensure that the measure-valued solution of problem (P) is, in fact, function-valued. 相似文献