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11.
Alberto Gambi 《Journal of Molecular Spectroscopy》2002,216(2):508-514
The anharmonic force field of difluoromethanimine, F2C NH, has been reinvestigated theoretically using a coupled-cluster singles and doubles approach, augmented for structural optimization and harmonic force field by a contribution of connected triple excitations, CCSD(T). The cubic and quartic force constants have been obtained by numerical derivatives computed from analytical quadratic force constants calculated by second-order Møller-Plesset perturbation theory, MP2. The quadratic force constants and the equilibrium structure of F2C NH have then been scaled by a global least-squares fitting procedure to the spectroscopic data and parameters experimentally determined for this molecule. This force field, obtained in the internal coordinates space and therefore valid for all isotopomers of difluoromethanimine, yields a complete set of spectroscopic molecular constants providing a critical assessment of the experimental rotational and centrifugal distortion constants, fundamentals, overtones, and combination bands determined so far for F2C NH. In addition, the final force field can be used to make predictions of all important vibrational and rotational parameters which should be accurate and useful for new spectroscopic investigations. 相似文献
12.
Alberto S. Cattaneo 《Communications in Mathematical Physics》1997,189(3):795-828
In the context of the Batalin–Vilkovisky formalism, a new observable for the Abelian BF theory is proposed whose vacuum expectation value is related to the Alexander–Conway polynomial. The three-dimensional case
is analyzed explicitly, and it is proved to be anomaly free. Moreover, at the second order in perturbation theory, a new formula
for the second coefficient of the Alexander–Conway polynomial is obtained. An account on the higher-dimensional generalizations
is also given.
Received: 2 October 1996 / Accepted: 21 March 1997 相似文献
13.
Pablo Alberca Bjerregaard Alberto Elduque Cndido Martín Gonzlez Francisco Jos Navarro Mrquez 《Journal of Algebra》2002,250(2):397
The well-known Cartan–Jacobson theorem claims that the Lie algebra of derivations of a Cayley algebra is central simple if the characteristic is not 2 or 3. In this paper we have studied these two cases, with the following results: if the characteristic is 2, the theorem is also true, but, if the characteristic is 3, the derivation algebra is not simple. We have also proved that in this last case, there is a unique nonzero proper seven-dimensional ideal, which is a central simple Lie algebra of type A2, and the quotient of the derivation algebra modulo this ideal turns out to be isomorphic, as a Lie algebra, to the ideal itself. The original motivation of this work was a series of computer-aided calculations which proved the simplicity of derivation algebras of Cayley algebras in the case of characteristic not 3. These computations also proved the existence of a unique nonzero proper ideal (which turns out to be seven-dimensional) in the algebra of derivations of split Cayley algebras in characteristic 3. 相似文献
14.
Alberto Giaconia Giuseppe Filardo Onofrio Scialdone Alessandro Galia 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4122-4135
A laboratory‐scale continuous reaction system using a stirred tank reactor was assembled in our laboratory to study the dispersion polymerization of vinyl monomers in supercritical carbon dioxide (scCO2). The apparatus was equipped with a suitable downstream separation section to collect solid particles entrained in the effluent stream from the reactor, whose monomer concentration could be measured online with a gas chromatograph. The dispersion polymerization of methyl methacrylate in scCO2 was selected as a model process to be investigated in the apparatus. The experiments were performed at 65 °C and 25 MPa with 2,2′‐azobisisobutyronitrile as the initiator and a reactive polysiloxane macromonomer as a surfactant to investigate the effect of the mean residence time of the reaction mixture on the monomer conversion, polymerization rate, polymer molecular weight, and particle size distribution. The results were compared with those obtained in batch polymerizations carried out under similar operative conditions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4122–4135, 2006 相似文献
15.
Precisely two of the homogeneous spaces that appear as coadjoint orbits of the group of string reparametrizations,
, carry in a natural way the structure of infinite dimensional, holomorphically homogeneous complex analytic Kähler manifolds. These areN=Diff(S
1)/Rot(S
1) andM=Diff(S
1)/Möb(S
1). Note thatN is a holomorphic disc fiber space overM. Now,M can be naturally considered as embedded in the classical universal Teichmüller spaceT(1), simply by noting that a diffeomorphism ofS
1 is a quasisymmetric homeomorphism.T(1) is itself a homomorphically homogeneous complex Banach manifold. We prove in the first part of the paper that the inclusion ofM inT(1) iscomplex analytic.In the latter portion of this paper it is shown that theunique homogeneous Kähler metric carried byM = Diff (S
1/SL(2, ) induces preciselythe Weil-Petersson metric on the Teichmüller space. This is via our identification ofM as a holomorphic submanifold of universal Teichmüller space. Now recall that every Teichmüller spaceT(G) of finite or infinite dimension is contained canonically and holomorphically withinT(1). Our computations allow us also to prove that everyT(G), G any infinite Fuchsian group, projects out ofM transversely. This last assertion is related to the fractal nature ofG-invariant quasicircles, and to Mostow rigidity on the line.Our results thus connect the loop space approach to bosonic string theory with the sum-over-moduli (Polyakov path integral) approach. 相似文献
16.
Alberto Facchini 《Annali di Matematica Pura ed Applicata》1989,155(1):389-399
Sunto Se A è un modulo divisibile su un dominio d'integrità R e Q è il campo delle frazioni di R, sia RA Q il massimo sopraanello di R tale che A possa essere dotato della struttura di RA-modulo. La struttura di RA riflette quella di A. Se A è un modulo divisibile semplice di torsione, cioè è divisibile di torsione e non ha sottomoduli divisibili propri non nulli, RA è analiticamente irriducibile. Se C e D sono due moduli divisibili semplici, diciamo C equivalente a D se RC=RD. Se d-Space (R) è un insieme di rappresentanti delle classi di equivalenza degli R-moduli divisibili semplici, d-Space (R) puó essere dotato di una struttura di spazio di Hausdorff zero-dimensionale; lo spazio topologico d-Space (R) (da noi chiamato lo spazio di divisibilità di R) contiene un sottospazio chiuso omeomorfo alla superficie di Riemann astratta di R dotata della patch topology.
Lavoro eseguito con il contribute del Ministero délia Pubblica Istruzione 相似文献
Lavoro eseguito con il contribute del Ministero délia Pubblica Istruzione 相似文献
17.
Alberto Cavicchioli 《Geometriae Dedicata》1986,20(3):345-348
We construct a countable set of prime non-homeomorphic homology spheres with Heegaard genus 2.
Work performed under the auspicies of the G.N.S.A.G.A. of the C.N.R. (National Research Council of Italy) and within the project Geometria delle Varietà Differenziabili of the M.P.I. (Italy). 相似文献
Sunto Si prova l'esistenza di una classe numerabile di sfere omologiche prime non omeomorfe con genere di Heegaard 2.
Work performed under the auspicies of the G.N.S.A.G.A. of the C.N.R. (National Research Council of Italy) and within the project Geometria delle Varietà Differenziabili of the M.P.I. (Italy). 相似文献
18.
Substoichiometric amorphous thin films of MoO3 in both the transparent and absorptive forms have been studied by X-ray electron spectroscopy. The transparent films can be colored blue (absorptive) electrically or by UV irradiation. The electron distribution curve of the blue film exhibits a small band near the Fermi edge which is absent in the transparent sample. This new band is attributed to electrons trapped in positively charged anion vacancies in the substoichiometric MoO3 lattice. This model provides an interpretation of the electrical conductivity and color of the films. 相似文献
19.
20.
Aringhieri Roberto Bigharaz Sara Duma Davide Guastalla Alberto 《Central European Journal of Operations Research》2022,30(1):189-211
Central European Journal of Operations Research - Disaster management generally includes the post-disaster stage, which consists of the actions taken in response to the disaster damages. These... 相似文献