首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4017篇
  免费   102篇
  国内免费   35篇
化学   3041篇
晶体学   17篇
力学   91篇
数学   465篇
物理学   540篇
  2021年   43篇
  2020年   48篇
  2019年   47篇
  2018年   32篇
  2016年   59篇
  2015年   61篇
  2014年   109篇
  2013年   173篇
  2012年   203篇
  2011年   237篇
  2010年   127篇
  2009年   109篇
  2008年   173篇
  2007年   199篇
  2006年   219篇
  2005年   190篇
  2004年   165篇
  2003年   152篇
  2002年   169篇
  2001年   75篇
  2000年   78篇
  1999年   45篇
  1998年   36篇
  1997年   45篇
  1996年   61篇
  1995年   35篇
  1994年   38篇
  1993年   40篇
  1992年   40篇
  1991年   32篇
  1990年   34篇
  1989年   28篇
  1988年   24篇
  1987年   24篇
  1986年   34篇
  1985年   61篇
  1984年   51篇
  1983年   41篇
  1982年   50篇
  1981年   45篇
  1980年   53篇
  1979年   65篇
  1978年   52篇
  1977年   39篇
  1976年   44篇
  1975年   26篇
  1974年   28篇
  1973年   29篇
  1969年   21篇
  1968年   19篇
排序方式: 共有4154条查询结果,搜索用时 15 毫秒
21.
The use of multiresolution decompositions in the context of finite volume schemes for conservation laws was first proposed by A. Harten for the purpose of accelerating the evaluation of numerical fluxes through an adaptive computation. In this approach the solution is still represented at each time step on the finest grid, resulting in an inherent limitation of the potential gain in memory space and computational time. The present paper is concerned with the development and the numerical analysis of fully adaptive multiresolution schemes, in which the solution is represented and computed in a dynamically evolved adaptive grid. A crucial problem is then the accurate computation of the flux without the full knowledge of fine grid cell averages. Several solutions to this problem are proposed, analyzed, and compared in terms of accuracy and complexity.

  相似文献   

22.
Currently, most combinatorial optimisation problems have to be solved, if the optimum solution is sought, using general techniques to explore the space of feasible solutions and, more specifically, through exploratory enumerative procedures in trees and search graphs. We propose Branch and Win, a general formulation for understanding and synthesising the different tree search procedures that have been presented in the literature of operations research as well as in that of artificial intelligence. Several general ideas are also presented, whose application allows designing new hybrid search algorithms, in order to implement the procedure.  相似文献   
23.
The pressure-temperature ( p - T ) phase diagrams for four smectogenic members of the 4'-alkyl-4-cyanobiphenyl homologous series ( n CB, n =9, 10, 11 and 12) over the temperature range 320-410 K and pressure range 0.1-300 MPa (3 kbar) were constructed using DTA. At 1 atm 9CB exhibits nematic and smectic A d phases, while the other members show only the smectic A d phase. However, at elevated pressures the clearing line splits in the case of 10CB and 11CB which indicates the induction of a nematic phase. It was found that the triple point, where the isotropic, nematic and smectic phases coexist, is strongly shifted to higher pressures with increasing chain length. This was interpreted as being caused by a loss of the rod-like shape of the molecules containing longer alkyl tails which explore a range of conformations. The slope of the clearing line, d T /d p , depends strongly on the length of the alkyl chain for the n CB series, but does not show a step-wise change between the nematogenic and smectogenic members.  相似文献   
24.
Conductive composite films of poly(styrene‐con‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007  相似文献   
25.
The title compound (H2DTMSP[EBP]), C14H36O6P2Si2, was crystallized by the slow evaporation of a solution in a 20:1 mixture of pentane and acetone. The H2DTMSP[EBP] mole­cule lies about an inversion center. In the solid state, the mol­ecule exists in an anti configuration, with the mol­ecular backbone C—C bond located on an inversion center. The compound exists in the solid state as hydrogen‐bonded infinite sheets in the ab plane, unlike the methyl­ene analogue, which exists as hydrogen‐bonded infinite chains, demonstrating an `even–odd' effect of the length of the backbone alkyl chain.  相似文献   
26.
Monodisperse magnetizable colloidal silica particles in a stable dispersion have been functionalized with a homogeneous catalyst: a PCP–pincer Pd-complex. In a proof-of-principle experiment we demonstrate the catalytic activity of the colloids in a C–C bond formation reaction. Advantages of the magnetic silica carriers are the large surface-to-volume ratio and the easy recovery by magnetic separation. After magnetic separation, the catalyst-loaded particles are readily redispersed for further use.  相似文献   
27.
Résumé SoitG un groupe moyennable connexe, locallement compact, à base dénombrable. Soit une mesure positive sur les boréliens deG. Nous étudions les fonctions boréliennes positivesh vérifiant: g G, . Sous de bonnes hypothèses sur , nous obtenons, pour ces fonctions, une représentation intégrale à l'aide d'exponentielles.
Summary LetG be a connected locally compact separable amenable group. Let be a positive measure on the Borel -field ofG. We study the positive Borel functionsh onG which satisfy: g G, . Under smooth assumptions on , we establish an integral representation of these functions in term of exponentials.
  相似文献   
28.
Chiral tridentate N-tosylated aminoimine ligands were used in the Cu(II)-catalyzed enantioselective addition of phenylacetylene to N-aryl arylimines, affording products up to 92% ee.  相似文献   
29.
The growth and oxygen consumption of a variety of thermophilic, acidophilic bacteria in the presence of thiophene-2-carboxylate (T2C) and dibenzothiophene (DBT) have been determined. T2C was extremely toxic to the acidophiles in comparison with neutrophiles, but appeared to be degraded by a heterotrophicSulfolobus- like thermophile. DBT proved to be unstable at high temperatures, even in the absence of bacteria, and was not a substrate for the thermophiles.  相似文献   
30.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号