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991.
Summary: Imidazol(in)ium-2-carboxylates were used as N-heterocyclic carbene (NHC) ligand precursors to convert the [RuCl2(p-cymene)]2 dimer into three ruthenium-arene complexes of the [RuCl2(p-cymene)(NHC)] type. The decarboxylation of NHC · CO2 betaines also provided a convenient synthetic path to prepare five well-known ruthenium-NHC catalysts for olefin metathesis and related reactions, including the second generation Grubbs and Hoveyda–Grubbs catalysts, via ligand exchange with phosphine-containing, first generation ruthenium-benzylidene or indenylidene complexes. Both procedures are particularly attractive from a practical point of view, because NHC · CO2 adducts are stable zwitterionic compounds that can be stored and handled with no particular precautions. 相似文献
992.
993.
Albert Ziegler 《Mathematical Logic Quarterly》2010,56(6):666-669
In the article [4], a new constructive set theoretic principle called Refinement was introduced and analysed. While it seemed to be significantly weaker than its alternative, the more established axiom of Fullness (a constructive version of the Powerset axiom from classical set theory), it was shown to suffice to imply many of the mathematically important consequences. In this article, we will define for each set A a set of truth values which measures the complexity of the equality relation on A. Using these sets we will show that Refinement is actually equivalent to Fullness on the basis of the other axioms of constructive Zermelo‐Fraenkel set theory (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
994.
With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized. 相似文献
995.
Witold Korytowski Jared C. Schmitt Albert W. Girotti 《Photochemistry and photobiology》2010,86(4):747-751
Singlet oxygen attack on cholesterol (Ch), a prominent monounsaturated lipid of mammalian cell plasma membranes, gives rise to three hydroperoxide (ChOOH) isomers, 5α-OOH, 6α-OOH and 6β-OOH, the latter two in lower yield than 5α-OOH, and 6α-OOH in lowest yield. A third possible positional isomer, 7α-OOH and 7β-OOH, is produced by free radical attack. In the presence of iron and ascorbate (Fe/AH), 5α-OOH or 6β-OOH in phosphatidylcholine/Ch/ChOOH (20:15:1 by mol) liposomes was reduced to its corresponding alcohol, the rate constant being approximately the same for both ChOOHs. Using [14C]Ch as an in situ probe, we found that liposomal 5α-OOH readily set off free radical-mediated (chain) peroxidation reactions when exposed to Fe/AH, whereas 6β-OOH under the same conditions did not. Moreover, liposomal 5α-OOH triggered robust chain peroxidation in [14C]Ch-labeled L1210 cells, leading to cell death, whereas 6β-OOH was essentially inert in this regard. Thus, 5α-OOH and 6β-OOH undergo iron-catalyzed reductive turnover, but only the former can provoke toxic membrane damage. These novel findings have important implications for UVA-induced photodamage in Ch-rich tissues like skin and eye, where 1O2 often plays a major role. 相似文献
996.
The lipophile extract of Lonchocarpusnicou roots afforded the new pyranochalcone 3-O-methylabyssinone A as well as the new rotenoids 7′-hydroxytephrosin, and 7′-nor-6′-oxo-2′,3′-dehydrorotenone, both compounds occurring with the known 7′-hydroxydeguelin and 7′-nor-6′-oxo-2′,3′-dehydro-12aβ-hydroxyrotenone. Furthermore, two rotenoid epoxides previously reported as resulting from the direct oxidative conversion of rotenone and 12aβ-hydroxyrotenone, respectively, were isolated for the first time from a plant source. All the structures were established on the basis of UV, MS, and NMR data. 相似文献
997.
Indole-substituted N-propargylamides undergo a gold(III)-catalyzed cyclization to give oxazoles or β-carbolinones, depending on the substitution pattern at the amide nitrogen. Secondary amides furnished oxazoles via a 5-exo-dig cyclization, while tertiary indole-2-carboxamides cycloisomerized to give 2,9-dihydro-β-carbolin-1-ones upon treatment with catalytic amounts of gold(III) chloride. An optimized procedure was developed to prepare several new N-benzyl-β-carbolinones as well as the corresponding β-carbolines, which are of interest as core structures found in various natural products such as the harman, ervolanine, and lavendamycin class of alkaloids. 相似文献
998.
999.
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