Magnetic Properties of the Mechanically Alloyed (Fe0.85Mn0.15)0.3Cu0.7 System

Samples of nominal composition (Fe_0.85Mn_0.15)_0.3Cu_0.7 were prepared by mechanical milling starting from pure element powders. In order to elucidate the effect of the alloying time upon the magnetic properties of the system, milling times ranging from 1 hour up to 72 hours were considered. The phase distribution present on the as-milled materials was identified from the analysis of X-ray diffraction data. The room temperature magnetic properties of the samples were studied by means of ⁵⁷Fe Mössbauer spectroscopy and vibrating sample magnetometry, whereas their low temperature magnetic behavior was characterized through magnetic susceptibility measurements. The results evidenced a strong dependence of the magnetic properties on the milling time and, concretely, the occurrence of a superparamagnetic behavior in the long-time-milled samples for which an extended solid solution was obtained. This fact is attributable both to the obtained crystallite sizes, which resulted to be of the order of a few nanometers, and to a milling-driven increase of the lattice parameter.     

Rolf Huisgen,Eminent Chemist and Polymath (1920–2020): In His Own Words and In His Publication Metrics

As a compliment to several other publications that present and honor Rolf Huisgen's research achievements, the first part of this paper reveals the human side of this eminent chemist. From excerpts from many of his personal and professional writings, Huisgen's personality and philosophies of life are revealed. Also revealed is Huisgen functioning as a historian of chemistry. The second part of this paper examines the scientometrics of Huisgen's publication history. In the late 1950s and early 1960s, Huisgen's career experienced a major transition in terms of publication metrics and the influence these papers had on the organic chemistry community. This was the result of his research into 1,3‐dipolar cycloadditions. Citations to his scientific contributions are well spread over many of his papers, demonstrating his constant work and the building up of a research topic, which continued after his official retirement in 1988. In fact, 17 % of his more than 600 publications appeared after 1988. The majority of Huisgen's papers were co‐authored with his many graduate and postdoctoral students. Consistent with the trend of that era, Huisgen was the sole author of most of his Review articles, and not just those of his many plenary lectures, and it is those Review articles that proved to be his most cited publications. This demonstrates the power and influence of Review articles—secondary sources, in the vocabulary of historians and sociologists of science. In those Review articles, Huisgen principally described the state of the art of 1,3‐dipolar cycloadditions—his golden offspring.     

Weighted percolation on directed networks

We present and numerically test an analysis of the percolation transition for general node removal strategies valid for locally treelike directed networks. On the basis of heuristic arguments we predict that, if the probability of removing node i is p(i), the network disintegrates if p(i) is such that the largest eigenvalue of the matrix with entries A(ij)(1-p(i)) is less than 1, where A is the adjacency matrix of the network. The knowledge or applicability of a Markov network model is not required by our theory, thus making it applicable to situations not covered by previous works.     

Aggregation of sphalerite: role of zinc ions

Sphalerite from six sources is shown to aggregate at ca. pH 7-9, confirmed by different techniques (settling velocity, suspension analysis, and optical microscopy). This does not correlate with the isoelectric point, which is consistently < pH 6. A similar observation was made by Healy and Jellet [J. Colloid Interface Sci. 24 (1967) 41-46] for ZnO (and reconfirmed here), who suggested Zn hydrolysis products were responsible. The hypothesis is tested using chalcopyrite and silica suspensions in the presence of Zn ions. It is found that aggregation occurs over the same pH range, 7-9. Solution and surface analysis (extraction by EDTA) shows sphalerite released sufficient Zn ions to promote aggregation. The pH range 7-9 corresponds to hydroxide formation, suggesting this is the species responsible. Aggregation of sphalerite due to the polymerization/flocculation action of zinc hydroxide is proposed.     

Bulk Magnetic Properties of the Fe0.5Mn0.1Al0.4 Disordered Alloy: A Monte Carlo Study

Hyperfine Interactions - In this work we present a simulational study of the bulk magnetic properties of the Fe0.5Mn0.1Al0.4 disordered system. The magnetization per site, specific heat and...     

Most Probable Histories for Nonlinear Dynamics: Tracking Climate Transitions

The effective action provides an appropriate cost function to determine most probable (or optimal) histories for nonlinear dynamics with strong noise. In such strong-coupling problems, a nonperturbative technique is required to calculate the effective action. We have proposed a Rayleigh–Ritz variational approximation, which employs simple moment-closures or intuitive guesses of the statistics to calculate the effective action. We consider here an application to climate dynamics, within a simple bimodal Langevin model similar to that proposed by C. Nicolis and G. Nicolis [Tellus 33:225 (1981)]. Capturing climate state transitions even in this simple model is known to present a serious problem for standard methods of data assimilation. In contrast, it is shown that the effective action for the climate history is already well-approximated by a one-moment closure and that the optimal, minimizing history robustly tracks climate change, even with large observation errors. Furthermore, the Hessian of the effective action provides the ensemble variance as a realistic measure of confidence level in the predicted optimal history.     

Simultaneous effects of hydrostatic pressure and applied electric field on the impurity-related self-polarization in GaAs/Ga1−xAlxAs multiple quantum wells

A detailed theoretical study of the combined effects of hydrostatic pressure and in-growth direction applied electric field on the binding energy and self-polarization of a donor impurity in a system of GaAs-(Ga,Al)As coupled square quantum wells is presented. The study is performed in the framework of the effective mass and parabolic band approximations and using a variational procedure. The electron effective mass, the dielectric constant, the barrier height, the well sizes, all them varying with the hydrostatic pressure are taken into account within the study. The results obtained show that the impurity binding energy and its self-polarization bear strong dependencies with the hydrostatic pressure, the strength of the applied electric field, the width of the confining potential barriers, and the impurity position.     

Magnetic phase diagram simulation of La1−xCaxMnO3 system by using Monte Carlo, Metropolis algorithm and Heisenberg model

This work presents a critical temperature study of La_1−xCa_xMnO₃ manganites in bulk by means of Monte Carlo method thermal activated magnetic properties. The analysis was carried out for stoichiometries in the range of 0≤x≤1. The model is based on a three-dimensional classical Heisenberg-Hamiltonian involving the presence of Mn^3+eg, Mn^3+eg′ and Mn⁴⁺ ions, and their nearest neighbor interaction. For this modeling, simple cubic lattice samples of size L³, with L=6, 15 and 30 were used. The values of exchange parameters were determined by using LaMnO₃ (x=0), La_0.5Ca_0.5MnO₃ and CaMnO₃ (x=1) phases. Relationships between exchange parameters and anisotropy constants for different hole densities were found. Results of transition temperatures for each phase showed good agreement with experimental reports, especially for L=30 and L→∞.     

High dynamic range imaging method for interferometry

We demonstrate a method to easily and quickly extend the dynamic range imaging capabilities of the camera in a typical interferometric approach. The camera dynamic range is usually low and limited to 256 gray levels. Also, it is well known that one may have over or under-exposed regions in the interferogram (due to non-uniform illumination) which makes these image regions not reliable. In our proposed method it is not necessary to obtain or use the non-linear camera response curve in order to extend the camera dynamic range. We obtain a sequence of differently exposed interferograms, typically five or six; after that, we compute the corresponding normalized fringe patterns and modulation maps using a typical normalization method. These normalized patterns are combined through a temporal weighted average using as weights the corresponding modulation maps. We show a set of experimental results that prove the effectiveness of the proposed method.     

Predicting criticality and dynamic range in complex networks: effects of topology

The collective dynamics of a network of coupled excitable systems in response to an external stimulus depends on the topology of the connections in the network. Here we develop a general theoretical approach to study the effects of network topology on dynamic range, which quantifies the range of stimulus intensities resulting in distinguishable network responses. We find that the largest eigenvalue of the weighted network adjacency matrix governs the network dynamic range. When the largest eigenvalue is exactly one, the system is in a critical state and its dynamic range is maximized. Further, we examine higher order behavior of the steady state system, which predicts that networks with more homogeneous degree distributions should have higher dynamic range. Our analysis, confirmed by numerical simulations, generalizes previous studies in terms of the largest eigenvalue of the adjacency matrix.