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排序方式: 共有491条查询结果,搜索用时 15 毫秒
41.
Brandon J. O'Neill David H. K. Jackson Dr. Anthony J. Crisci Carrie A. Farberow Fengyuan Shi Dr. Ana C. Alba‐Rubio Dr. Junling Lu Dr. Paul J. Dietrich Dr. Xiangkui Gu Dr. Christopher L. Marshall Prof. Peter C. Stair Dr. Jeffrey W. Elam Dr. Jeffrey T. Miller Prof. Fabio H. Ribeiro Prof. Paul M. Voyles Prof. Jeffrey Greeley Prof. Manos Mavrikakis Prof. Susannah L. Scott Prof. Thomas F. Kuech Prof. James A. Dumesic 《Angewandte Chemie (International ed. in English)》2013,52(51):13824-13824
42.
43.
Stefan Eibl Andrew Fitch Michela Brunelli Alexander Dominic Evans Philip Pattison Marie Plazanet Mark Robert Johnson Christiane Alba‐Simionesco Helmut Schober 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(6):o278-o280
The title compound, C10H18, a decalin stereoisomer, crystallizes with Z′ = 0.5 in the space group P21/n. The trans‐decalin molecule is located on an inversion centre with both rings in a chair conformation, making for a quasi‐flat overall shape. Despite the absence of hydrogen bonds, it crystallizes easily. In this work the unknown crystal structure of trans‐decalin has been solved and refined using X‐ray powder diffraction data. 相似文献
44.
B. Mill 《Chromatographia》1999,50(11-12):745-745
45.
Andrea‐Nekane R. Alba Xavier Companyó Guillem Valero Albert Moyano Prof. Dr. Ramon Rios Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(18):5354-5361
A new, easy, and highly enantioselective method for the synthesis of quaternary α‐alkyl‐α‐amino acids based on organocatalysis is reported. The addition of oxazolones to 1,1‐bis(phenylsulfonyl)ethylene is efficiently catalyzed by simple chiral bases or thioureas. The reaction affords α,α‐disubstituted α‐amino acid derivatives with complete C4 regioselectivity and with excellent yields and enantioselectivities. This methodology is complementary to previously reported enantioselective approaches to quaternary α‐amino acids and allows the synthesis of α‐phenyl‐α‐alkyl‐α‐amino acids and α‐tert‐butyl‐α‐alkyl‐α‐amino acids. It has distinct advantages in terms of operational simplicity, enviromentally friendly conditions, and suitability for large‐scale reactions. 相似文献
46.
The nucleophilic addition of both silyl ketene acetals and lithium enolates derived from methyl acetate to chiral non-racemic N-(benzyloxyethyl)nitrones has been studied both experimentally and theoretically. Aromatic nitrones showed lower reactivity that aliphatic nitrones and the addition of the silyl ketene acetal led to lower selectivities than the addition of the corresponding lithium enolate. Whereas low selectivity was obtained for the addition of the silyl ketene acetal, only one diastereomer could be detected in all cases for the addition of lithium enolate to aliphatic nitrones. The synthetic utility of the two chiral auxiliaries employed lies in the preparation of enantiomeric compounds. DFT theoretical calculations confirmed the stepwise mechanism for the addition of silyl ketene acetals to nitrones and are in good agreement with the observed experimental results. 相似文献
47.
The absorption and circular dichroism (CD) spectra of La3Ga5SiO14 langasite crystals doped with Pr3+, Ho3+, and Er3+ ions have been studied in the wavelength range of 350–700 nm. The electronic transitions of these ions, which replace La3+
ions in the 3e position with the symmetry 2, are observed in the spectra. All transitions are active in both the absorption and CD spectra.
The dipole strengths D
om, rotational strengths R
om, and anisotropy factors g have been calculated for well-resolved bands. Some features are noted for the spectra that were
obtained, and their relationship with the structure disorder is considered 相似文献
48.
Ofelia T. Alas Lucia R. Junqueira Jan van Mill Vladimir V. Tkachuk Richard G. Wilson 《Central European Journal of Mathematics》2011,9(3):603-615
For a topological property P, we say that a space X is star Pif for every open cover Uof the space X there exists Y ? X such that St(Y,U) = X and Y has P. We consider star countable and star Lindelöf spaces establishing, among other things, that there exists first countable pseudocompact spaces which are not star Lindelöf. We also describe some classes of spaces in which star countability is equivalent to countable extent and show that a star countable space with a dense σ-compact subspace can have arbitrary extent. It is proved that for any ω 1-monolithic compact space X, if C p (X)is star countable then it is Lindelöf. 相似文献
49.
J. Y. Bello Cruz R. Díaz Millán 《Journal of Optimization Theory and Applications》2014,161(3):728-737
We propose a direct splitting method for solving a nonsmooth variational inequality in Hilbert spaces. The weak convergence is established when the operator is the sum of two point-to-set and monotone operators. The proposed method is a natural extension of the incremental subgradient method for nondifferentiable optimization, which strongly explores the structure of the operator using projected subgradient-like techniques. The advantage of our method is that any nontrivial subproblem must be solved, like the evaluation of the resolvent operator. The necessity to compute proximal iterations is the main difficulty of other schemes for solving this kind of problem. 相似文献
50.
Ultrasound‐assisted emulsification microextraction coupled with high‐performance liquid chromatography for the simultaneous determination of fragrance allergens in cosmetics and water
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Jessica Pérez‐Outeiral Esmeralda Millán Rosa Garcia‐Arrona 《Journal of separation science》2015,38(9):1561-1569
A simple, inexpensive, and environmentally friendly method based on ultrasound‐assisted emulsification microextraction followed by solidification of floating organic drop and high‐performance liquid chromatography coupled to diode array detection was developed for the simultaneous determination of 18 potentially allergenic fragrance substances. Several parameters affecting the microextraction process were investigated in detail by the “one‐variable‐at‐a‐time” approach. Optimal conditions were the following: 50 μL of 2‐dodecanol as extraction solvent, 10 mL of sample containing 150 g/L of salt, and 5 min of sonication at 35°C. Under the optimized conditions, method showed good linearity in the selected ranges, with squared correlation coefficients ranging from 0.948 to 0.999. Limits of detection ranged from 0.001 to 0.154 μg/mL and enrichment factors from 9 to 237. Precision of the method, expressed as relative standard deviation, was checked at two levels obtaining good results (3.3–14.4%). Recovery studies were made in baby bath water and in eau de cologne showing acceptable accuracy. Finally, the developed method was successfully applied to different commercial cosmetic and water samples. The most commonly found analyte was linalool followed by cinnamal and lilial. Most of the analyzed samples contained at least one of the target compounds. 相似文献