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141.
The fluorescence characteristics of the complex of piperine with cation in micellar system were studied. At the same time, the influence of experimental condition on the fluorescence intensity was also studied. The experiments indicated that piperine had very low fluorescence signal itself. But in pH 8.77 Na2HPO4-NaH2PO4 buffer solution, both Mn(Ⅱ) and cationic surfactant cetyltrimethylammonium bromide can enhance the fluorescence intensity and stability of piperine. Based on this, a sensitive method has been developed for the quantitative determination of piperine in Mn(Ⅱ)-piperine-cetyltrimethylammonium bromide ternary system. Under the optimum conditions, there is a linear relationship between the enhancement of fluorescence intensity and the concentration of Mn(Ⅱ). The optimal conditions are as follows: the concentration of Mn(Ⅱ) is 2.5×10-4 mol·L-1 and the concentration of cetyltrimethylammonium bromide is 5×10-4 mol·L-1. The fluorescence intensity was determined by a 1 cm quartz cell with the excitation wavelength of 352 nm and the emission wavelength of 452 nm. The linear range of concentration of piperine was 2.02-10.1 μg·mL-1 with the relative coefficient of 0.998 5 and the detection limit of 0.060 2 μg·mL-1. The relative standard deviation (RSD) was 1.10%. The proposed method has been successfully applied to the quantitative determination of piperine in the Mongolian medicine Piper longum L, and the recovery was within the range of 97.6%-102.0%. The results were very satisfactory. 相似文献
142.
143.
基于LED光源痕量二氧化氮气体的检测 总被引:3,自引:0,他引:3
随着现代化工业的发展,大气污染越来越严重,吸收光谱法是检测大气污染的重要手段.NO2是大气污染的主要污染物之一,文章将发光二极管作为光源,选择发光光谱范围处于NO2强吸收峰位置的发光二极管,通过测虽含有NO2污染物的吸收光谱,利用最小二乘法,将实验得到的吸收光谱与标准谱作拟合运算,反演计算出污染物浓度.分析了检测的幕本原理,研究了光谱分析过程,包括实验光谱与标准光谱的拟合、浓度的反演计算等数据处理过程.具体利用NO2在300~500 nm光谱范围内有强吸收的特点,测量了样品中NO2的浓度.实验使用发光二极管作为光源,使检测变得方便快捷,实验装置便于携带,可以随时对待测场所实现高精度的实时在线检测. 相似文献
144.
Shuang Xi MEI Zhi NA Xue Mei NIU Chao Ming LI Zhong Wen LIN Han Dong SUN* Laboratory of Phytochemistry Kunming Institute of Botany Chinese Academy of Sciences Kunming 《中国化学快报》2000,11(12)
In our previous paper1, we reported a novel sesquiterpenoid from the EtOAc part of Coleus xanthanthus. The continuous work for the investigation of the petroleum part of C. xanthanthus led to the isolation of two new abietane diterpenoids which were identified as 11-acetoxy-coleon U(1) and 11,16-diacetoxy-coleon U(2) by spectral methods. Figure 1 The structures of 1 and 2 1 2 R= H OAcCompound 1 was obtained as pale yellow cubic crystals, mp:190.5-1920C; [(]+ 20.50 (c=0.875, CHCl3). Its… 相似文献
145.
最小势能原理作为结构力学的提高部分,很少在该课程中看到关于它的完整介绍。本文以等刚度连续梁为研究对象,在只考虑弯曲变形的情况下,讨论了位移法典型方程的适用条件。在此基础上,分析了势能法和位移法之间的对偶关系。得出:等刚度连续梁在平面载荷与支座反力构成的平衡力系作用下,可能的小位移状态由虚力方程控制。若真实位移还能利用叠加原理进行求解,则可能位移状态下的总势能在真实位移处取极小值。等刚度连续梁弯曲变形的分析验证了最小势能原理,有助于对一般情况下最小势能原理的深刻认识。
相似文献146.
147.
P. Bordalo Ph. Busson L. Kluberg A. Romana R. Sameron Cl. Vallée J. J. Blaising A. Degré P. Juillot R. Morand M. Winter M. Guanziroli P. Le Coultre H. Suter V. L. Telegdi K. Freudenreich L. Carotenuto A. Ereditato E. Gorini P. Strolin NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,39(1):7-11
We present a study of \(B\bar B\) meson pair production inπ ? interactions at 140, 194 and 286 GeV incident pion energy. At 286 GeV, where we have the best statistics, we find a model-dependent \(B\bar B\) production cross-section \(\sigma _{BB} = 14_{ - 6}^{ + 7} nb/nucleon\) . 相似文献
148.
我国静电生物学效应机理研究新进展 总被引:23,自引:0,他引:23
文章综述了静电处理作物种子及诱发的生物学效应,研究了电场阈值、电场极限值和电场作用时间等电场剂量问题。通过生理指标分析了电场对作物发芽势、发芽率、芽长、根长、叶片自然鲜重、种子简化活力指数、植物代谢及营养吸收的影响。从大量的应用研究中广泛探索了电场对植物细胞膜完整性的影响及对酶活性的改变,希望用物理学方法研究对酶蛋白分子构象的影响,总结了电场在改善植物抗逆性研究方面的最新进展,以期在细胞和分子水平上探讨其作用机理,为静电在农业上的进一步广泛应用奠定理论基础。 相似文献
149.
聚醚醚酮酮等温结晶动力学的研究陈艳,王军佐,曹俊奎,那辉,吴忠文(吉林大学化学系,长春,130023)关键词聚醚醚酮酮,等温结晶动力学,差示扫描量热法聚醚醚酮酮(PEEKK)是在聚醚醚酮(PEEK)基础上开发成功的一种耐热高分子材料。它保持了PEEK... 相似文献
150.
It is still a matter of debate to understand the equation of state of cold matter with supra-nuclear density in compact stars because of unknown non-perturbative strong interaction between quarks. Nevertheless, it is speculated from an astrophysical view point that quark clusters could form in cold quark matter due to strong coupling at realistic baryon densities. Although it is hard to calculate this conjectured matter from first principles, one can expect that the inter-cluster interaction will share some general features with the nucleon-nucleon interaction successfully depicted by various models. We adopt a two-Gaussian component soft-core potential with these general features and show that quark clusters can form stable simple cubic crystal structure if we assume that the wave function of quark clusters have a Gaussian form. With this parametrization, the Tolman-Oppenheimer-Volkoff equation is solved with reasonably constrained parameter space to give mass-radius relations of crystalline solid quark stars. With baryon number densities truncated at 2n0 at surface and the range of the interaction fixed at 2 fm we can reproduce similar mass-radius relations to that obtained with bag model equations of state. The maximum mass ranges from 0.5M⊙ to 3M⊙. The recently measured high pulsar mass ( 2M⊙) is then used to constrain the parameters of this simple interaction potential. 相似文献