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321.
Phenylbiguanide reacts with some π-acceptors such as TCNE, TCNQ, CNIND, DCNQ, and CHL-o, if any. opy; 2003 Wiley Periodicals, Inc. Heteroatom Chem 15:63–66, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10213 相似文献
322.
Alaa S. Abd-El-Aziz Nelson M. Pereira Waleed Boraie Shaune L. McFarlane Erin K. Todd 《Macromolecular Symposia》2004,209(1):207-216
The synthesis of sulfone-containing monomers with pendent cationic cyclopentadienyliron (CpFe+) moieties has been accomplished via nucleophilic aromatic substitution of dichloroarene complexes with a number aliphatic dithiols. These complexes were further oxidized using m-CPBA to give the sulfone-based monomers. Polymerization of the sulfone-based monomers with O-containing nucleophiles produced the sulfone-based polymers. Direct nucleophilic aromatic substitution of dichloroarene complexes with dinucleophiles allowed for the formation of organoiron sulfide-based polymers. Oxidation of these polymers led to the formation of sulfone polymers with the pendent iron moieties. The organometallic monomers and polymers were found to be more soluble in polar solvents in comparison to their organic analogues. 相似文献
323.
Organoiron polynorbornene containing arylazo or hetarylazo dye chromophores has been prepared via ring opening metathesis polymerization using Grubbs' catalyst. The obtained polymers were isolated as brightly colored materials and displayed good solubility in polar organic solvents. The colors of these polymers were affected by the nature of the incorporated azo chromophores. Thermogravimetric analysis of these materials showed that the cleavage of the cyclopentadienyliron (CpFe+) moieties was between 225 and 231 °C, while the degradation of the polymer backbones occurred between 400 and 450 °C. UV-vis studies in DMF showed that the organoiron polymers containing arylazo dyes exhibit wavelength maxima around 425 nm. However, the replacement of these arylazo moieties with hetarylazo dyes displayed substantial bathochromic shifts in the λmax values (≈ 511 nm). 相似文献