Structural, Optical and Electrical Properties of Hydrogen-Doped Amorphous GaAs Thin Films

Amorphous CaAs films are deposited on substrates of quartz glass and sificon by rf magnetron sputtering technique in different gas ambient. First, the amorphous structure of the prepared samples is identified by x-ray diffraction. Second, analysis by radial distribution function and pair correlation function method is established to characterize the microstructure of the samples. Then, the content and bond type of hydrogen are analysed using Fourier transform infrared absorption spectroscopy. It is found that the bonded hydrogen content increases with increasing partial pressure PH of H2. However, the hydrogen content saturates at PH 〉 1 × 10^-1 Pa. Hydrogen addition shills the optical absorption edge to higher energy, decreases the dark conductivity and improves the photo-sensitivity. The optical gap, dark conductivity and photo-sensitivity of the films are dependent on the bonded hydrogen content. These results demonstrate that hydrogen has obvious passivation effects on rf sputtered amorphous GaAs thin films.     

A Continuous-Wave Diode-Side-Pumped Tm:YAG Laser with Output 51W

A compact diode-side-pumped Tm：YAG laser is presented, which can output 51 W of cw power at 2.02 μm. The Tm：YAG rod is side pumped by nine diode arrays with the central wavelength of 783nm and the with bandwidth of about 2.5 nm at 25^o C. To decrease the thermal effect on the both ends and dissipate the heat effectively, one composite Tm：YAG rod with the undoped YAG end caps and the screw threads on the side surface of the rod is used as the laser crystal. The maximum optical-to-optical conversion efficiency of the 2.02-μm laser output is 14.2%, with a slope effciency of 26.8%     

Highly Efficient Diode-Side-Pumped Six-Rod Nd:YAG Laser

We have demonstrated a highly efficient, high average output power laser based on the optimized resonator made up of multiple Nd:YAG rods. The laser consists of three groups, each of which contains two rods with one quartz 90° rotator between them. By a desirable design of the resonator, the average output power of 1906W at 1064nm is reached with repetition rate of 1.1kHz. The optical to optical conversion efficiency is up to 50.8% with the pulse width 224μs and it is the highest conversion efficiency of six rods resonator.     

迹非零的布尔矩阵的广义幂敛指数

设Ｄｎ（ｄ）是恰含ｄ个非零对角元的ｎ阶布尔矩阵的集合,１≤ｄ≤ｎ。本文得到了Ｄｎ（ｄ）中矩阵的广义幂敛指数的最大值。     

土壤和水系沉积物中硒的价态分析方法研究

研究土壤和水系沉积物中硒的价态有助于了解硒(Se)的迁移和转化.目前报道大多只是测定土壤和水系沉积物中部分Se的价态,而如何测定土壤和水系沉积物中全部Se的价态一直是一个难题,难点在于如何将土壤和水系沉积物中的Se消解完全而不改变Se的价态.试验发现6.0 mol·L-1 HCl可以将Se(Ⅵ)还原成Se(Ⅳ);而在室...     

高热稳定性和可逆交联性质的含新型偶氮发色团电光聚合物的研究

制备了两种新型的分别含有以三苯胺为电子给体的偶氮类发色团作为特征活性官能团和3-呋喃甲酸及受保护的马来酰亚胺的可交联型聚合物体系.通过研究表明利用该制备方法,发色团在聚合物中的含量得到了极大的提高,分别达到32 .1 %( NLO1-P1)和44 .4 %( NLO1-P2) .该聚合物体系以"Diels-Alder"[4 +2]环加成反应作为其交联特征,具有高温非交联、低温交联的特点,其过程与以往的热交联型聚合物相反,可解决传统电光交联聚合物中存在的热交联对极化效率影响的问题并用热失重分析法(TGA)和差示扫描量热法(DSC)分析了这一过程.此外DA交联型聚合物,不需要引入额外的助交联剂,克服了传统热交联聚合物分离难的问题,最大程度的保证了材料的纯度.     

气相色谱/质谱法测定食品中甲氧基丙烯酸酯类杀菌剂残留

建立了一种专属、灵敏的气相色谱-质谱分析方法,用于检测水果、蔬菜、饮料、粮谷类、坚果类和肉、蛋、奶类等多种类型食品中嘧菌酯、醚菌胺、嘧蟎酯、氟嘧菌酯、醚菌酯、Z-苯氧菌胺、E-苯氧菌胺、肟醚菌胺、啶氧菌酯、唑菌胺酯和肟菌酯等11种甲氧基丙烯酸酯类杀菌剂残留量。对于不同类型的样品,使用不同有机溶剂对甲氧基丙烯酸酯类杀菌剂进行超声波提取,经凝胶渗透色谱对样品提取液进行净化、富集,采用气相色谱-质谱法以选择离子监测模式进行定性,外标法定量。上述各种杀菌剂在0.05~5.0 mg/kg浓度范围内呈线性,相关系数r>0.99。在空白样品中,添加甲氧基丙烯酸酯类杀菌剂的回收率在60.3%~120.0%之间,精密度(RSD)为1.54%~13.41%。各组分检出限均在0.002~0.015 mg/kg之间。     

n阶非自治Volterra-Lotka竞争系统有界解的存在性和吸引性

本文考察ｎ阶非自治且非周期的Ｖｏｌｔｅｒｒａ－Ｌｏｔｋａ竟争系统，在通常的条件下，证明了这种系统存在一个有正的上、下界的解，而且当ｔ趋向正无穷大时，系统的任何正解都逼近于它．     

简单分歧的迭代解

出于实际的需要,分歧的数值解法一直受到工程界和理论界的注目,从70年代以来,分歧的数值计算已有了很大的发展.由于分歧点的奇异性和非线性性带来的巨大工作量,怎样提高分歧近似解的精度呢?分歧的奇异性使我们不能类似于[10],直接证得其 Galerkin 近似分歧解经过简单迭代就可提高收敛速度.为此,我们先给出一种有高精度近似分歧解的离散格式,进而证明离散 Galerkin 分歧解经过一定的迭代(就微分方程而言,通常再解一次非奇异的线性方程)就可获得更快的收敛速度.为方便起见,先给出几个有关的条件.     

利用金刚石对顶砧超高压装置测量金属高压电阻变化率的实验方法的建立及锰铜高压电阻变化率的测量

本文建立了一个利用金刚石对顶砧超高压装置测量金属高压电阻变化率的实验方法,并用这种方法研究了锰铜的高压电阻变化率,压力达18.5GPa。实验表明:在低于13GPa的压力范围内,锰铜电阻随压力的变化呈一线性关系,在13—18.5GPa的压力范围内则是另一线性关系。在13GPa附近,出现一个线性关系的“转折点”。在“转折点”以下我们测得的压阻系数为0.024GPa^-1与Barsis和Kume以及苏昉等人最新给出的结果都符合得很好。在“转折点”以上,需用新的线性关系来描述,对应的压阻系数为0.020GPa^-1。