Barker码激励超声导波在长骨检测中的应用

单脉冲激励的超声导波在长骨中传播时,信号的衰减大,导致接收信号的幅度很小,且噪声严重。Barker码激励能有效增大接收信号幅度,提高信噪比(SNR)。将其应用到超声导波长骨检测中,进行仿真和长骨实验,得到的信号分别用加权匹配滤波器和有限冲激响应-最小均方误差(FIR-LS)逆滤波器进行压缩,并与单脉冲激励的结果进行了对比。结果表明,对于13位的Barker码,采用加权匹配滤波器进行解码时,压缩信号幅度是单脉冲激励接收信号的13倍;而FIR-LS逆滤波器则达到-63.59 dB的峰值旁瓣水平(PSL),更好地抑制噪声。说明可以将Barker码激励超声导波应用于长骨的检测中。     

超声导波的频散补偿与模式分离算法研究

超声导波已被广泛应用于无损检测与评价,针对超声导波应用中普遍存在的模式混叠与频散问题,本文在采用频谱相位与信号时延函数建模导波频散信号传递系统的基础上,提出了一种单一模式的频散补偿算法。进一步地,通过将选择性频散补偿技术与导波模式分离相结合,本文算法克服了传统补偿算法所不能解决的多模式导波频散问题。板中的Lamb波A0,A1和S0混合模式仿真分析表明,本算法不仅可用于单一导波模式信号合成与频散补偿,而且可在实现多模式混合导波信号选择性频散补偿基础上,解决多模式导波信号中单一模式提取与分离。本文研究有助于超声导波多模式频散信号的分析与处理.     

基于离散随机介质平均散射声功率的无损测温方法

生物组织中超声散射回波的平均功率与其温度有关.该理论包含:(1)生物组织近似为离散随机介质.(2)离散随机介质的平均散射功率与组织的衰减系数α和声速c有关。对于似水生物组织(如:猪肝),当温度升高时,衰减系数的减小使平均散射声功率增加,但其影响大小与时间窗△t有关,而声速的增大则使平均散射声功率减小。实验结果表明:生物组织的平均散射声功率随温度变化趋势明显,该结果提供一种肿瘤热疗无损伤检测温度的新方法。     

骨折长骨中超声导波传播特性的仿真研究

采用超声导波评价长骨骨折已成为近两年来的一个研究热点.本文采用混合边界元方法(HBEM)对超声导波在骨裂长骨中的传播情况以及各导波模式的反射系数和透射系数进行了数值分析.研究结果表明,入射导波模式经由裂纹处模式转换后依然保持为主要接收模式不变.对某一裂纹,各模式透射系数常在相近的频率点上达到局部峰值.对于不同深宽比(d/w)裂纹,某些模式透射系数曲线局部峰值所对应的频率存在着相互错开的现象,这些结果可用于选择最优入射导波模式和频率,以便更好地定量评价骨质以及骨裂状况.     

Hydrothermal Synthesis and Crystal Structure of a Novel Polyoxometalate K(C_4N_2H_(12))_4(C_4N_2H_(11))_(2-)[Mo_8~ⅤMo_4~ⅥCdP_8O_(54)(OH)_8]F·6H_2O

The title compound 1 has been synthesized by the reaction of H_2MoO_4, CdCl_2, H_3PO_4, KF, piperazine hexahydrate and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound crystallizes in the triclinic system, space group P(-1) with a = 14.049(3), b = 15.972(3), c = 20.043(4) (A), α = 85.82(3), β = 81.28(3),γ = 67.15(3)°, V= 4095.9(14) (A)~3, M_r = 3204.62, Z=2,D_c = 2.598 g/cm~3,μ = 2.360 mm~(-1), F(000) = 3124, the final R = 0.0314, wR = 0.0826 and S = 0.989 for 18592 observed reflections with I > 2σ(I). The crystal packing is stabilized by N-H…O and O-H…O intra- and intermolecular hydrogen bonds to form an infinite 3D network.     

A Simple and Rapid Label-free Fluorimetric “Turn Off-on” Sensor for Cadmium Detection Using Glutathione-capped CdS Quantum Dots

A convenient label-free fluorescence(FL) nanoprobe for rapid detection of cadmium(Cd) was established using glutathione-capped CdS quantum dots(QDs) and 1,10-phenanthroline(phen). The prepared CdS QDs exhibited a strong FL emission at 536 nm, which could be quenched by phen due to the photoinduced hole transfer(PHT) mechanism. The existence of Cd effectively recovered the FL intensity of CdS QDs, which was due to the easy detachment of phen from the surface of QDs to form[Cd(phen)₂(H₂O)₂]²⁺ in solution. Cd concentrations were linearly correlated with the FL intensity in the range of 0.0625-1.25 μmol/L under the optimized conditions and the detection limit was 0.01 μmol/L. Finally, the Cd concentration was accurately quantified in real water sample using the proposed sensor.     

Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: Synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF4 and [Pt(AMP)(dmso)Cl]ClO4

Treatment of [M(AMP)Cl₂] (M = Pt^II, Pd^II; AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO₄, BF₄, PF₆) in dmso yields [M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the Pd^II and Pt^II complexes indicate that dmso is S-bondedtrans to the pyridyl ring in both complexes. (2-Aminomethylpyridine)chloro(dimethylsulphoxide-S) palladium(II) tetrafluoroborate.     

纳米尺度CeO2在多相催化反应中的形貌效应

CeO2的催化性能不仅与粒子大小有关,而且与其形貌密切相关. 本文分析了CeO2的纳米结构和氧化还原特性,综述了CeO2在催化反应中的形貌效应,着重介绍了CeO2的结构和形貌对CO氧化、水气变换和乙醇水蒸气重整制氢以及二元醇脱水反应活性的影响.