全文获取类型
收费全文 | 2253篇 |
免费 | 162篇 |
国内免费 | 9篇 |
专业分类
化学 | 1572篇 |
晶体学 | 25篇 |
力学 | 68篇 |
数学 | 270篇 |
物理学 | 489篇 |
出版年
2023年 | 17篇 |
2022年 | 105篇 |
2021年 | 76篇 |
2020年 | 56篇 |
2019年 | 88篇 |
2018年 | 68篇 |
2017年 | 49篇 |
2016年 | 115篇 |
2015年 | 76篇 |
2014年 | 83篇 |
2013年 | 168篇 |
2012年 | 139篇 |
2011年 | 129篇 |
2010年 | 96篇 |
2009年 | 93篇 |
2008年 | 109篇 |
2007年 | 122篇 |
2006年 | 107篇 |
2005年 | 80篇 |
2004年 | 69篇 |
2003年 | 56篇 |
2002年 | 55篇 |
2001年 | 51篇 |
2000年 | 37篇 |
1999年 | 30篇 |
1998年 | 16篇 |
1997年 | 16篇 |
1996年 | 16篇 |
1995年 | 15篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 9篇 |
1988年 | 7篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 23篇 |
1983年 | 14篇 |
1982年 | 7篇 |
1981年 | 12篇 |
1980年 | 18篇 |
1979年 | 10篇 |
1978年 | 14篇 |
1977年 | 11篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1973年 | 8篇 |
1862年 | 8篇 |
排序方式: 共有2424条查询结果,搜索用时 15 毫秒
81.
82.
Rosenani A. Haque Abbas Washeel Salman Srinivasa Budagumpi Amirul Al‐Ashraf Abdullah Zena A. Abdul Hameed Al‐Mudaris Amin M. S. Abdul Majid 《应用有机金属化学》2013,27(8):465-473
A series of Ag(I) complexes ( 6 , 7 , 8 , 9 ) derived from imidazol‐2‐ylidenes was synthesized by reacting Ag2O with an o‐, m‐, p‐xylyl or 1,3,5‐triazine‐linked imidazolium salts ( 1 , 2 , 3 , 4 ) and then characterizing these using various spectro‐analytical techniques. Additionally, triazine‐linked bis‐imidazolium salt 5 was characterized using the single‐crystal X‐ray diffraction method. Complexes 6–9 were formed from the N‐heterocyclic carbene ligand precursors 1–3 as PF6‐ salts in good yields. Conversely, salt 5 does not form Ag(I) complex even under various reaction conditions. Using ampicillin as a standard, complexes 6–9 were tested against bacteria strains Escherichia coli and Staphylococcus aureus as Gram‐negative and Gram‐positive bacteria, respectively, showing potent antimicrobial activities against the tested bacteria even at minimum inhibition concentration and bacterial concentration levels. Furthermore, the potential anticancer activities of the reported complexes were evaluated against the human colorectal cancer (HCT 116) cell lines, using 5‐fluorouracil as a standard drug. The highest anticancer activities were observed for complex 8 with an IC50 value of 3.4 μm , whereas the lowest was observed for complex 9 with an IC50 value of 18.1 μm . Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
83.
There has been a considerable interest in recent years in developing polymer gel matrices for many important applications such as 2DE for quantization and separation of a variety of proteins and drug delivery system to control the release of active agents. However, a well‐defined knowledge of the ultrastructures of the gels has been elusive. In this study, we report the characterization of two different polymers used in 2DE: Gelatin, a naturally occurring polymer derived from collagen (protein) and agar, a polymer of polysaccharide (sugar) origin. Low‐temperature SEM is used to examine the internal structure of these gels in their frozen natural hydrated states. Results of this study show that both polymers have an array of hollow cells that resembles honeycomb structures. While agar pores are almost circular, the corresponding Gaussian curve is very broad exhibiting a range of radii from nearly 370 to 700 nm. Gelatin pores are smaller and more homogeneous reflecting a narrower distribution from nearly 320 to 650 nm. Overall, these ultrastructural findings could be used to correlate with functions of the polymers. 相似文献
84.
85.
86.
87.
88.
Cover Picture: Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports (Angew. Chem. Int. Ed. 25/2016)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Han Zhang Prof. Qiang Xiao Prof. Xianghai Guo Prof. Najun Li Prashant Kumar Neel Rangnekar Mi Young Jeon Prof. Shaeel Al‐Thabaiti Prof. Katabathini Narasimharao Prof. Sulaiman Nasir Basahel Prof. Berna Topuz Frank J. Onorato Prof. Christopher W. Macosko Prof. K. Andre Mkhoyan Prof. Michael Tsapatsis 《Angewandte Chemie (International ed. in English)》2016,55(25):7009-7009
89.
90.
Mahmoud Al‐Ktaifani Mwaffak Rukiah 《Acta Crystallographica. Section C, Structural Chemistry》2012,68(9):m246-m250
In order to explore the potential propensity of the 1,1′‐methylenedipyridinium dication to form organic–inorganic hybrid ionic compounds by reaction with the appropriate halide metal salt, the organic–inorganic hybrid salts 1,1′‐methylenedipyridinium tetrachloridocuprate(II), (C11H12N2)[CuCl4], (I), and 1,1′‐methylenedipyridinium bis[tetrachloridoaurate(III)], (C11H12N2)[AuCl4]2, (II), were obtained by treatment of 1,1′‐methylenedipyridinium dichloride with CuCl2 and Na[AuCl4], respectively. Both hybrid salts were isolated as pure compounds, fully characterized by multinuclear NMR spectroscopy and their molecular structures confirmed by powder X‐ray diffraction studies. The crystal structures consist of discrete 1,1′‐methylenedipyridinium dications and [CuCl4]2− and [AuCl4]− anions for (I) and (II), respectively. As expected, the dications form a butterfly shape; the CuII centre of [CuCl4]2− has a distorted tetrahedral configuration and the AuIII centre of [AuCl4]− shows a square‐planar coordination. The ionic species of (I) and the dication of (II) each have twofold axial symmetry, while the two [AuCl4]− anions are located on a mirror‐plane site. Both crystal structures are stabilized by intermolecular C—H...Cl hydrogen bonds and also by Cl...π interactions. It is noteworthy that, while the average intermolecular centroid–centroid pyridinium ring distance in (I) is 3.643 (8) Å, giving strong evidence for noncovalent π–π ring interactions, for (II), the shortest centroid–centroid distance between pyridinium rings of 5.502 (9) Å is too long for any significant π–π ring interactions, which might be due to the bulk of the two [AuCl4]− anions. 相似文献