Kinetics of interaction of Histidine and Histidine Methyl Ester with Ninhydrin in micellar media

Kinetics of the interaction of histidine and histidine methyl ester with ninhydrin under varying concentrations of reactants, anionic (sodium dodecyl sulphate, SDS), cationic (cetyltrimethylammonium bromide, CTAB) and non‐ionic (Triton X‐100, TX‐100) micelles have been carried out. Rate of the reaction was found to be independent of the initial concentration of histidine (and histidine methyl ester) but was dependent on [Ninhydrin]. The SDS micelles had no effect on the rate of the reaction. In the presence of the CTAB micelles a small enhancement in the rate was observed. The rate − [CTAB] profile showed that the increase in [CTAB] increased the rate up to a maximum value and a further increase had a decreasing effect on the rate. The rate was enhanced by TX‐100 also but, unlike CTAB micelles, TX‐100 possessed a curve without peak for the rate − [TX‐100] profile. The following rate equation was obeyed by the reaction in CTAB and TX‐100 micelles: Values of k_w, k_m, and K_S were evaluated and are reported herein. ©1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 103–111, 1999     

Localization and dephasing driven by magnetic fluctuations in low carrier density colossal magnetoresistance materials

Localization and dephasing of conduction electrons in a low carrier density ferromagnet due to scattering on magnetic fluctuations is considered. We claim the existence of the “mobility edge”, which separates the states with fast diffusion and the states with slow diffusion; the latter is determined by the dephasing time. When the “mobility edge” crosses the Fermi energy a large and sharp change of conductivity is observed. The theory provides an explanation for the observed temperature dependence of conductivity in ferromagnetic semiconductors and manganite pyrochlores. Received 17 January 1999 and Received in final form 12 March 1999     

Optimal domain decomposition via -median methodology using ACO and hybrid ACGA

In this paper an efficient method is developed for decomposing large-scale finite element meshes. A weighted incidence graph is used to transform the connectivity properties of finite element models into those of graphs. A graph G_c of manageable size is obtained from the main graph model by a coarsening algorithm. The p-medians of this graph are selected using two approaches. The first algorithm uses an ant colony optimization and the second algorithm employs a hybrid ant colony together with genetic algorithm. Here, p is the number of subdomains which the finite element meshes is intended to be decomposed. Once the medians are obtained, the nodes in G_c associated with each median are selected. In an expansion process, the nodes of the subdomains in G are obtained. The capabilities of both ant colony optimization, and hybrid ant colony and genetic algorithm are evaluated using many examples of different topology.     

Statistics of waves propagating in a random medium

We present a review of part of the results obtained by the authors for the statistics of coherent radiation propagating in a random medium both in the framework of diagrammatic techniques and random matrix theory. Distribution functions for the total transmission coefficient and the angular transmission coefficient for the diffusive transport and the crossover between the diffusive and ballistic regimes are obtained.The authors acknowledge the financial support of the Israeli Academy of Sciences and of the Schottenstein Center.     

Role of the phonon trial function in determining the phonon-drag contribution to the low-temperature electrical resistivity

It is demonstrated that there is excellent agreement between the low-temperature electrical resistivity data for potassium and the Bailyn formulation for the phonon-drag electrical resistivity, which is based on a consistent solution for the phonon trial function in terms of the electron trial function.     

p-Frames and Shift Invariant Subspaces of Lp

In this article we investigate the frame properties and closedness for the shift invariant space V_p(F) = { ?_i=1^r ?_{j ? \Zd} d_i(j) f_i (·-j):  ( d_i(j) )_{j ? \Zd} ? l^p }, \q 1 ￡ p ￡ ￥ . \displaystyle V_p(\Phi) = \left\{ \sum_{i=1}^r \sum_{j\in \Zd} d_i(j) \phi_i (\cdot-j): \ \left( d_i(j) \right)_{j\in \Zd}\in \ell^p \right\}, \q 1\le p \le \infty~. We derive necessary and sufficient conditions for an indexed family {f_i(·-j): 1 ￡ i ￡ r, j ? \Zd}\{\phi_i(\cdot-j):\ 1\le i\le r, j\in \Zd\} to constitute a pp-frame for V_p(F)V_p(\Phi), and to generate a closed shift invariant subspace of L^pL^p. A function in the L^pL^p-closure of V_p(F)V_p(\Phi) is not necessarily generated by l^p\ell^p coefficients. Hence we often hope that V_p(F)V_p(\Phi) itself is closed, i.e., a Banach space. For p 1 2p\ne 2, this issue is complicated, but we show that under the appropriate conditions on the frame vectors, there is an equivalence between the concept of pp-frames, Banach frames, and the closedness of the space they generate. The relation between a function f ? V_p(F)f \in V_p(\Phi) and the coefficients of its representations is neither obvious, nor unique, in general. For the case of pp-frames, we are in the context of normed linear spaces, but we are still able to give a characterization of pp-frames in terms of the equivalence between the norm of ff and an l^p\ell^p-norm related to its representations. A Banach frame does not have a dual Banach frame in general, however, for the shift invariant spaces V_p(F)V_p(\Phi), dual Banach frames exist and can be constructed.     

Determination of uranium contents in rock samples from Kakul phosphate deposit, Abbotabad (Pakistan), using fission-track technique

Some times high uranium contents are present in the phosphate rocks used for the manufacturing of fertilizer. In view of the harmful effects on human health due to the processing and use of such fertilizers in agriculture, it is important to analyse phosphate rocks for uranium content determination. Ten representative rock samples from Kakul phosphate deposit exposed near Abbotabad, Pakistan which are used for the manufacturing of fertilizers were studied for uranium content determination with the help of fission track and neutron activation analysis techniques. Each sample was split into three parts. The first and second parts (solid slabs and pellets) were subjected to fission track analysis, while the third part was analysed using neutron activation analysis technique for comparison. On the average a uranium content of 37 ppm was found in the phosphate rocks. The results of uranium content determinations with the help of fission track and neutron activation analysis techniques show a remarked resemblance up to ±0.1%. This indicates that the fission track analysis technique of uranium content determination is a reliable method inspite of its simplicity. The uranium content in the Kakul deposits is within the permissible limit allowed for the mining and processing of the phosphate rocks for the manufacturing of fertilizers.     

Green formulation and chemical characterization of Lens culinaris seed aqueous extract conjugated gold nanoparticles for the treatment of acute myeloid leukemia in comparison to mitoxantrone in a leukemic mouse model

The high prevalence of cancer has been increased the rate of studying about the new formulation of chemotherapeutic drugs. In this regards, one of the suitable options is the use of metal nanoparticles for formulating these drugs. In the recent study, Lens culinaris seed aqueous extract conjugated gold nanoparticles (AuNPs) are reported for the first time to exert a dietary therapeutic potential compared to mitoxantrone in an animal model of acute myeloid leukemia. The synthesized AuNPs were characterized using different techniques including UV–Vis., FT-IR, XRD, FE-SEM, and TEM. DPPH free radical scavenging test was done to evaluate the antioxidant potentials of HAuCl₄, L. culinaris, AuNPs, and mitoxantrone. For the analyzing of cytotoxicity effects of HAuCl₄, L. culinaris, AuNPs, and mitoxantrone, MTT assay was used on HUVEC, 32D-FLT3-ITD, Human HL-60/vcr, and Murine C1498 cell lines. In vivo assay, induction of acute myeloid leukemia was done by 7,12-Dimethylbenz[a]anthracene (DMBA) in 75 mice. Then, the animals were randomly divided into six subgroups, including control, untreated, HAuCl₄, L. culinaris, AuNPs, and mitoxantrone. SEM and TEM images showed uniform spherical morphology and average diameters of 10–40 nm for the nanoparticles. DPPH test revealed similar antioxidant potentials for mitoxantrone and AuNPs. Similar to mitoxantrone, AuNPs had low cell viability dose-dependently against 32D-FLT3-ITD, Human HL-60/vcr, and Murine C1498 cell lines without any cytotoxicity on HUVEC cell line. AuNPs and mitoxantrone significantly (p ≤ 0.05) reduced the weight and volume of liver and spleen, the pro-inflammatory cytokines, and the total WBC, blast, neutrophil, monocyte, eosinophil, and basophil counts and increased the mRNA expression of Sphingosine-1-phosphate receptor-1 and Sphingosine-1-phosphate receptor-5, the anti-inflammatory cytokines, and the lymphocyte, platelet, and RBC parameters as compared to the untreated mice. It looks that AuNPs can be administrated as a chemotherapeutic supplement or drug for the treatment of acute myeloid leukemia in the clinical trial.     

Free-Standing CoO-POM Janus-like Ultrathin Nanosheets

A single-step solution-based strategy is used to obtain 2D Janus-like free-standing ultrathin nanosheets build from two structurally unrelated species, that is, polyoxomolybdate (POM) and CoO. A controlled 2D-to-1D morphological transition was achieved by judiciously adjusting the solvent choice. These POM-CoO heterostructures can behave as an ideal catalyst for the epoxidation of styrene. Benefiting from their amphiphilic nature, these 2D POM-CoO nanosheets have also been used as surfactant to emulsify immiscible solvents. It is anticipated that structurally diverse polyoxometalates will offer promise as design elements for variety of structurally and compositionally tunable van der Waals integrated heteromaterials having a broad range applications.