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61.
Imamura A Kimura A Ando H Ishida H Kiso M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(34):8862-8870
The high versatility of di-tert-butylsilylene(DTBS)-directed alpha-predominant galactosylation have been extended to the construction of difficult glycan sequences. First, to investigate the compatibility of the alpha-predominant reaction with various glycosylation systems a variety of 4,6-O-DTBS-tethered galactosaminyl or galactosyl donors were synthesized efficiently, which have C2-participating groups with a wide variety of leaving groups such as alkylsulfenyl, halide, trichloroacetimidate groups. The results of the detailed examination of the glycosylation reaction using the glycosyl donors showed the wide scope of the 4,6-DTBS-directed alpha-galactosylation. In the next step, the stereoselective construction of alpha-GalN-Ser/Thr sequences was examined by employing the DTBS-directed glycosylation. As a result, various types of serine and threonine derivatives were glycosylated alpha-selectively, producing alpha-GalN-Ser/Thr sequences in high yields. Moreover, the DTBS-directed galactosylation was successfully applied for the synthesis of alpha-tetrasaccharyl-Ser segment of glycophorin A. 相似文献
62.
Orito K Miyazawa M Nakamura T Horibata A Ushito H Nagasaki H Yuguchi M Yamashita S Yamazaki T Tokuda M 《The Journal of organic chemistry》2006,71(16):5951-5958
A phosphine-free catalytic system [Pd(OAc)2-Cu(OAc)2-air] induced a substrate-specific carbonylation of amines in boiling toluene under CO gas (1 atm). Symmetrical N,N'-dialkylureas were obtained by the carbonylation of primary amines. N,N,N'-Trialkylureas were selectively formed by addition of a secondary amine to the above reaction vessel. Secondary amines did not give tetraalkylureas. However, dialkylamines with a phenyl group on their alkyl chains, such as N-monoalkylated benzylic amine or phenethylamine derivatives, underwent a direct aromatic carbonylation to afford five- or six-membered benzolactams. In the carbonylation, the chelation effect or steric repulsion between Pd(II) and the meta-substituent in the ortho-palladation and the ring sizes of cyclopalladation products that were formed prior to carbonylation were found to generate good site selectivity and increase the reaction rate. In contrast, carbonylation of omega-arylalkylamines with a hydroxyl group gave neither ureas nor benzolactams but instead produced 1,3-oxazolidinones smoothly. Hydrochlorides of amines also underwent carbonylation to afford the corresponding amides under the conditions used. This procedure made it possible to prepare ureas of amino acid esters and N-alkylcarbamates in practical yields. 相似文献
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65.
Shinji Takemoto Kanji Tsuru Satoshi Hayakawa Akiyoshi Osaka Seisuke Takashima 《Journal of Sol-Gel Science and Technology》2001,21(1-2):97-104
We examined blood compatibility of titania gels prepared through a sol-gel processing or yielded on titanium substrates by treating with hydrogen peroxide or simple heating. The blood compatibility was evaluated in terms of blood clotting time and correlated to the crystalline phases, roughness, specific surface area, and wettability. The sol-gel derived titania gel heated above 200°C had good blood compatibility. Ti substrate treated with hydrogen peroxide and subsequently heated at 550°C showed the best blood compatibility among the Ti substrates with or without the chemical treatment and heat-treatment. The specimen consisted of rutile and anatase phases, and had hydrophilic surface. 相似文献
66.
A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system 总被引:1,自引:0,他引:1
Kawanami H Sasaki A Matsui K Ikushima Y 《Chemical communications (Cambridge, England)》2003,(7):896-897
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported. 相似文献
67.
Akiyoshi Osaka Motokazu Yuasa Yoshinari Miura Katsuaki Takahashi 《Journal of Non》1988,100(1-3):409-412
A sodium borosilicate gel of composition 80SiO2·15B2O3·5Na2O (wt%) was prepared from tetraethyl orthosilicate, trimethyl borate, sodium methylate, H2O, and HCl as the catalyst. Variation of specific surface area and porosity as a function of heating temperature indicated that closed pores were opened at temperatures lower than 400°C and collapsed above 450°C. From TG and DTA curves, about 19% Si and B atoms are evaluated to have −OH bonds. X-ray diffraction patterns indicated crystallization of low-cristobalite out of the gel when it was heated at 700°C for 5 h, showing a difference from a melt-quenched glass of the same composition. 相似文献
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The CTA film can be characterized by e.g. its relatively high moisture regain, significantly low birefringence, and moderate mechanical strength. Having been commercialized more than fifty years ago, it has been widely used as photographic film, protective film for polarizing plate, and optical compensation film for liquid crystal display (LCD). The photographic film application exploits the optical isotropy and unique physical properties of the CTA film. In the application of the CTA film to protective film for polarizing plate, its low in-plane birefringence is of particular importance. In the optical compensation to enhance the viewing angle of LCD, the CTA film, because of its moderate retardation in thickness direction (Rth), serves as an element of compensator as well as a base film. Considering the growth of the LCD market, the demand for CTA film is believed to be further expanding. 相似文献
70.
Akira Matsumoto Akiyoshi Ueda Hiroyuki Aota Jun‐ichi Ikeda 《Macromolecular rapid communications》2000,21(10):701-703
The preliminary study of the effect of physical crosslinking on the gelation in monovinyl/divinyl copolymerizations is described. Thus, mono(2‐methacryloyloxyethyl) succinate was added to the crosslinking copolymerization of butyl methacrylate with 1,6‐hexanediol dimethacrylate and the gelation was explored in terms of the effect of hydrogen bonds formed between carboxyl groups introduced into the primary polymer chain. 相似文献