Facile and convenient synthesis of 2,6-disubstituted 4H-1,3-oxazin-4-one derivatives

Facile and convenient methods for the preparation of a variety of 2,6-disubstituted 4H-1,3-oxazin-4-ones 3 by three complementary methods are described. Treatment of the branched aliphatic imidate 2c,d with diketene 1 in the presence of a catalytic amount of acetic acid affords 2-substituted 6-methyl-1,3-oxazin-4-ones 3c,d , whereas the unbranched imidate 2b,e gave oxazines 3b,e and pyrimidines 4b,e (Method A). The reaction of acyl Meldrum's acid 5 with imidate 2 afford 2,6-disubstituted oxazine 3, though the alkylimidate with acetyl Meldrum's acid yielded 3 and 5-acetyl-1,3-oxazine-4,6-dione 8 (Method B). The cylodehydration of acylacetylcarboxamide 13 with acid, such as 70% perchloric acid or fluorosulfonic acid, afforded 1,3-oxazines 3 (Method C).     

Drawing behavior and characteristics of laser‐drawn polypropylene fibers

Drawing behavior, flow drawing, and neck drawing, was studied for isotacticpolypropylene fibers in CO₂ laser drawing system, and the fiber structure and the mechanical properties of drawn fibers were analyzed. For a certain laser power, flow drawing of polypropylene (PP) was possible up to draw ratio (DR) 19.5. Though the drawing stress was very low, the flow‐drawn PP fiber exhibited oriented crystal structure and improved mechanical properties. On the other hand, neck‐drawing was accomplished from DR 4 to 12, with significant increase in drawing stress that enhanced the development of fiber structure and mechanical properties. Unlike PET, the drawing stress depends not only on the DR, but on irradiated laser power also. The 10–12 times neck‐drawn fibers were highly fibrillated. The fibers having tensile strength 910 MPa, initial modulus 11 GPa, and dynamic modulus 14 GPa were obtained by single‐step laser drawing system. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 398–408, 2006     

Investigation of molecular motions of crosslinked polyepichlorohydrin by nuclear magnetic resonance spectroscopy

The molecular motion of crosslinked polyepichlorohydrin (PECH) is studied qualitatively by NMR techniques. The results of temperature dependence of ¹H T₂ and T₁ indicate that the crosslinking (crosslink density < 3%) restricts molecular motions of the polymer even far above its T_g. The ¹H T₁ minimum, corresponding to the large-scale chain-motion of crosslinked PECH, shifts to higher temperatures with increasing crosslink density. ¹H T₂ data also show that the crosslinking hinders free chain motions of the polymer above its T_g. The ¹³C T₁ relaxation time is sensitive to such motional changes as well. ¹³C linewidths of crosslinked PECHs vary with the crosslink density in both the swollen state and the solid state. The mechanism of ¹³C linewidth broadening of crosslinked polymers is discussed in detail. In the case of PECH, the linewidth broadening is caused by changing molecular environment due to crosslinking (such as presence of various chemical shift structures and freezing effects in conformational environment as chain mobility decreases), rather than increasing correlation times, which shorten the relaxation time (T₂) of polymer chains. © 1994 John Wiley & Sons, Inc.     

Gate-voltage dependence of zero-bias anomalies in multiwall carbon nanotubes

Temperature dependence of zero-bias conductance of the vanadium (V)/multiwall carbon nanotube (MWNT)/V structure is studied. As temperature is reduced, the conductance decreases with a functional form consistent with a power law. For the first time, we find that the exponent depends significantly on gate voltage. This exponent dependence cannot be explained by Luttinger-liquid theory for ballistic MWNTs. We interpret the obtained results within the framework of the nonconventional Coulomb blockade theory for strongly disordered MWNTs.     

Ionization of long-lived highly excited atoms by collision with molecules. II

A theoretical treatment of the collisional ionization of a highly excited atom with a molecule is improved by use of the exact form factor of the hydrogen atom in highly excited states. The present treatment is still based on the previously proposed mechanism in which the Rydberg electron is ionized by gain of energy from rotational de-excitation of the molecule in a rotationally excited state. Closer comparison of experiment with theory is made for symmetric- as well as asymmetric-top molecules.     

Mechanische Denaturierung von Hochpolymeren in L?sung. 33. Mitt. Einflu? von Antischaumreagentien auf die flie?induzierte Kristallisation von Polyvinylalkohol aus dessen w?llriger L?sung

Ohne Zusammenfassung     

Mechanische Denaturierung von Hochpolymeren in Lösung. 33. Mitt. Einfluß von Antischaumreagentien auf die fließinduzierte Kristallisation von Polyvinylalkohol aus dessen wällriger Lösung

Ohne Zusammenfassung     

A Payne�CRayner Type Inequality for the Robin Problem on Arbitrary Minimal Surfaces in {\mathbb{R}^N}

We prove a Payne?CRayner type inequality for the first eigenfunction of the Laplacian with Robin boundary condition on any compact minimal surface with boundary in ${\mathbb{R}^N}$ . We emphasize that no topological condition is necessary on the boundary.