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51.
Kouhei Hatanaka Shigeo Tanimoto Toyonari Sugimoto Masaya Okano 《Tetrahedron letters》1981,22(34):3243-3244
It has been found that the reaction of enol silyl ethers with 2-ethoxy-1,3-dithiolane proceeds smoothly in the presence of zinc chloride catalyst to afford half-protected 1,3-dicarbony1 compounds in moderately good yields. 相似文献
52.
S. Tanimoto 《Journal of Optimization Theory and Applications》1980,31(3):331-342
For a convex-concave functionL(x, y), we define the functionf(x) which is obtained by maximizingL with respect toy over a specified set. The minimization problem with objective functionf is considered. We derive necessary conditions of optimality for this problem. Based upon these necessary conditions, we define its dual problem. Furthermore, a duality theorem and a converse duality theorem are obtained. It is made clear that these results are extensions of those derived in studies on a class of nondifferentiable mathematical programming problems.This work was supported by the Japan Society for the Promotion of Sciences. 相似文献
53.
Takahiko Ishiguro Ei-ichiro Suzuki Akiko Y. Hirakawa Masamichi Tsuboi 《Journal of Molecular Spectroscopy》1980,83(2):360-372
Raman spectra of thiourea have been observed in H2O and D2O solutions with the exciting laser beams of 514.5, 488.0, 457.9, 363.8, 325.0, and 257.3 nm. The resonance Raman excitation profile of the 729-cm?1 line has been examined in the region of the 237-nm absorption band () by use of a solvent shift of the absorption band instead of by changing the wavelength of the exciting beam. The depolarization degree of this line was measured and its overtone Raman line was also observed. On the basis of the results of these experiments, it has been concluded that the 729-cm?1 Raman line, assignable to the CS stretching vibration, derives its intensity solely from the 237-nm band when it is excited at 257.3 or 325.0 nm. On exciting in the region 363.8–514.5 nm, however, contributions of the higher-frequency bands are predominant rather than the contribution from the 237-nm band. The Raman line at 1520 cm?1 of thiourea-d4 is assignable to the NCN antisymmetric stretching vibration. From its excitation profile, its intensity has been considered to come from a vibronic coupling between the excited electronic states of the 220-nm () and the 197-nm () bands. 相似文献
54.
55.
I. V. Blokhin A. S. Markosyan R. B. Morgunov K. Inoue Y. Tanimoto Y. Yoshida 《Physics of the Solid State》2005,47(11):2106-2113
The variations in the magnetic resonance spectra accompanying the transition from the paramagnetic to ferrimagnetic state in [{Cr(CN)6} {Mn(S)-pnH-(H2O) }] · H2O orthorhombic chiral molecular crystals were studied. The dependence of the EPR linewidth on temperature in the proximity of the transition point TC = 38 K argues for the two-dimensional character of spin ordering. The spin resonance line was found to undergo exchange narrowing at T > TC. The ferrimagnetic phase has an easy magnetization axis coinciding with the a crystallographic axis. 相似文献
56.
57.
Katoh K Okabayashi T Tanimoto M Sumiyoshi Y Endo Y 《The Journal of chemical physics》2004,120(17):7927-7932
The rotational spectra of the CrF and CrCl radicals in the X 6Sigma+ state were observed by employing a Fourier transform microwave spectrometer. The CrF and CrCl radicals were generated by the reaction of laser-ablated Cr with F2 and Cl2, respectively, diluted in Ar. A chromium rod made of chromium powder pasted with epoxy resin was ablated by a Nd:YAG laser. Rotational transitions were measured in the region between 8 and 26 GHz. Several hyperfine constants due to the halogen nuclei were determined by a least-squares analysis. The electronic properties of CrF and CrCl were derived from their hyperfine constants and were compared with those of other 3d transition metal monohalides: TiF, MnF, FeF, CoF, NiF, and FeCl. 相似文献
58.
A new low-coherence interferometric technique is proposed for measuring the group refractive indices of dispersive samples with high accuracy. A tandem configuration of interferometers is used to compensate for the asymmetrical distortion of interferograms that results from the broad spectrum of the light source. The group refractive index can be measured without knowledge of the geometrical thickness of the sample under test. The proposed technique can successfully measure even a thick sample. Computer calculations have shown the effectiveness of the proposed technique, which was verified by preliminary experiments; the difference between the experimental result and the catalog data was 7 x 10(-4). 相似文献
59.
Hong FL Minoshima K Onae A Inaba H Takada H Hirai A Matsumoto H Sugiura T Yoshida M 《Optics letters》2003,28(17):1516-1518
A frequency comb spanning more than one octave has been achieved by injecting the second-harmonic generation (780 nm) of a mode-locked fiber laser (1.56 microm) into a photonic crystal fiber. We propose and realize a novel interferometric scheme for observing the carrier-envelope offset frequency of the frequency comb. Frequency noise has been observed on the measured carrier-envelope offset frequency, which has been confirmed to be generated in the photonic crystal fiber by comparing the measured beat frequencies between cw lasers and frequency combs before and after the photonic crystal fiber. The mode-locked fiber laser is considered to be an important candidate for the light source used in realizing a compact optical frequency measurement system including applications in the telecommunication bands. 相似文献
60.
Gold nanowires were synthesized at 150 K by electron beam thinning of a gold thin foil in an UHV electron microscope. The gold nanowires were found to have a helical multishell structure (HMS). One particular nanowire, which was thinner than the 7-1 HMS nanowire, was found to have a tubular structure. The gold single wall nanotube is composed of five atomic rows that coil about the tube axis. The diameter was 0.4 nm and the pitch was 11 nm. The stability of the (5,3) nanotube was discussed in terms of the shear deformation of the triangular network of gold atoms. 相似文献