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排序方式: 共有106条查询结果,搜索用时 218 毫秒
71.
Kakehi A Ito S Suga H Miwa T Mori T Fujii T Tanaka N Kobayashi T 《Chemical & pharmaceutical bulletin》2003,51(1):75-84
Various ethyl 1-arylcarbonyl-3-[(un)substituted methylthio]thieno[3,4-b]indolizine-9-carboxylates were synthesized in good yields by a novel methodology in which the S-alkylation of 5-arylcarbonyl-4-ethoxycarbonylmethyl-3-(1-pyridinio)thiophene-2-thiolates with alkyl or benzyl halides, the 1,5-dipolar cyclization of the resulting pyridinium salts in the presence of a base, and the aromatization were performed. In the X-ray analyses of some 3-(benzylthio)thieno[3,4-b]indolizine-9-carboxylates, a gauche and two anti conformers in relation to the exocyclic sulfide linkage were found. Interestingly, all of the 3-(benzylthio)thieno[3,4-b]indolizine derivatives showed significant high-field shifts (delta up to 0.3 ppm) for the 5- and 6-proton signals compared with those of the 3-methylthio derivatives in the (1)H-NMR spectra and exhibited a definite absorption band near 425 nm in their UV spectra, indicating an intramolecular arene-arene interaction between the thieno[3,4-b]indolizine and the phenyl ring. 相似文献
72.
Masashi ShiraiHidekazu Kuwabara Satoshi MatsumotoHidetoshi Yamamoto Akikazu KakehiMichihiko Noguchi 《Tetrahedron》2003,59(23):4113-4121
A facile oxime-nitrone isomerization through the 1,2-hydrogen shift in 4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carbaldehyde oximes is discussed. The resultant NH-nitrones are trapped by maleimides to afford intermolecular cycloadducts. The reaction of the oximes with electron-deficient acetylenes undergoes via another path initiated by a nucleophilic attack of the oxime to acetylene moiety. 相似文献
73.
Akikazu Matsumoto Kenichi Yamagishi Shuzo Aoki 《Journal of polymer science. Part A, Polymer chemistry》1994,32(5):917-928
Radical polymerizations of methyl methacrylate (MMA), styrene (St), and vinyl acetate (VAc) were carried out in the presence of a novel phenyl acrylate derivative bearing a hindered phenol moiety (HPA). It has been clarified that HPA acts as a retarder and inhibitor for the polymerizations of MMA and VAc, respectively, and that in the polymerization of St it behaves as a monomer to give a copolymer. These additive effects were interpreted in terms of intramolecular transfer of the phenolic hydrogen in competition with propagation of the HPA radical to monomers. © 1994 John Wiley & Sons, Inc. 相似文献
74.
Toru Doi Akikazu Matsumoto Takayuki Otsu 《Journal of polymer science. Part A, Polymer chemistry》1994,32(15):2911-2918
Polymerization of methyl acrylate (MA) with benzyl N, N-diethyldithiocarbamate (BDC) was carried out in bulk or in benzene under UV irradiation. The polymerization proceeded to give a high yield of polymer, however it was found that BDC did not function as an iniferter in the MA polymerization. Bimolecular termination leading to deactivation of the iniferter site was observed during the polymerization in preference to chain transfer and primary radical termination which reproduce the iniferter site. The deactivation was successfully prevented by combining BDC and tetraethylthiuram disulfide (TD) as a two-component iniferter. This two-component iniferter system was also applied to synthesis of a star polymer with 1,2,4,5-tetrakis (N,N-diethyldithocarbamylmethyl) benzene (DDC) as a tetrafunctional photoiniferter. © 1994 John Wiley & Sons, Inc. 相似文献
75.
4-Acetoxytricyclo[4.1.0.02,7]hept-4-en-3-one (), a valence isomer of 2-acetoxytropone, was synthesized. Upon heating in pyridine at 150°C, rearranged into 1-acetoxybicyclo[3.2.0]hepta-3,6-dien-2-one (); the mechanism of which was examined by means of deuterium labeling experiments. 相似文献
76.
Hiroyuki Watanabe Akikazu Matsumoto Takayuki Otsu 《Journal of polymer science. Part A, Polymer chemistry》1994,32(11):2085-2091
Two kinds of itaconamic esters, α-substituted acrylate derivatives (IAE-I) and α-substituted acrylamide derivatives (IAE-II), as well as itaconamides (IAm) were prepared and polymerized with a radical initiator. It has been revealed that N,N-disubstituted IAE-I as an acrylate is more reactive in polymerization than N,N-disubstituted IAE-II as an acrylamide and that N,N′-dialkyl substituted IAm homopolymerizes but N,N,N′,N′;-tetraalkyl substituted one does not. In radical copolymerization with styrene, IAE-I showed a higher polymerization reactivity than IAE-II. The effects of the N-substituents on the polymerization reactivity were discussed on the basis of conformation of the monomers. The polymers obtained were also characterized. © 1994 John Wiley & Sons, Inc. 相似文献
77.
Toru Doi Akira Akimoto Akikazu Matsumoto Yoshitaka Oki Takayuki Otsu 《Journal of polymer science. Part A, Polymer chemistry》1996,34(12):2499-2505
Radical copolymerization of N-(alkyl-substituted phenyl)maleimides (RPhMI) with isobutene (IB) was carried out with an initiator in various solvents at 60°C. The copolymerization of N-(2,6-diethylphenyl)maleimide (2,6-DEPhMI) with IB in benzene proceeded readily in a homogeneous system to give an alternating copolymer over a wide range of the comonomer compositions in the feed. Whereas the alternating tendency of the copolymerization of other RPhMI with IB decreased depending on the alkyl substituents of RPhMI in the following order: 2,6-DEPhMI > N-(2,6-dimethylphenyl)maleimide ≥ N-(2-methylphenyl)maleimide >. N-(4-ethylphenyl)maleimide. The copolymerization reactivities were discussed based on the rate constants for the homo-propagations and cross-propagations. Subsequently, the effect of the solvent on the rate and the reactivity ratios was examined. It was revealed that the copolymerization in chloroform proceeded with higher alternating tendency at a higher copolymerization rate than in the copolymerizations in benzene or dioxane. The copolymers of RPhMI with IB showed excellent thermal stability, i.e., high glass transition temperature and initial decomposition temperature over 200 and 350°C, respectively. © 1996 John Wiley & Sons, Inc. 相似文献
78.
79.
Akikazu Matsumoto Yasufumi Mohri 《Journal of polymer science. Part A, Polymer chemistry》1999,37(15):2803-2814
We carried out radical homopolymerization and copolymerization in various kinds of solvents at 60°C by using diisopropyl fumarate (DiPF) and methyl methacrylate (MMA) as electron-accepting polar monomers and styrene (St) and vinyl benzoate (VB) as electron-donating monomers. The highest polymerization rate was observed in the polar and electron-pair accepting solvents, such as 2,2,2-trifluoroethanol for the homopolymerization and copolymerization of these monomers. It has been revealed that the polymerization rate is correlated to the electron-pair–accepting property of the solvent used, rather than the polarity in the linear free energy relationship. We have demonstrated the validity of the acceptor number as the index for interpreting the interaction of the solvent with the monomer and the propagating chain end. The monomer reactivity ratios were determined for the St–DiPF, VB–DiPF, and St–MMA copolymerizations. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2803–2814, 1999 相似文献
80.
Molecular design of diene monomers containing an ester functional group for the synthesis of poly(diene sulfone)s by radical alternating copolymerization with sulfur dioxide
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Akikazu Matsumoto Sungi Lee Haruyuki Okamura 《Journal of polymer science. Part A, Polymer chemistry》2015,53(8):1000-1009
Functional poly(diene sulfone)s are prepared by the radical alternating copolymerization of 1,3‐diene monomers containing an ester substituent with sulfur dioxide. Methyl 3,5‐hexadienoate (MH) and methyl 5,7‐octadienoate (MO) with both an alkylene spacer and a terminal diene structure are suitable to produce a high‐molecular‐weight copolymer in a high yield, while the copolymerization of 5,7‐nonadienoic acid, ethyl 2,4‐pentadienoate, and ethyl 4‐methyl‐2,4‐pentadienoate including either an alkylene spacer or a terminal diene structure lead to unsuccessful results. The 13C NMR chemical shift values of MH and MO suggest a high electron density at their reacting α‐carbon for exhibiting a high copolymerization reactivity. Fluorene‐containing diene monomers, 9‐fluorenyl 3,5‐hexadienoate (FH) and 9‐fluorenyl 5,7‐octadienoate (FO), are also prepared and copolymerized with sulfur dioxide. The thermal and optical properties of the poly(diene sulfone)s containing the methyl and fluorenyl ester substituents in the side chain are investigated. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1000–1009 相似文献