全文获取类型
收费全文 | 523篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 367篇 |
晶体学 | 8篇 |
力学 | 6篇 |
数学 | 42篇 |
物理学 | 113篇 |
出版年
2023年 | 4篇 |
2022年 | 2篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 10篇 |
2013年 | 36篇 |
2012年 | 32篇 |
2011年 | 43篇 |
2010年 | 22篇 |
2009年 | 11篇 |
2008年 | 30篇 |
2007年 | 29篇 |
2006年 | 36篇 |
2005年 | 24篇 |
2004年 | 20篇 |
2003年 | 27篇 |
2002年 | 21篇 |
2001年 | 6篇 |
2000年 | 13篇 |
1999年 | 10篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 4篇 |
1986年 | 11篇 |
1985年 | 6篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1973年 | 2篇 |
排序方式: 共有536条查询结果,搜索用时 312 毫秒
51.
52.
K. Suzuki M. Takahashi M. Saitoh 《Applied Physics A: Materials Science & Processing》1999,69(7):S263-S266
This paper presents for the first time experimental results which show a crucial role of the local Si-H bonding structures in Si precursors for crystallinity of polycrystalline silicon (p-Si), obtained by an excimer laser crystallization (ELC) process. This role was revealed in the distinct differences among (111) lattice plane spacings of p-Si according to deposition and dehydrogenation conditions of the precursors. It was also found that preablation behaviors, especially ebullition of the melt, are highly sensitive to the precursors. These results provide an important guide for the selection of the most adequate precursor in production, and also contribute an understanding of the mechanism of the ELC process. 相似文献
53.
M. Hasegawa Y. Saitoh S. Yamaguchi H. Takahashi S. Ohnuki 《Hyperfine Interactions》1994,84(1):389-396
Angular correlation of two-photon annihilation radiation (ACAR) measurements have been performed to study the effect of interstitial impurities (O, C and D) on positronium (Ps) formation in irradiation-induced voids of vanadium. It has been observed that Ps formation is sensitively affected by doping with the interstitial impurities, irradiation dose, irradiation temperature, and also by post-irradiation annealing. The Ps component intensity is found to be related to segregation of the interstitial impurities and provides a new experimental method to study void surfaces. 相似文献
54.
Hiroaki Minamisawa Ryoko Okunugi Mayumi Minamisawa Satoshi Tanaka Kazunori Saitoh Nobumasa Arai Masami Shibukawa 《Analytical sciences》2006,22(5):709-713
The solid-phase extraction (SPE) method for the preconcentration of trace amounts of cadmium using synthetic zeolite A-4 and its determination by graphite furnace atomic absorption spectrometry (GFAAS) was investigated. The preconcentration conditions, such as the optimum pH range of the sample solution for the adsorption of cadmium and the kind of acid solution for dissolving the cadmium-adsorbed synthetic zeolite A-4, as well as the measurement conditions for the determination of cadmium by GFAAS, e.g., the ashing and atomizing temperature, were investigated. Quantitative recovery of cadmium onto zeolite A-4 from the sample solution over the pH range 2.0 - 9.0 was achieved by the batch method. After the solid-phase (cadmium-adsorbed zeolite A-4) was separated from the sample solution by a membrane filter, it was dissolved in 2.0 cm(3) of 2.0 mol dm(-3) nitric acid. An aliquot of the resulting solution was injected into the graphite furnace. In GFAAS measurements an alternate gas (Ar, 90%; O(2), 10%) was used as a sheath gas, and the ashing temperature and atomizing temperature were 400 degrees C and 1600 degrees C, respectively. The detection limit (3 sigma) for cadmium was 0.002 microg dm(-3). The relative standard deviation at 0.010 microg dm(-3) was 3.5 - 4.5% (n = 5). The proposed method has been successfully applied to the analysis of trace cadmium in environmental water samples. 相似文献
55.
Akihito Kitajima Takeshi Kashirajima Takao Minamizawa Hiroyasu Sato Kazuo Iwaki Taisuke Ueda Yoshio Kimura Toshimasa Toyo'oka Tamio Maitani Rieko Matsuda Yuzuru Hayashi 《Analytical sciences》2007,23(9):1077-1080
The stochastic properties of baseline noise in HPLC systems with a UV photo-diode array, photo-multiplier and gamma-ray detector were examined by dividing the noise into auto-correlated random process (Markov process) and an independent process (white noise). The present work focused on the effect of the stochastic noise properties on a theoretical estimation of the standard deviation (SD) of area measurements in instrumental analyses. An estimation theory, called FUMI theory (Function of Mutual Information), was taken as an example. A computer simulation of noise was also used. It was shown that the reliability (confidence intervals) of theoretical SD estimates mainly depends on the following factors: the ratio of the white noise and Markov process occurring in the baselines; the number of data points used for the estimation; the width of a target peak for which the SD is estimated. 相似文献
56.
S. Saitoh H. Tanaka A. Ono Y. Furuhama T. Manabe T. Ihara 《International Journal of Infrared and Millimeter Waves》1986,7(6):795-812
The attenuation of 245.52 GHz millimeter wave was measured through a near ground horizontal path in order to study the anomalous water vapor absorption at the window region. The result demonstrates that the attenuation coefficient includes the quadratic dependence on the water vapor density. The quadratic component of the water vapor density in the expression of the attenuation was assumed to arises from the contribution of water dimers alone, then the concentration of water dimers was estimated adopting the published theoretical water dimers absorption coefficient. The obtained concentration was 0.062% of monomers in number when the water vapor density is 7.5 g/m3. This concentration is in agreement with the published result obtained by way of another method. 相似文献
57.
Highly photoluminescent nanocrystals based on a gold(I) complex and their electrophoretic patterning
Saitoh M Balch AL Yuasa J Tada K Onoda M Nakashima T Kawai T 《Langmuir : the ACS journal of surfaces and colloids》2011,27(17):10947-10952
The fabrication of nanocrystals (NCs) composed of the cationic Au(I) complex was demonstrated by the reprecipitation method in which the colloidal solution of the NCs showed brilliant green phosphorescence with a quantum yield of 83% in n-hexane. Characterization of the prepared NCs was performed by transmission electron microscopy observation and elemental analysis with energy-dispersive X-ray spectroscopy. The obtained Au(I) NCs were particles of random shapes with a diameter of 200-400 nm. The selected-area electron diffraction and X-ray diffraction measurements showed the characteristic diffraction patterns attributable to the crystal structure of the bulk crystal of the Au(I) complex. A similar method was performed with a different counteranion, leading to a colloidal solution of the microcrystals (MCs) with brilliant yellow phosphorescence and a quantum yield of 26% in n-hexane. Luminescence patterning of the NCs and MCs was also achieved successfully by electrophoretic deposition onto an indium tin oxide (ITO)-coated glass substrate, resulting in characteristic luminescence patterns on the ITO substrates with relatively high photoluminescence quantum yields. 相似文献
58.
Tsuyoshi Satoh Yu AwataYuichi Kato Shingo OgataMasashi Ishigaki Shimpei SugiyamaHideki Saitoh 《Tetrahedron》2011,67(6):1102-1113
Treatment of 1-chlorovinyl p-tolyl sulfoxides, which were derived from cyclobutanones and chloromethyl p-tolyl sulfoxide, with lithium enolate of tert-butyl carboxylates, amides, lithium α-sulfonyl carbanions, and lithium α-carbanion of acetonitrile gave adducts in high to quantitative yields. The adducts were treated with Grignard regents, such as i-PrMgCl and EtMgCl in toluene to afford 1-substituted cyclopentenes in good to high yields with one-carbon ring-expansion via 1,2-carbon-carbon (1,2-CC) insertion reaction of the generated magnesium carbenoid intermediates. The magnesium carbenoid 1,2-CC insertion was found to be highly stereospecific. When optically pure chloromethyl p-tolyl sulfoxide was used in this procedure, optically active 1-substituted cyclopentenes were obtained in high optical purity. 相似文献
59.
The proton conductivities of the porous coordination polymers M(OH)(bdc-R) [H(2)bdc = 1,4-benzenedicarboxylic acid; M = Al, Fe; R = H, NH(2), OH, (COOH)(2)] were investigated under humid conditions. Good correlations among pK(a), proton conductivity, and activation energy were observed. Fe(OH)(bdc-(COOH)(2)), having carboxy group and the lowest pK(a), showed the highest proton conductivity and the lowest activation energy in this system. This is the first example in which proton conductivity has been widely controlled by substitution of ligand functional groups in an isostructural series. 相似文献
60.
Saigusa D Shibuya M Jinno D Yamakoshi H Iwabuchi Y Yokosuka A Mimaki Y Naganuma A Ohizumi Y Tomioka Y Yamakuni T 《Analytical and bioanalytical chemistry》2011,400(10):3635-3641
We recently demonstrated that nobiletin, a citrus flavonoid, exhibits anti-dementia action in animals. However, no determination methods for the content of nobiletin with beneficial action in the brain of nobiletin-administered animals have been developed, nor has its pharmacokinetics been revealed completely. Here, we established the high-performance liquid chromatography/photodiode array detection method for nobiletin determination using Bond Elut C18 SPE cartridges for extraction, where the calibration curve was linear over 0.025-10 ng, with coefficient of variation of less than 6.76%. This method enabled us to determine pharmacokinetic parameters of nobiletin given intraperitoneally or per os in the brain of mice. 相似文献