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101.
102.
Akihiro Furuta 《Tetrahedron letters》2008,49(1):110-113
A combination of a catalyst derived from ferrous acetate and sodium thiophene-2-carboxylate efficiently promoted hydrosilylation of aromatic and aliphatic ketones to give the corresponding secondary alcohols in high yields with extremely high selectivity. 相似文献
103.
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105.
Akihiro Tohsaki 《Frontiers of Physics》2011,6(3):320-336
We explain how to treat a microscopic wave function of ??-condensation taking a 3??-nucleus as a typical example. The wave function has been originally proposed ten years before by Horiuchi, R?pke, Schuck and the present author (Phys. Rev. Lett., 2001, 87: 192501). The microscopic model, which fully takes into account the Pauli principle between all the constituent nucleons, effective internucleon forces and the Coulomb force, can play an important role in reproducing an ??-gas nature thanks to ??-condensation as an excited state of ??-like nuclei. An essential point of the wave function is to describe their ground state simultaneously. We study its typical features by giving an analytical formula of the norm kernel and the kernel concerning the one-body operator for 3??-condensation. 相似文献
106.
The uniqueness of a binary doubly-even self-dual [48, 24, 12] code is used to prove that a self-orthogonal 5-(48, 12, 8) design, as well as some of its derived and residual designs, including a quasi-symmetric 2-(45, 9, 8) design, are all unique up to isomorphism.Received November 5, 2003 相似文献
107.
Renhua Qiu Guoping Zhang Xinhua Xu Kangbin Zou Lingling Shao Dawei Fang Yinhui Li Akihiro Orita Ryosuke Saijo Hidetaka Mineyama Tomoyoshi Suenobu Shunichi Fukuzumi Delie An Junzo Otera 《Journal of organometallic chemistry》2009,694(9-10):1524-1528
Zirconocene and titanocene bis(perfluorooctanesulfonate)s were synthesized. In contrast to the corresponding triflates and perchlorates, these compounds are air- and water-stable. They were proved to be ionic on the basis of conductivity measurements and X-ray analysis, allowing these complexes to be stored for months. The strong Lewis acidity of these cationic metallocene species, which was proved by ESR study, enabled catalytic glycosylation. 相似文献
108.
Tomohiro Hirano Shou Nasu Akihiro Morikami Koichi Ute 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6534-6539
Radical polymerization of N‐methylacrylamide (NMAAm), N,N‐dimethylacrylamide (DMAAm), and N‐methyl‐N‐phenylacrylamide (MPhAAm) was investigated in toluene at low temperatures. Atactic, isotactic, and syndiotactic polymers were obtained by the polymerization of NMAAm, DMAAm, and MPhAAm, respectively, indicating that the stereospecificity of the radical polymerization of acrylamide derivatives depended on the N‐substituents of the monomer used. From the viewpoint of monomer structure, the origin of the stereospecificity of radical polymerization of NMAAm derivatives is discussed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6534–6539, 2009 相似文献
109.
Practical two-dimensional high-spin organic polymers are newly designed and the electronic structures are examined on the basis of the ab initio two-dimensional unrestricted Hartree–Fock crystal orbital (UHF-CO) method. The present polymers can be oxidized up to six electrons per unit cell, and it is predicted that the three-electron and six-electron oxidations per unit cell lead to the high-spin organic polymers having superdegenerate band structures originating from the characteristic non-bonding crystal orbital patterns. 相似文献
110.
Akihiro Ito Haruhiro Ino Kazuyoshi Tanaka Katsuichi Kanemoto Tatsuhisa Kato 《The Journal of organic chemistry》2002,67(2):491-498
Syntheses of both the dimer (3) and the trimer (4) of all-para-brominated poly(N-phenyl-m-aniline)s (2c) were achieved in a one-pot procedure from the parent nonbrominated oligomers and benzyltrimethylammonium tribromide [(BTMA)Br(3)]. An X-ray crystallographic analysis revealed that 4 has a U-shaped structure, suggesting that 2c easily adopts helical structures. Furthermore, the redox properties were investigated by the UV-vis and EPR measurements. It was confirmed that the both 3 and 4 can be oxidized into the dications 3(2+) and 4(2+) with triplet spin-multiplicity. 相似文献