Fluctuating hydration structure around nanometer-size hydrophobic solutes. I. Caging and drying around C60 and C60H60 spheres

The hydration structure around nanometer-size hydrophobic solutes is studied with molecular dynamics simulation by taking aqueous solutions of C60 and C60H60 as examples. In the hydration shell around a single C60 or C60H60, dipoles of simulated water molecules tend to be aligned to form the vortexlike coherent pattern which lasts for 100 ps, while individual water molecules stay within the hydration shell for about 10 ps. This structural pattern organized by fluctuating and diffusively moving molecules should be called a "fluctuating cage". In the narrow region between a pair of C60 molecules or a pair of C60H60 molecules, water density strongly fluctuates and is correlated to the mean force between solutes. The fluctuating caging and drying between solutes affect the hydrophobic interaction and dynamical behaviors of solutes.     

Few-electron molecular states and their transitions in a single InAs quantum dot molecule

We study electronic configurations in a single pair of vertically coupled self-assembled InAs quantum dots, holding just a few electrons. By comparing the experimental data of nonlinear single-electron transport spectra in a magnetic field with many-body calculations, we identify the spin and orbital configurations to confirm the formation of molecular states by filling both the quantum mechanically coupled symmetric and antisymmetric states. Filling of the antisymmetric states is less favored with increasing magnetic field, and this leads to various magnetic field induced transitions in the molecular states.     

Separation-independent attractive force between like particles mediated by nematic-liquid-crystal distortions

We investigate numerically with the aid of the Landau-de Gennes continuum theory the interaction between two spherical particles carrying the same topological charges +1 mediated by the elastic distortion of a nematic liquid crystal. We consider the case where an escaped nontopological ring disclination is situated between the particles; the director is continuous everywhere and no counterdefects are present. We find that the interaction is attractive and its potential energy depends linearly on the interparticle distance D. This behavior yields the D-independent interaction force, which was observed experimentally by Poulin, Cabuil, and Weitz [Phys. Rev. Lett. 79, 4862 (1997)] in the presence of narrow strings of birefringent regions ("bubble-gum" configuration) between the particles.     

Surface-emitted terahertz-wave difference-frequency generation in two-dimensional periodically poled lithium niobate

We report on the demonstration of surface-emitted terahertz- (THz-) wave difference-frequency generation from two-dimensional (2D) periodically poled lithium niobate (PPLN). The two orthogonal periodic structures individually compensate for both the phase mismatch of the launched lasers and the generated THz wave. Tunable 1.5-1.8 THz wave generation with a bandwidth of 10-GHz was obtained by use of two 2D PPLN crystals. We also confirmed that THz waves were simultaneously generated into two opposite directions, which suggests the possibility of higher THz-wave output power.     

A relation between gauge-invariant formulation of QCD and string theory in two dimensions

We have studied the explicit relation between the gauge-invariant path-ordered operator (POO) and a string field in two dimensions. For this purpose, we use the hamiltonian of two-dimensional quantum chromodynamics reformulated in terms of POO. POO is expanded in a power series of a non-local bosonic operator. We show that such a bosonic operator describes Bars and Hanson's free string field in the second quantization. Interactions among bosonic operators are treated in perturbation theory. The coupling constant is proportional to 1/√N_c.     

Formation of excited Cu II levels through second-kind collisions in a Ne-Cu discharge

Transient spectroscopic techniques have been used to discriminate between various processes forming excited Cu II levels in a Ne-Cu discharge. Ratio of the cross sections for Ne⁺-Cu charge transfer reaction into individual Cu II 5s levels has been determined. The Cu II 4p levels were found to be excited through some unidentified process as well as Ne(metastable) -Cu Penning reaction, and the former was more effective.