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201.
Kazuo Yoshino Kotaro Hachiman Akihiro Yokoyama Tsutomu Yokozawa 《Journal of polymer science. Part A, Polymer chemistry》2010,48(6):1357-1363
Chain‐growth condensation polymerization of p‐aminobenzoic acid esters 1 bearing a tri(ethylene glycol) monomethyl ether side chain on the nitrogen atom was investigated by using lithium 1,1,1,3,3,3‐hexamethyldisilazide (LiHMDS) as a base. The methyl ester monomer 1a afforded polymer with low molecular weight and a broad molecular weight distribution, whereas the polymerization of the phenyl ester monomer 1b at ?20 °C yielded polymer with controlled molecular weight (Mn = 2800–13,400) and low polydispersity (Mw/Mn = 1.10–1.15). Block copolymerization of 1b and 4‐(octylamino)benzoic acid methyl ester ( 2 ) was further investigated. We found that block copolymer of poly 1b and poly 2 with defined molecular weight and low polydispersity was obtained when the polymerization of 1b was initiated with equimolar LiHMDS at ?20 °C and continued at ?50 °C, followed by addition of 2 and equimolar LiHMDS at ?10 °C. Spherical aggregates were formed when a solution of poly 1b in THF was dropped on a glass plate and dried at room temperature, although the block copolymer of poly 1b and poly 2 did not afford similar aggregates under the same conditions. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1357–1363, 2010 相似文献
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204.
Polycatenar materials composed of a four-aromatic-ring core, with either a bulky or end-branched perfluorinated moiety attached at one end through a methylene spacer group, and three peripheral alkoxy chains of varying length (the carbon number n = 4, 6, 8, 10, 12, 14, 16) on the other end-ring, were synthesized to investigate the roles of the chemical structure of the compositional segments in relation to liquid crystalline phase formation. It was found that a homologous series of polycatenar materials exhibited a variety of liquid crystalline phases strongly dependent on the length of the peripheral alkyl chains. Moreover it was shown that changes in the spacer group and in the structure of the perfluorinated segment had a significant influence on mesophase formation. 相似文献
205.
The synthesis of a variety of organotin compounds with 1H, 1H, 2H, 2H‐perfluorooctyl groups is reported, together with an improved method for the corresponding distannoxane. Unique properties of this compound are disclosed in terms of fluorophilicity and activity as a Lewis acid catalyst in comparison with other mono‐nuclear derivatives. A new criterion for obtaining high solubility in fluorocarbon solvents is presented. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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207.
Fumiaki Ishii Toshio Ohga Akihiro Tsutsumi Hiroji Ohigashi 《Journal of Polymer Science.Polymer Physics》2002,40(10):1026-1037
The heterogeneous higher order structure and molecular motion in a single crystalline film of a vinylidene fluoride (VDF) and trifluoroethylene (TrFE) copolymer with 73 mol % VDF was investigated with the 1H–13C cross‐polarization/magic‐angle spinning NMR technique. A transient oscillation was observed in plots of the 13C peak intensity versus the contact time for the CH2, CHF, and CF2 groups. On the basis of the extended cross‐relaxation theory of spin diffusion, we determined that the oscillation behavior was caused by the TrFE‐rich segments in the chain and that the crystal consisted of VDF‐rich and TrFE‐rich domains. The former had TrFE‐rich segments in VDF and TrFE fractions of 0.24 and 0.27, respectively, and the latter had VDF‐rich segments in a VDF fraction of 0.49. The spin–lattice relaxation time T1ρH in the rotating frame for each group was minimal in the three temperature regions of β, αb, and αc (↑) on heating and in the two temperature regions of α1D and αc (↓) on cooling. The αc (↑) and αc (↓) processes depended on the first‐order ferroelectric phase‐transition regions on heating and cooling, respectively. The motional modes for the other processes were confirmed by the T1ρH minimum behavior of the VDF and TrFE groups in the TrFE‐rich domain and the VDF‐rich segments in the VDF‐rich domain. The β and αb processes were attributed to the flip–flop motion of the TrFE‐rich segments and the competitive motion of the TrFE‐ and VDF‐rich segments in the ferroelectric phase, respectively. The α1D process was due to the one‐dimensional diffusion motion of the conformational defects along the chain in the paraelectric phase, accompanied by the trans and gauche transformation of the VDF conformers of ttg+tg? and g+tg?tt. The effect of the competitive motion of the TrFE‐rich segment on the thermal stability of the VDF‐rich segment in the chain near the Curie temperature was examined. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1026–1037, 2002 相似文献
208.
Hironori Ohashi Hiroyuki Ezoe Yoshihiro Okaue Yasuhiro Kobayashi Shuji Matsuo Tsutomu Kurisaki Akane Miyazaki Hisanobu Wakita Takushi Yokoyama 《Analytical sciences》2005,21(7):789-793
The effect of UV (ultraviolet) irradiation on the adsorption of Au(III) ions on manganese dioxide and their reduction to Au(0) (gold with 0 valence state) was investigated using XPS (X-ray photoelectron spectroscopy) and 197Au M?ssbauer spectroscopy. The UV irradiation accelerated the adsorption and the reduction. From the fact that the proportion of Au(0) estimated from Au 4f XPS spectra for surface analysis was significantly smaller than that from 197Au M?ssbauer spectra for bulk analysis, we deduced that Au(0) was interpenetrated to the inside of manganese dioxide (into deeper places than about 30 A) where XPS is impossible to detect. The content of surface hydroxyl groups on manganese dioxide also increased due to the UV irradiation. The relationship between the charge in the content of hydroxyl groups and the interpenetration of Au(0) is discussed. 相似文献
209.
210.
Takahisa Yokoyama 《Annals of the Institute of Statistical Mathematics》1995,47(2):309-320
We consider a parallel profile model which is useful in analyzing parallel growth curves of several groups. The likelihood ratio criterion for a hypothesis concerning the adequacy of a random-effects covariance structure is obtained under the parallel profile model. The likelihood ratio criterion for the hypothesis in the general one-way MANOVA model is also obtained. Asymptotic null distributions of the criteria are derived when the sample size is large. We give a numerical example of these asymptotic results. 相似文献