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831.
832.
Adsorption isotherms of nitrogen monoxide (NO) and in situ EPR spectra of adsorbed NO on mordenite zeolites (MOR) of different cation types (HM, NaM and CaM) are measured at different temperatures to elucidate the effect of the strong adsorption promoted by the enhancement of potential field in micropore of MOR (micropore filling) as well as the electrostatic interaction in MOR on NO adsorption. The NO molecules adsorb irreversibly and fill up the micropore of MOR at 201 K, above the critical temperature of NO, regardless of the kind of cation species. The NO adsorption takes place even at 273 K. In the adsorption at 273 K, the strength of electrostatic field formed by cation sites affects the adsorptivity and the order of saturation amount of adsorption (V
s) corresponds to that of the electrostatic field strength. EPR results show that NO molecules strongly interact with cation sites in MOR and disproponation reaction of NO take place on CaM. 相似文献
833.
A theory T is called almost ??0-categorical if for any pure types p1(x1),…,pn(xn) there are only finitely many pure types which extend p1(x1) ∪…∪pn(xn). It is shown that if T is an almost ??0-categorical theory with I(??0,T) = 3, then a dense linear ordering is interpretable in T. 相似文献
834.
835.
The microwave spectrum of CH2DNH2 has been observed in the 8–74 GHz region. The spectrum shows that this molecule takes essentially two distinguishable conformers, trans and gauche forms, although a small amount of coupling between them can be detected. For each line of the trans form a small inversion splitting has been found. It is 93.97 MHz at K = 0 and a periodic function of K. The mean frequencies of the inversion pairs of lines are well explained as the frequencies of a rigid rotor. The gauche spectrum is extremely complicated; each rotational line splits into four because of inversion and gauche-gauche tunneling interactions. The analysis was carried out based on the theory developed in the preceding paper. Tunneling energy parameters of internal-rotation, ?gg and ?tg, and inversion, δgg and δtg, were determined as ?gg = 3476.6 MHz, ?tg = 3233.1 MHz, δgg = 2790.6 MHz and δtg = 3052.7 MHz. Energy difference between trans and gauche conformers ΔEtg was estimated to be 7.060 cm?1 from these values of parameters and also on the basis of the observed anomaly in the Q branch series of trans form which is due to an accidental degeneracy between the K = 1 level of trans and K = 2 level of gauche. The effects on the internal-rotation of other internal motions have also been discussed. 相似文献
836.
837.
Akiko Hori Hisashi Kataoka Akihiko Akasaka Takashi Okano Makoto Fujita 《Journal of polymer science. Part A, Polymer chemistry》2003,41(22):3478-3485
A Pd(II)-linked coordination ring is reversibly transformed into its catenanted dimer at room temperature through the efficient organic stacking of the component rings. An analogous Pt(II)-linked ring is also catenated only at high temperature (100 °C), but not at room temperature because of the kinetic inertness of Pt(II)-ligand interaction. Interestingly, the combination of the Pd(II)- and the Pt(II)-linked coordination rings selectively gives a Pd(II)/Pt(II) cross-catenane, because the kinetically inert Pt(II) ring can be catenated only via the dissociation of the kinetically labile Pd(II) ring. Planer conformation of the monomer rings is twisted upon catenation, inducing helical chirality in the catenated structure. Thus, induced circular dichroism (ICD) is observed in the catenation when chiral-1,2-cyclohexandiamine is attached as a chiral auxiliary on the metal centers. The ICD decreases with increasing temperature due to less effective chiral aromatic stacking at higher temperature. The Pd(II) ring shows higher ICD than the Pt(II) ring, probably due to the more flexible conformation of the Pd(II) ring that can adopt chiral orientation easily. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3478–3485, 2003 相似文献
838.
Masayuki Kirihara Hiroko Kakuda Yuta Ochiai Asuka Mokuya Akihiko Hatano 《Tetrahedron》2005,61(20):4831-4839
Tertiary cyclopropanol compounds react with a catalytic amount of vanadyl acetylacetonate in the presence of oxygen affording β-hydroxyketones and β-diketones. For 3-substituted-bicyclo[4.1.0]alkanols, peroxides are obtained, as are the β-hydroxyketones. Conversely, 2-ethoxycarbonylcyclopropyl silyl ethers produce ethyl γ-oxocarboxylate derivatives given the same reaction conditions. 相似文献
839.
Akihiko Nishimura Hironori Ohba Koichi Ogura Takemasa Shibata 《Optics Communications》1994,110(5-6):561-564
The absolute values of the oscillator strength ƒ were measured for the six spectral lines of Gd by means of laser absorption spectroscopy with the atomic vapor produced by electron beam heating. The ƒ values obtained for the transition are 0–17381 cm−1, 215–17750 cm−1, 533–17795 cm−1, 999–18070 cm−1, 999–17931 cm−1, 1719–18070 cm−1 were obtained to be 0.0036, 0.012, 0.014, 0.019, 0.0075 and 0.039, respectively. The error of ƒ values was 24% due to uncertainty of metastable states' density. 相似文献
840.