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71.
Kawahara N Kurata A Hakamatsuka T Sekita S Satake M 《Chemical & pharmaceutical bulletin》2001,49(10):1377-1379
Two novel cucurbitacins designated as neocucurbitacins A (1), possessing inhibitory activity of polyoma enhancer binding protein 2alphaA (PEBP2alphaA) and osteoclastogenesis-inhibitory factor (OCIF) gene expression in human osteoblast-like cells, and B (2) were isolated from the fruit of Luffa operculata. Their structures have been determined by extensive spectroscopic investigation. 相似文献
72.
The preparation of benzimidazole compound 7, an ORL‐1 agonist, is described. The four‐step procedure gave the compound 7 in 29% overall yield. 相似文献
73.
Shohei Satake 《Discrete Mathematics》2019,342(12):111613
A tournament is an oriented complete graph. The problem of ranking tournaments was firstly investigated by P. Erd?s and J. W. Moon. By probabilistic methods, the existence of ?? ?? unrankable” tournaments was proved. On the other hand, they also mentioned the problem of explicit constructions. However, there seems to be only a few of explicit constructions of such tournaments. In this note, we give a construction of many such tournaments by using skew Hadamard difference sets which have been investigated in combinatorial design theory. 相似文献
74.
75.
Hirashita T Kamei T Satake M Horie T Shimizu H Araki S 《Organic & biomolecular chemistry》2003,1(21):3799-3803
Diastereoselective couplings of salicylaldehyde, anisaldehyde and 2-pyridylaldehyde with crotyl- and cinnamylindium reagents were studied. The syl/anti selectivity was found to depend largely on the ligands on the indium atom of the allylic indium reagents. A syn-selective cinnamylation of salicylaldehyde was realized by the combination of cinnamyl acetate and indium(I) iodide, whereas an anti-selective coupling with salicylaldehyde was achieved by the indium trichloride/aluminium-mediated cinnamylation. 相似文献
76.
Myoga Arata Iwashita Ryutaro Unno Noriyuki Satake Shin-ichi Taniguchi Jun Yuki Kazuhisa Seki Yohji 《Optical Review》2018,25(3):450-455
Optical Review - Various water purification reactors were constructed using beads of TiO2-coated MEXFLON, which is a fluoropolymer exhibiting a refractive index identical to that of water. The... 相似文献
77.
Iwao Satake Masao Fukuda Tomohisa Ohta K
zaburo Nakamura Noboru Fujita Akira Yamauchi Hideo Kimizuka 《Journal of Polymer Science.Polymer Physics》1972,10(12):2343-2354
Counterion activity coefficients in solutions of dextran sulfate with and without added salts were determined potentiometrically by using a cation-exchange membrane and a sodium glass electrode. Dextran sulfate was shown to interact with monovalent cations in the order of preference: K+ > Cs+ > Na+ > Li+, whereas no specificity was found for bivalent cations. On the basis of light-scattering measurements, the expansion of the dextran sulfate polyion in solutions of alkali metal salts was found to fall in the same order as the counterion activity coefficients in salt-free solutions. It was also shown that the dextran sulfate polyion assumes a more extended conformation in magnesium chloride solution than in calcium chloride. These results were substantiated by measurements of solution viscosities. 相似文献
78.
A porphyrin-based nanopore was constructed through a bilayer lipid membrane (BLM). The macrocyclic porphyrin (the inner diameter = ca. 2.1 nm) having six carboxylic acid groups directed up and down was synthesized by self-assembly of three trisporphyrins, metathesis linking, and subsequent hydrolysis. The porphyrin was incorporated into soybean lecithin based BLM, and the ion currents through the nanopore were observed under 500 mM KCl, LiCl, CaCl2, and tetraalkylammonium chloride solutions, indicating formation of a large pore through BLM. Blocking of the ion current was achieved by addition of the polycationic fourth-generation PAMAM dendrimer. 相似文献
79.
Naphthalene powder doped with 1-(2-thiazolylazo)-2-naphthol is used as collector for traces of metals, which are then determined by X-ray fluorescence analysis of the naphthalene. The method is used for traces of nickel. 相似文献
80.
Hagiwara M Dohi M Nakahara Y Komatsu K Asahina Y Ueki A Hojo H Nakahara Y Ito Y 《The Journal of organic chemistry》2011,76(13):5229-5239
The biantennary complex-type N-glycans bearing LacNAc and LacdiNAc as the nonreducing end motif were synthesized in a protected form suitable to use in the Fmoc solid-phase peptide synthesis studies. Two approaches for the nonasaccharide synthesis were examined by taking advantage of the highly β-selective glycosylation with GlcNTCA (N-phenyl)trifluoroacetimidate. An earlier approach, which involved the reaction of the trisaccharide donor (Gal-GlcNTCA-Man) and trisaccharide acceptor (Man-GlcNPhth(2)-N(3)), produced a mixture of nonasaccharide isomers. On the other hand, mannosylation of the trisaccharide acceptor (Man-GlcNPhth(2)-N(3)) stereoselectively afforded the known pentasaccharide (Man(3)-GlcNPhth(2)-N(3)), which was reacted with the disaccharyl glycosyl donor (Gal-GlcNTCA or GalNTCA-GlcNTCA) to produce the desired nonasaccharide as a single stereoisomer. Selective dephthaloylation followed by N-acetylation furnished the GlcNAc(2) functionality. The resulting nonasaccharyl azides were condensed with Fmoc-Asp(OPfp)-OBu(t) or Fmoc-Asp(OPfp)-OPac in the presence of Ph(CH(3))(2)P and HOOBt. Finally, the Zn reduction and cleavage of the tert-butyl ester or Zn reduction alone produced the targeted nonasaccharyl Asn building blocks. 相似文献