Solid state NMR strategies for the structural characterization of new hybrid materials based on the intercalation of nitroxide radicals into CdPS3

The radical cations 2-(3-N-butylpyridinium)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-N-oxide (m-BuPYNN) and 4-(ethylammonium)-2,2,6,6-tetramethylpiperidin-1-oxide (EATEP) are successfully intercalated into the layered host structure of CdPS(3) via ion exchange. The reaction proceeds either directly from ethanolic solutions of the radical iodide salt or via a two-stage process involving first the formation of an intermediate tetramethylammonium intercalate. The resulting materials, which are described by the compositional formula Cd(1-x)PS(3){Rad}(2x), are characterized by chemical analysis, X-ray powder diffraction, bulk susceptibility measurements and EPR spectroscopy. Modern single and double resonance solid state NMR techniques are introduced successfully to study the structural modifications of the host lattice and the details of the intermolecular guest/host interactions. (1)H MAS-NMR spectra reveal substantial differences in the unpaired electron spin density distributions within the radical ions intercalated into the host lattice compared to those obtained for the pure radical ion salts, leading to different bulk magnetic properties. The results of (1)H/(31)P double resonance experiments indicate that the orientation of the guest molecules is dominated by Columbic interactions between the radical cations and the negatively charged cadmium vacancies in the host lattice.     

A Tiled Order of Finite Global Dimension with No Neat Primitive Idempotent

The aim of this article is to introduce the notion of Hom-Lie color algebras. This class of algebras is a natural generalization of the Hom-Lie algebras as well as a special case of the quasi-hom-Lie algebras. In the article, homomorphism relations between Hom-Lie color algebras are defined and studied. We present a way to obtain Hom-Lie color algebras from the classical Lie color algebras along with algebra endomorphisms and offer some applications. Also, we introduce a multiplier σ on the abelian group Γ and provide constructions of new Hom-Lie color algebras from old ones by the σ-twists. Finally, we explore some general classes of Hom-Lie color admissible algebras and describe all these classes via G–Hom-associative color algebras, where G is a subgroup of the symmetric group S ₃.     

Correlation between shapes of Shockley stacking faults and structures of basal plane dislocations in 4H-SiC epilayers

Abstract

Shockley-type stacking faults expanded in 4H–SiC epilayers induced by ultraviolet illumination were investigated using a photoluminescence imaging method, a photoluminescence mapping method and X-ray topography. After ultraviolet illumination, more than 30 patterns of Shockley-type stacking faults which expanded from perfect basal plane dislocations were observed by photoluminescence imaging. The initial basal plane dislocations were crystallographically classified, and individual shapes of expanded Shockley-type stacking faults were predicted. The correspondence between the predicted shapes and observed ones was discussed.     

Direct Measurement of 12C+4He Fusion Cross Section at E cm = 1.5 MeV at KUTL

¹²C+⁴He fusion reaction at E _cm  = 0.3 MeV is one of the main reaction in ⁴He-burning in stars, and is very important in nuclear synthesis. However the fusion cross section has not been determined yet in spite of 40 years efforts in the world. Recently we succeeded in the measurement at 1.5 MeV. We have a plan to make direct measurement of the total fusion cross section down to 0.7 MeV at Kyushu University Tandem accelerator Laboratory (KUTL), and to determine the cross section at 0.3 MeV by extrapolation.     

Measurement of 4He(12C,16 O)γ Reaction in Inverse Kinematics

A cross section measurement employing a direct ¹⁶O detection method for the reaction energies from E _cm = 2.4 to 0.7 MeV is planned at Kyushu University Tandem Laboratory. To perform this experiment and to obtain quantitative information about the cross section to within an error of 10%, we have developed several instruments, including a blow-in type windowless gas target and a ionization chamber. A target thickness of 24 × 3.9 Torr cm was achieved using the developed gas target. The particle identification was successfully performed by using the energy deposit in the ionization chamber. Experiments were performed at E _cm = 2.4 and 1.5 MeV using the developed instruments and the cross sections were obtained.     

Complex Formation of Homoionic Montmorillonites with Propylene Carbonate and Osmotic Swelling in Aqueous Electrolyte Solutions

Abstract

Homoionic montmorillonites saturated with several kinds of cations can form complexes with propylene carbonate (PC) by intercalation. The PC molecules interact with the interlayer cations by way of H₂O molecules between the silicate layers. The PC-montmorillonite complexes exhibit osmotic swelling even in aqueous electrolyte solutions. This is interpreted in terms of the formation of thick electric double-layers consisting of PC and H₂O between the silicate layers. Although the PC molecules are gradually hydrolyzed to propylene glycol between the layers, the hydrolyzed complex also shows a similar swelling power in aqueous electrolyte solutions.     

Linear and nonlinear transports of coupled quantum dots

Series of double quantum dots each with a size around 400 × 400nm² have been realized by delineating a 2DEG in modulation-doped AlGaAs/GaAs with 100 nm wide Schottky split gates fabricated by an electron-beam lithography and a lift-off technique. The split gate in the middle of the double dot allows us to control interdot coupling widely. The charging diagram obtained from linear transports in the Coulomb blockade regime shows that the isolated dots merge into a single composite dot with increase of interdot coupling. A clear Coulomb staircase has been observed in the double-dot system at a limited high-bias condition.     

Retrospective dosimetry using Japanese brick quartz: A way forward despite an unstable fast decaying OSL signal

Quartz extracted from heated bricks has been previously suggested for use in dose estimation in accident dosimetry, but this technique has never been applied before to Japanese quartz which often has unusual OSL characteristics. In this study the optically stimulated luminescence (OSL) characteristics of quartz extracted from a Japanese commercial red brick produced by Mishima – Renga – Seizoujyo Co. are studied. These companies are based in the Aichi Prefecture (capital Nagoya), which accounts for about half of the red brick production in Japan. A comparison of TL (thermoluminescence) and OSL signals has been carried out towards identification of common source traps. It is observed that OSL from Japanese brick quartz shows unusual luminescence characteristics; in particular, the initial fast decaying OSL signal contains a dominant (>90%) thermally unstable component related to the 85 °C TL peak, which necessitates a prior heat treatment. A single-aliquot regenerative-dose (SAR) protocol is developed and tested using thermal treatments intended to isolate a stable dosimetric signal. A minimum detection limit of ～65 mGy is then estimated using this protocol. Following irradiation using ⁶⁰Co and ¹³⁷Cs, dose–depth profiles were measured on two different commercial brick types (Mishima – Renga – Seizoujyo Co. and Hase – Renga Co.) with 5 Gy and 10 Gy surface doses. The profiles derived from the two sources were readily distinguishable. It is concluded that the OSL signals from the two types of Japanese brick quartz examined here can be used to derive precise estimates of accident dose, and, possibly to distinguish between sources of gamma radiation in a nuclear accident.To our knowledge, this is the first report on the existence of an unstable fast decaying OSL signal in quartz derived from bricks, and demonstrates a way forward with such samples in retrospective dosimetry.     

Simple and environmentally friendly preparation and size control of silver nanoparticles using an inhomogeneous system with silver-containing glass powder

A simple, environmentally friendly method for preparing highly size-controlled spherical silver nanoparticles was developed that involved heating a mixture of silver-containing glass powder and an aqueous solution of glucose. The stabilizing agent for silver nanoparticles was found to be caramel, which was generated from glucose when preparing the nanoparticles. The particle size was independent of the reaction time, but it increased proportionally with the square root of the glucose concentration in the range 0.25–8.0 wt% (corresponding to particle sizes of 3.48 ± 1.83 to 20.0 ± 2.76 nm). Difference of the generation mechanism of silver nanoparticles between this inhomogeneous system and a system in which Ag⁺ was homogeneously dispersed was discussed.