Die gas-chromatographische Abtrennung und Bestimmung der Milchs?ure

Ohne Zusammenfassung     

EPR observation of a high temperature phase transition in Zn(ClO4)2·6H2O:Mn2+

The electron paramagnetic resonance of Mn²⁺ doped in single crystals of Zn(ClO₄)₂·6H₂O has been studied at X-band in the temperature range 300–380 K. A phase transition, observed at ～ 346 K, is reported for the first time.     

Zum Nachweis von Nanogrammengen Resochin

Ohne Zusammenfassung     

Einen Beitrag zur gaschromatographischen Analyse des ?les von Monarda punctata L

Ohne Zusammenfassung     

Ferroelectric soft-mode contribution to zero-field splitting: Paramagnetic resonance investigation of phase transition in Mn2+-doped NaNO2

The contribution of the ferroelectric soft-mode to the zero-field splitting is calculated and separated from the thermal contribution arising from the splitting due to the electron-phonon interaction. The predicted effect is compared with the measured values in Mn²⁺-doped NaNO₂.     

beta-Sheet mediated self-assembly of dipeptides of omega-amino acids and remarkable fibrillation in the solid state

Single crystal X-ray diffraction studies show that the extended structure of dipeptide Boc-beta-Ala-m-ABA-OMe (m-ABA: meta-aminobenzoic acid) self-assembles in the solid state by intermolecular hydrogen bonding to create an infinite parallel beta-sheet structure. In dipeptide Boc-gamma-Abu-m-ABA-OMe (gamma-Abu: gamma-aminobutyric acid), two such parallel beta-sheets are further cross-linked by intermolecular hydrogen bonding through m-aminobenzoic acid moieties. SEM (scanning electron microscopy) studies reveal that both the peptides and form amyloid-like fibrils in the solid state. The fibrils are also found to be stained readily by Congo red, a characteristic feature of the amyloid fiber whose accumulation causes several fatal diseases such as Alzheimer's, prion-protein etc.     

Stimulated and spontaneous optical generation of electron spin coherence in charged GaAs quantum dots

We report on the coherent optical excitation of electron spin polarization in the ground state of charged GaAs quantum dots via an intermediate charged exciton (trion) state. Coherent optical fields are used for the creation and detection of the Raman spin coherence between the spin ground states of the charged quantum dot. The measured spin decoherence time, which is likely limited by the nature of the spin ensemble, approaches 10 ns at zero field. We also show that the Raman spin coherence in the quantum beats is caused not only by the usual stimulated Raman interaction but also by simultaneous spontaneous radiative decay of either excited trion state to a coherent combination of the two spin states.     

A revised model for the paired-electron gas plasma in a magnetic field and its application to experimental determinations on weakly ionized rare-gas plasmas

Summary The formation of electron pairs at the glass walls of the enclosing container in a low-pressure, high-frequency, electrodeless, rare-gas discharge is discussed. The pairs drift towards the discharge tube axis under the acceleration of the weak radial-space-charge electric field. The properties of the gas in an uniform magnetic field are outlined in a model which is subsequently applied to experimental data from four different experiments in four rare gases. Determinations of plasma parameters from the analyses of the experiments are found to agree. The values for the pair aggregation number,n′, for the excited plasmas on the tube axis range from one at low-power excitation to between ten and twenty at higher powers. In the afterglow plasmas following the cessation of the energizing current pulse (which is typically 20 ms in duration), the aggregation number varies from one in the body of the gas to between one and five on the tube axis. The direct evidence for the presence of electron pairs, and aggregates of electron pairs, is obtained from the ≪spin-flip≫ of single electrons of a pair in a magnetic field, an event which destroys the pair, or pair aggregate, and the associated experimental phenomena.

---

Riassunto Si discute la formazione di coppie di elettroni, sulle pareti di vetro del contenitore circostante in una discarica a bassa pressione, alta frequenza, senza elettrodi e a gas rari. Le coppie si spostano verso l’asse del tubo della discarica con l’accelerazione del campo elettrico debole con carica di spazio radiale. Le proprietà del gas in un campo magnetico uniforme sono sottolineate in un modello che è successivamente applicato a dati sperimentali da quattro diversi esperimenti in quattro gas rari. Si trova che i valori dei parametri del plasma dalle analisi degli esperimenti sono in accordo. I valori del numero di aggregazione della coppia,n′, per i plasma eccitati sugli assi del tubo variano da 1 ad eccitazione a bassa potenza a 10÷20 ad alte potenze. Nei plasmi a fluorescenza che seguono la cessazione dell’impulso di corrente energizzante (che dura tipicamente 20 ms) il numero di aggregazione varia da uno nel corpo del gas a 1÷5 sull’asse del tubo. La prova diretta della presenza delle coppie di elettroni, e di aggregati di coppie di elettroni è ottenuta dallo ≪spin-flip≫ di elettroni singoli di una coppia in un campo magnetico, un evento che distrugge la coppia, o l’aggregato di coppie, e dagli associati fenomeni sperimentali.

---

Резюме Обсуждается образование электронных пар на стеклянных стенках замкнутого контейнера при высокочастотном, безэлектродном разряде в разреженном газе при низком давлении. Пары дрейфуют по направлению к оси разрядной трубки под действием электрического поля слабого радиального пространственного заряда. Описываются свойства газа в однородном магнитном поле, используя модель, которая впоследствии применяется к экспериментальным данным из четырех различных экспериментов, проведенных для четырех разреженных газов. Обнаружено хорошее согласие при определении параметроб плазмы из анализа указанных экспериментов. Значения для числа электронных пар в агрегации,n′, для возбужденной плазмы на оси трубки изменяется от единицы при инзкой степени возбуждения до величины между десятью и двадцатью при высоких степенях возбуждения. При послесвечении плазмы, после прекращения возбуждающего имлульса тока (который обычно имеет длительность 20 мс), число пар в агрегации изменяется от единицы в объеме газа до величины между единицей и пятью на оси трубки. Получено прямое подтверждение для наличия электронных пар и агрегаций электронных пар из изменения ориентции спина отдельных злектронов пары в магнитном поле, т.е. из события, которое разрушает пару или агрегации рар, и из связанных экспериментальных явлений.