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81.
82.
Shohji Tsushima Fumiteru Akamatsu Masashi Katsuki Yukio Mizutani Yong-Dae Cho 《Particle & Particle Systems Characterization》1997,14(5):225-232
The objectives of the present study were to clarify the influence of flames on phase-Doppler anemometry (PDA) and to consider quantitatively the accuracy of measured sizes and velocities using a known-size polystyrene particle and a Bunsen burner placed in the optical path in PDA simulating the variation of refractive index in a combusting field. It was found that fluctuations of a flame had some influence on the measurement, especially on size, while the velocities obtained in these experiments showed little influence of the flame. Furthermore, a compensation procedure for the error was discussed by comparing the scattered data in size measurement with the displacement of incident laser beams. As a result, it was found that the displacement of the laser beams can be related to the degree of errors caused by the influence of a flame on the optical path in PDA. 相似文献
83.
总结了1990年6月到1993年10月期间西藏空气簇射阵列的观测结果。寻找了来自于蟹状星云、X射线双星、脉冲星、活动星系核和其它活动天体的能量为10TeVγ射线连续发射,没有发现连续稳定发射的迹象,但给出了每个源的流强上限。在阵列所观测的天区寻找了10TeV的γ暴,结果没有发现能量10TeV的γ暴,最后也给出了发现此种γ暴的上限。应用该阵列,明显地观测到了能量为10TeV的宇宙线流强的太阳和月亮阴影。观测了朝向和远离太阳的行星际空间磁场对宇宙线阴影的影响,这是行星际磁场对阴影位移影响的第一次直接观测。研究并发现在实验期间,太阳阴影的位置每年都在变化。同时观测在此期间,朝向和远离方向的宇宙线阴影的不同变化。另外,应用该实验的数据,给出了所谓的“膝”区的原初宇宙线能谱。 相似文献
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87.
Kazuhiko Kandori Akemi Yasukawa Tatsuo Ishikawa 《Journal of colloid and interface science》1996,180(2):446
The structure and properties of hematite particles obtained by hydrolysis of ferric chloride solution doped with various kinds of amines were examined by TEM, XRD, TG-DTA, N2and H2O adsorption, and zeta potential measurements. The shape of precipitates was concentration dependent; they changed from large spheres (diameter: ca. 820 nm) to cubes (edge length: ca. 400 nm) via double-spheres (long axis length: ca. 600 nm) with increasing monoamine concentrations. This effect was enhanced by increasing their pKavalues. Much pronounced effects of di- and triamines on the particle formation were observed; cubic and double-spherical particles were obtained at a much lower concentration of di- and triamines and small spherical (diameter: ca. 100 nm) and diamond-like (long axis length: ca. 100 nm) particles were further produced at higher concentration. It was suggested that the acceleration of the rate of phase transformation from β-FeOOH to hematite induced by amines plays an important role for producing fairly uniform hematite particles with different shape and size. The hematite particles produced with amines contained small amounts of OH−ions in the lattice but were confirmed to be nearly single crystal. 相似文献
88.
The triangular six-electron cluster complex [Mo3S4Cl4(PEt3)
x
(thf)5] produced by the excision reaction of Mo3S7Cl4 with triethypholsphine is reduced by magnesium at – 20°C. Subsequent addition of dppe (=1,2-his(diphenylphosphino)ethane) to the reduced species affords a seven-electron triangular cluster complex [Mo3S4Cl3(dppe)2(PEt3)]. The complex crystallizes in the space groupCm witha=17.170(6),b-19.878(6),c = 13.289(5) = 121.73(2)°,V = 3858(2) A3, andZ = 2. The structure shows an almost equilateral triangle of three molybdenum atoms capped by a Sulfur atom and bridged by three sulfur atoms. The Mo Mo distances, ranging from 2.804(1) to 2.809(1) A are elongated ca. 0.04 A as compared with lose of a six-electron cluster complex with drape ligands. Two molybdenum atoms have a chlorine and a dppe ligands, and the other molybdenum atom bas a chlorine and a triethylphosphine ligands. The UV-Vis spectrum has a characteristic broad hand centered at 1410 n m, which is not observed for six-electron clusters. The ESR spectrum indicates the presence of an unpaired electron consistent with the formulation of the compound as a seven-electron cluster.Dedicated to Professor fiaxi Lu on the occasion of his 80th birthday. 相似文献
89.
Hojo H Matsumoto Y Nakahara Y Ito E Suzuki Y Suzuki M Suzuki A Nakahara Y 《Journal of the American Chemical Society》2005,127(39):13720-13725
Peptide thioester corresponding to a MUC2 tandem repeat unit, which retains seven GalNAc moieties, was prepared by the Fmoc method followed by the low TfOH treatment to remove benzyl groups at the carbohydrate portions. The glycosylated peptide thioester was then consecutively joined by the activation of a thioester group by silver ions to obtain a MUC2 tandem repeat model composed of 141 amino acids with 42 GalNAc moieties. 相似文献
90.
Akemi YasukawaKaori Kamiuchi Takashi YokoyamaTatsuo Ishikawa 《Journal of solid state chemistry》2002,163(1):27-32
Lead-calcium hydroxyapatite solid solutions with different Pb/(Pb+Ca) molar ratios (XPb) were prepared by a wet method using acetamide (AA). The crystal phase and structure of the products depended on the aging period (ta), Pb/(Pb+Ca) molar ratio ([XPb]), and AA concentration ([AA]) of the starting solution. At [AA]=1.6 mol dm−3 and ta=6 days, the large needle-like PbCaHap particles were formed from solutions at [XPb]=0-0.6 and 0.9-1. Under the other AA concentrations and aging periods, pure PbCaHap particles could be obtained in a narrower region of [XPb]; e.g., PbCaHap was formed from solutions at [AA]=0.8 mol dm−3, ta=6 days, and [XPb]= 0-0.1, 0.4-0.5, and 0.9-1. 相似文献