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71.
Sattar Ebrahimi Akbar Mobinikhaldei Naser Foroughifar 《Journal of heterocyclic chemistry》2012,49(4):955-958
A practical and regioselective synthetic method for the synthesis of cis‐diastereomers of bibracchial lariat ethers (BiBLEs) bearing ester and amide groups is reported. The novel BiBLEs 3a and 4a–e with neutral side arms were prepared by reaction of the corresponding aza‐crown macrocycles 1a – c with ethylchlroacetate and chloroacetamide. The structures of the new compounds have been confirmed by FTIR, 1H, 13C, DEPT, and MS spectroscopy. 相似文献
72.
A new, one-pot multicomponent reaction of two molecules of aromatic aldehydes with 2,7-naphthalenediol and ammonium hydrogen phosphate is described as an efficient and direct procedure for the preparation of novel 1,3-diphenyl-2-azaphenalene derivatives in a mixture of EtOH-H2O (3:1) under reflux conditions. 相似文献
73.
Synthesis of some novel 1,2,4‐triazoles, 1,3,4‐oxadiazoles and 1,3,4‐thiadiazoles bearing a (R) 5‐(1‐(4‐(5‐chloro‐3‐fluoropyridin‐2‐yloxy)phenoxy)ethyl) unit, as a moiety of commercial herbicide, using their thiosemicarbazides in an alkaline, iodine and acidic media is reported, respectively. The structure of the synthesized compounds was characterized by IR, 1H, 13C NMR spectroscopic data, and elemental analyses. The herbicidal activities of synthesized compounds were evaluated against Echinochloa cruss‐galli, Avena fatua, and Sorgum halepense weeds. Compounds 7 and 12a showed potential herbicidal activity against gramineous weeds. Our results may provide some guidance for synthesis development of some novel oxa or thiadiazole and triazole‐based herbicidal lead structures. 相似文献
74.
Cr doped TiO2-SiO2 nanostructure thin film on glass substrates was prepared by a sol-gel dip coating process. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to characterize the structural and chemical properties of the films. A UV-vis spectrophotometer was used to measure the transmittance spectra of the thin film. The hydrophilicity of the thin film during irradiation and storage in a dark place was measured by a contact angle analyzer. The results indicated that Cr doping has a significant effect on the transmittance and super-hydrophilicity of TiO2-SiO2 thin film. 相似文献
75.
Ali Akbar Ashkarran 《Applied Physics A: Materials Science & Processing》2012,107(2):401-410
Ag:ZnO hybrid nanostructures were successfully prepared by a twice arc discharge method in liquid. The visible light photocatalytic
activities were successfully demonstrated for the degradation of Rhodamine B (Rh. B), Methyl orange (MO), and Methylene blue
(MB) as standard organic compounds under the irradiation of 90 W halogen light for 2 h. The Ag:ZnO nanostructures were characterized
by X-Ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and ultraviolet-visible
absorption spectroscopy (UV-Vis). The results revealed that the Ag:ZnO nanostructures extended the light absorption spectrum
toward the visible region and significantly enhanced the Rh. B photodegradation under visible light irradiation. 3 mM Ag:ZnO
nanostructures exhibited highest photocatalytic efficiency. It has been confirmed that the Ag:ZnO nanostructures could be
excited by visible light (E<3.3 eV). The significant enhancement in the Ag:ZnO nanostructures photocatalytic activity under visible light irradiation
can be ascribed to the effect of physisorbed noble metal Ag by acting as electron traps in ZnO band gap. A mechanism for photocatalytic
degradation of organic pollutant over Ag:ZnO photocatalyst was proposed based on our observations. 相似文献
76.
Saraji M Khalili Boroujeni M Hajialiakbari Bidgoli AA 《Analytical and bioanalytical chemistry》2011,400(7):2149-2158
Dispersive liquid–liquid microextraction (DLLME) and hollow fiber liquid–liquid–liquid microextraction (HF-LLLME) combined
with HPLC–DAD have been applied for the determination of three narcotic drugs (alfentanil, fentanyl, and sufentanil) in biological
samples (human plasma and urine). Different DLLME parameters influencing the extraction efficiency such as type and volume
of the extraction solvent and the disperser solvent, concentration of NaOH, and salt addition were investigated. In the HF-LLLME,
the effects of important parameters including organic solvent type, concentration of NaOH as donor solution, concentration
of H2SO4 as acceptor phase, salt addition, stirring rate, temperature, and extraction time were investigated and optimized. The results
showed that both extraction methods exhibited good linearity, precision, enrichment factor, and detection limit. Under optimal
condition, the limits of detection ranged from 0.4 to 1.9 μg/L and from 1.1 to 2.3 μg/L for DLLME and HF-LLLME, respectively.
For DLLME, the intra- and inter-day precisions were 1.7–6.4% and 14.2–15.9%, respectively; and for HF-LLLME were 0.7–5.2%
and 3.3–10.1%, respectively. The enrichment factors were from 275 to 325 and 190 to 237 for DLLME and HF-LLLME, respectively.
The applicability of the proposed methods was investigated by analyzing biological samples. For analysis of human plasma and
urine samples, HF-LLLME showed higher precision, more effective sample clean-up, higher extraction efficiency, lower organic
solvent consumption than DLLME. 相似文献
77.
Isotropic Berwald metrics are as a generalization of Berwald metrics. Shen proved that every Berwald metric is of vanishing S-curvature. In this paper, we generalize this fact and prove that every isotropic Berwald metric is of isotropic S-curvature. Let F = α + β be a Randers metric of isotropic Berwald curvature. Then it corresponds to a conformal vector field through navigation representation. 相似文献
78.
79.
The effects of Mg, La and Ca promoters on primary and secondary CO_2 and H_2O formation pathways during Fischer-Tropsch synthesis on precipitated Fe/Cu/SiO_2 catalysts are investigated. The chemisorbed oxygen atoms in the primary pathway formed in the CO dissociation steps reacted with co-adsorbed hydrogen or carbon monoxide to produce H_2O and CO_2 , respectively. The secondary pathway was the water-gas shift reaction. The results indicated that the CO_2 production led to an increase in both primary and secondary pathways, and H_2 O production
decreased when surface basicity of the catalyst increased in the order Ca >Mg >La. 相似文献
80.
The synthesis and structural characterization of dendritic macromolecules based on 3,5-dihydroxybenzoic acid are described. The molecular structures and purity of all new compounds were confirmed by 1H NMR, 13C NMR spectroscopy and elemental analysis. The dendritic non-covalent liquid crystalline complexes were prepared through the formation of hydrogen bonds between different generation of dendritic acids (proton donor) and stilbazole derivative containing bipyridyl units (proton acceptor). We found that, the hydrogen-bonded dendritic liquid crystals supramolecules (G1-2py, G2-2py and G3-2py) exhibits nematic and semectic phase. The polarizing optical microscopy (POM) and differential scanning calorimetry (DSC) were used for investigation of the liquid crystalline properties of the hydrogen-bonded dendritic supramolecular complexes. 相似文献