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31.
M. N. Cheema M. Mufazzal Saeed Akbar Ali Munir Ahmed 《Journal of Radioanalytical and Nuclear Chemistry》1994,178(1):153-163
Extraction of Hg(II), Se(IV), Mn(II) and Co(II) has been carried out with 1-phenyl-3-methyl-4-trifluoroacetyl-2-pyrazolin-5-one (HPMTFP) and triphenylphosphine oxide (TPPO) into chloroform from pH 1–10. Quantitative extraction of Hg(II), Mn(II) and Co(II) at pH 4 with equimolar 0.05M (PMTFP+TPPO) in chloroform was observed. Se(IV) remains unextracted at this pH range. The stoichiometric composition of the extracted complexes M(PMTFP)2·nH2O (M=Mn, Hg), M(PMTFP)2·2TPPO (M=Mn and Co) and Co(PMTFP)2·TPPO·H2O at less than 0.1M TPPO has been established. The formation constantsK
m,0 andK
m,n and stability constants
m,n have been computed. The analytical method developed was applied to the IAEA standard reference material (SRM) potato fluor V-4 for the determination of these elements using NAA technique. 相似文献
32.
Kazem D. Safa Mohammad Shahrivar Shahin Tofangdarzadeh Akbar Hassanpour 《Tetrahedron》2007,63(15):3189-3194
Metalation of (HSiMe2)3CH with lithium diisopropylamide (LDA) in THF gives (HSiMe2)3CLi, which reacts with ethylene oxide, propylene oxide, 1,2-epoxy butane, 1,2-epoxy pentane, 1,2-epoxy hexane, and epichlorohydrin to give the corresponding 1-oxa-2-silacyclopentane derivatives. Then, glycidylmethacrylate (GM) random copolymers with styrene (St) (in a 1:1 and 1:3 mol ratio) were synthesized by solution free radical polymerization at 70(±1) °C using α,α′-azobis(isobutyronitrile) (AIBN) as an initiator. Both types of copolymers were treated with (HSiMe2)3CLi to give new modified copolymers. The reaction of (HSiMe2)3CLi with epoxides on the side chains of the copolymers does not lead to intramolecular nucleophilic attack contrary to simple epoxides. All the products have been characterized by spectroscopic techniques. 相似文献
33.
Shariff?E.?KabirEmail author M.?Arzu?Miah M.?Abdur?Rahim Sonia?Sultana G.?M.?Golzar?Hossain Ebbe?Nordlander Edward?Rosenberg 《Journal of Cluster Science》2005,16(1):93-110
Treatment of Ru3(CO)12 with dpphSe2 (dpph = 1,6-bis(diphenylphosphino)hexane) in refluxing toluene in the presence of Me3NO afforded two new compounds, Ru3(CO)7(-CO)(3-Se)(-dpph) (1) and Ru3(CO)7(3-Se)2(-dpph) (2). A similar reaction of Ru3(CO)12 with dpppeSe2 (dpppe = 1,5-bis(diphenylphosphino)pentane) gave exclusively Ru3(CO)7(3-Se)2(-dpppe) (3). Treatment of Ru3(CO)12 with dpphS2 and dpppeS2 at 110°C in the presence of Me3NO afforded Ru3(CO)7(3-S)2(-dpph) (4) and Ru3(CO)7(3-S)2(-dpppe) (5), respectively. Reactions of Fe3(CO)12 with dpphSe2 and dpppeSe2, under identical conditions, afforded Fe3(CO)7(3-Se)2(-dpph) (6) and Fe3(CO)7(3-Se)2(-dpppe) (7), respectively. Compounds 1–7 were characterized spectroscopically and the molecular structures of compounds 1–4 were determined by single crystal X-ray crystallography. The core of 1 contains an equilateral triangle of ruthenium atoms with one capping selenium, one bridging dpph, one doubly bridging carbonyl and seven terminal carbonyl ligands. Complexes 2–4 have a square-pyramidal structure with two metal and two chalcogenide atoms alternating in the basal plane and the third metal atom at the apex of the pyramid, and belong to the family of well-known nido clusters with seven skeletal electron pairs. 相似文献
34.
Noorjahan Begum Amarash C. Ghosh Shariff E. Kabir Md. Arzu Miah G.M. Golzar Hossain 《Polyhedron》2005,24(18):3074-3081
Four triosmium carbonyl clusters bearing terminal pyrazines, bridging hydroxy and methoxycarbonyl ligands of general formula [Os3(CO)9(μ-OH)(μ-OMeCO)L] (1, L = pyrazine; 2, L = 2-methylpyrazine; 3, L = 2,3-dimethylpyrazine; 4, L = 2,3,5-trimethylpyrazine) were synthesized by the reactions of [Os3(CO)12] with the corresponding pyrazine derivatives and water in the presence of a methanolic solution of Me3NO in moderate yields. Compounds [Os3(CO)9(μ-OH)(μ-OMeCO)L] react with a series of two electron donor ligands, L′ at ambient temperature to give [Os3(CO)9(μ-OH)(μ-OMeCO)L′] (5, L′ = PPh3; 6, L′ = P(OMe)3; 7, L′ = tBuNC; 8, L′ = C5H5N) in good yields by the displacement of the pyrazine ligands. This implies that the pyrazine ligands in 1–4 are relatively labile. Compounds 2, 3, 4, and 8 were characterized by single crystal X-ray diffraction analyses. All the four compounds possess two metal–metal bonds and a non-bonded separation of two osmium atoms defined by Os(1)Os(3), which are simultaneously bridged by OH and MeOCO ligands and a heterocyclic ligand is terminally coordinated to one of the two non-bonded osmium atoms. 相似文献
35.
36.
Ali Mohammad Akbar Edwards Alice A. Tuah Jauyah Hossain Mir Ezharul Nazimuddin Mohamed 《Transition Metal Chemistry》1997,23(1):41-44
A new, potentially polydentate sulfur–nitrogen chelating agent, 2,6–bis(N-methyl-S-methyldithiocarbazato)pyridine (L) has
been synthesized and characterized. With nickel(II) salts, the ligand yields complexes of empirical formula NiLX2·nH2O (X=Cl−,
NCS− or NO3−; n=0 or 1) in which it behaves as a quadridentate NSSN chelating agent, coordinating to the nickel(II) ion via
the two amino nitrogen atoms and the two sulfur atoms. Magnetic and spectral evidence support a distorted octahedral structure
for these complexes. The ligand reacts with copper(II), platinum(II) and palladium(II) salts to yield homo-binuclear complexes
of general formula [M2LX4]·nSol (M=CuII, PtII or PdII; X=Cl− or Br−; n=0.5, 1 or 2; Sol=H2O, MeOH or MeCOMe), in which each
of the metal ions is in a square-planar environment. These complexes have been characterized by a variety of physicochemical
techniques.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
37.
Ali Mohammad Akbar Mirza Aminul Huq Keng See Tho Wai Butcher Raymond J. 《Transition Metal Chemistry》2003,28(2):241-245
Condensation of 2,6-diacetylpyridine (dap) with S-methyldithiocarbazate (smdtc) in a 1:2 molar ratio yields a bicondensed pentadentate Schiff base (H2dapsme) which reacts with K2MCl4 (M = PdII, PtII) giving stable complexes of empirical formula, [M(dapsme)] · 0.5Me2CO. These complexes have been characterized by a variety of physico-chemical techniques. Condensation of dap with smdtc in a 1:1 molar ratio also yields the bicondensed Schiff base (H2dapsme) as the major product, but a mono-condensed one-armed Schiff base (Hmdapsme) is also obtained as a minor product. The latter reacts with K2PdCl4 in an EtOH–H2O mixture yielding a crystalline complex of empirical formula, [Pd(mdapsme)Cl], the crystal structure of which has been determined by X-ray diffraction. The complex has a distorted square-planar structure in which the ligand is coordinated to the palladium(II) ion as a uninegatively charged tridentate chelating agent via the pyridine nitrogen atom, the azomethine nitrogen atom and the thiolate sulfur atom; the oxygen atom of the acetyl group does not participate in coordination. 相似文献
38.
Six known metabolites, two new isocoumarins 4 and 8, and one new highly substituted benzoic acid derivative 9 were isolated from the ethyl acetate culture extract of a fungal endophyte, Scytalidium sp. In addition, another new benzoic acid 10 with an unusual 1,2-dicarbonyl side chain was indirectly identified from its methylated derivatives 10a-10d. 相似文献
39.
Habib-ur- Rehman Akbar Ali Jamil Anwar Wasim Yawar 《Journal of Radioanalytical and Nuclear Chemistry》2006,267(2):421-425
Summary The synergistic mixture comprising picrolonic acid (HPA) and benzo-15-crown-5 (B15C5) in chloroform has been used for the
extraction of Ce(III), Eu(III) and Tm(III) as representatives of lanthanide(III) ions from pH 1-2 solutions having ionic strength
of 0.1 mol. dm-3(K+/H+, Cl-). The composition of the extracted species has been determined as M(PA)3. nB15C5 where M is Ce, Eu and Tm and n=1 or 2. The influence of various anions and cations on the extraction of these ions has also been studied and only oxalate,
cyanide and tartrate have some deleterious effect. The extraction equilibrium constants have been evaluated and discussed. 相似文献
40.
Akbar Ali Mohammad Huq Mirza Aminul Nazimuddin Mohamed Rahman Hafazatur Butcher Raymond J. 《Transition Metal Chemistry》2002,27(3):268-273
New cadmium(II) complexes of empirical formulae, [Cd(dpksme)X] (dpksme = anionic form of the Schiff base; X = NCS–, Cl–, I–) and [Cd(dpksme)2] · 0.5MeOH, respectively have been prepared and characterized. The mono-ligated cadmium(II) complexes, [Cd(dpksme)X] are four-coordinate and tetrahedral but the bis-ligand complex, [Cd(dpksme)2] · 0.5MeOH is six-coordinate and octahedral. The crystal and molecular structure of [Cd(dpksme)2] · 0.5MeOH has been determined by X-ray diffraction. The complex has a distorted mer-octahedral structure in which the ligands are coordinated as uninegatively charged tridentate chelating agents via the pyridine nitrogen atoms, the azomethine nitrogen atoms and the thiolate sulfur atoms. The distortion from regular octahedral geometry is ascribed to the restricted bite angles of the ligands. The Schiff base and its cadmium(II) complexes exhibit mild antibacterial activities against Shigella dysenteriae, Bacillus cereus, Staphylococcus aureus and Escherichia coli. They are also mildly fungitoxic against the phytopathogenic fungi, Alternaria alternata and Macrophomina phaseolina. 相似文献