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71.
The molecular structure of 1,2,4-triazole has been determined by gas phase electron diffraction. The intemuclear distances and bond angles were obtained by applying a least-squares analysis to the experimental intensity. The bond distances (rg) and bond angles were N1-N2 = 1.380 ± 0.010 Å, N2C3 = 1.329 ± 0.009 Å, C3-N4 = 1.348 ± 0.009 Å, N1-C5 = 1.377 ± 0.004 Å, N4C5 = 1.305 Å (calculated value). N-H = 0.990 Å, C-H = 1.054 Å, ∠N1N2C3 = 102.7± 0.5°, ∠N2C3N4 = 113.8 ± 1.3°, ∠N2N1C5 = 108.9 ± 0.8°, ∠H1N1N2 = 110.9°, ∠H2C3N4 = 119.2°, ∠H3C5N1 = 131.0°, ∠C3N4C5 = 105.7° (calculated value) and ∠N4C5N1 = 108.7° (calculated value). 相似文献
72.
LetA be a noetherian ring. In generalA will not admit a classical Artinian ring of quotients. Yet a problem in enveloping algebras leads one to consider the possible
embedding ofA in a prime ringB which is finitely generated as a left and a rightA module. Under certain additional technical assumptions, it is shown that the setS of regular elements ofA is regular inB and is an Ore set in bothA andB withS
−1
A andS
−1
B Artinian. This enables one to establish the following additivity principle for Goldie rank. Let {P
1,P
2, …P
1} be the set of minimal primes ofA. Then under the above conditions it is shown that there exist positive integersz
1,z
2, …,z, such that
, where rk denotes Goldie rank. This applies to the study of primitive ideals in the enveloping algebra of a complex semisimple
Lie algebra.
This paper was written while the authors were guests of the Institute for Advanced Studies, The Hebrew University of Jerusalem.
The first author was on leave of absence from the Centre Nationale de la Recherche Scientifique, France. 相似文献
73.
74.
The elimination of CH3COOH from the molecular ions of trans-3- and 4-arylcyclohexyl acetates takes place to a greater extent than in the cis isomers. Deuterium labelling shows that the elimination involves mainly the benzylic hydrogen in the trans-acetates, but not in the cis isomers. This behaviour is similar qualitatively to that of the corresponding alcohols and methyl ethers, but entirely different from that of t-butylcyclohexyl acetates, which do not exhibit any stereospecificity. Substituent effects on the elimination for both cis and trans isomers are discussed. 相似文献
75.
The elimination of H20 from the molecular ions of trans-4- and trans-3-arylcyclohexanois takes place to a greater extent than in the corresponding cis isomers. The remarkable differences in abundance taken together with substituent effects and the results of deuterium labelling, show that configuration is retained in the molecular ions which undergo the elimination, and that this process is a cis-1,4 and cis-1,3 elimination in the trans-4- and trans-3- arylcyclohexanois, respectively. Possible mechanisms for the elimination in the cis isomers are discussed. 相似文献
76.
2,2′-Biquinoline dioxide and 4,4′-dichloro-2,2′-biquinoline have been used for the preparation of the following 4,4′-disubstituted-2,2′-biquinolines: dimethoxy, diethoxy, dihydroxy, dipiperidino, dipyrrolidino, dibromo, diphenoxy, dithiophenoxy, di(p-chloro-phenoxy), di(p-bromophenoxy), di(p-fluorophenoxy), di(β-naphthoxy) and the dinitro dioxide. Molar extinction coefficients have been determined for several of the copper (I) complexes of these compounds. 相似文献
77.
Joseph P. Kennedy Kenneth F. Castner 《Journal of polymer science. Part A, Polymer chemistry》1979,17(7):2039-2054
The reaction between tert-butylchloride (t-BuCl) and dimethylcyclopentadienylaluminum (Me2AlCPD) was studied as a model for initiation by the tert-butyl cation (t-Bu⊕) and termination by cyclopentadienylation by the Me2Al(CPD)Cl? counteranion of isobutylene polymerization. All reaction products formed in this model system have been identified and quantitatively determined. A comprehensive scheme that indicates pathways to these products was developed (scheme III). It is proposed that the predominant product, tert-butylcyclopentadiene (t-BuCPD), arises in the collapse of the t-Bu⊕-Me2Al(CPD)Cl? ion pair, mainly by CPD? transfer to the tert-butyl cation. The minor products are neopentane (t-BuMe) and isobutylene (i-C4H8), which are probably formed, respectively, by Me? transfer to and proton loss from the t-butyl cation. Cyclopentadienylation selectivity increases by lowering the temperature and extrapolation of results suggests 100% cyclopentadienylation at ?55°C. The t-BuCl/Me2AlCPD ratio strongly influences the overall reaction pathway. The reaction is first order in t-BuCl with ΔEa of ca. 7 kcal/mole (1,2-dichloroethane or chlorobenzene solvents, +24 to ?29°C). Indirect evidence indicates that the kinetic product of cyclopentadienylation is 5-t-BuCPD and that this isomer cannot be tert-butylated; that is, the initiation of 5-t-BuCPD polymerization by t-Bu⊕ is sterically unfavorable. Detailed analysis of the chemistry and kinetics of the t-BuCl/Me2AlCPD model system holds important clues to the controlled polymerization of olefins leading to macromolecules with cyclopentadiene (CPD) termini. 相似文献
78.
Joseph Rosenblatt 《Mathematische Annalen》1977,230(3):245-272
For a mean zero norm one sequence (f
n
)L
2[0, 1], the sequence (f
n
{nx+y}) is an orthonormal sequence inL
2([0, 1]2); so if
, then
converges for a.e. (x, y)[0, 1]2 and has a maximal function inL
2([0, 1]2). But for a mean zerofL
2[0, 1], it is harder to give necessary and sufficient conditions for theL
2-norm convergence or a.e. convergence of
. Ifc
n
0 and
, then this series will not converge inL
2-norm on a denseG
subset of the mean zero functions inL
2[0, 1]. Also, there are mean zerofL[0, 1] such that
never converges and there is a mean zero continuous functionf with
a.e. However, iff is mean zero and of bounded variation or in some Lip() with 1/2<1, and if |c
n
| = 0(n
–) for >1/2, then
converges a.e. and unconditionally inL
2[0, 1]. In addition, for any mean zerof of bounded variation, the series
has its maximal function in allL
p[0, 1] with 1p<. Finally, if (f
n
)L
[0, 1] is a uniformly bounded mean zero sequence, then
is a necessary and sufficient condition for
to converge for a.e.y and a.e. (x
n
)[0, 1]. Moreover, iffL
[0, 1] is mean zero and
, then for a.e. (x
n
)[0, 1],
converges for a.e.y and in allL
p
[0, 1] with 1p<. Some of these theorems can be generalized simply to other compact groups besides [0, 1] under addition modulo one. 相似文献
79.
If a pointset of the projective spacePG(d,q), together with a lineset ofPG(d,q) form a generalized quadrangleS, thenS is of classical type. This beautiful theorem was proved by F. Buekenhout and C. Lefèvre. In this paper we give a simple proof of this theorem in the cased 4 (we suppose that the result is established ford = 3). We remark that in our proof a central role is played by the theory of subquadrangles. 相似文献
80.
An efficient asymmetric synthesis of selective estrogen receptor β-modulator (S)-4-bromo-9a-butyl-8-chloro-6-fluoro-7-hydroxy-1,2,9,9a-tetrahydro-fluoren-3-one was developed. The route features a chemoselective aromatic chlorination reaction, an asymmetric phase-transfer-catalyzed alkylation of an indanone with efficient ee upgrade by racemate crystallization, and a robust bromination reaction using imidazole as an in situ bromine trap to avoid overreaction. The synthesis proceeds in 34% yield over 8 steps from 2-fluoroanisole, and provides material with >99.5% ee. 相似文献