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91.
92.
In this paper a hybrid multiplexing technique has been presented that merges WDM and OTDM multiplexing technologies. The WDM-OTDM hybrid realizes wavelength parallel bus architecture and is inherent with features of high spectral efficiency, high scalability and bandwidth elasticity. Simulations and experiments were carried out to investigate the selection of most suitable modulation format, dispersion compensation technique and erbium doped fiber amplifier (EDFA) noise figure for WDM-OTDM hybrid, where link lengths exceeding 500 km at high Q-values was achieved. 相似文献
93.
Low‐temperature sol–gel transformation of methyl silicon precursors to silica‐based hybrid materials
Veena Dhayal Rakesh Bohra Meena Nagar Ajay Kaushik Sanjay Mathur Sven Barth 《应用有机金属化学》2008,22(11):629-636
Six new methyl silicon (IV) precursors of the type [MeSi{ON?C(R)Ar}3] [when R = Me, Ar = 2‐C5H4N ( 1 ), 2‐C4H3O ( 2 ) or 2‐C4H3S ( 3 ); and when R = H, Ar = 2‐C5H4N ( 4 ), 2‐C4H3O ( 5 ) or 2‐C4H3S ( 6 )] were prepared and structurally characterized by various spectroscopic techniques. Molecular weight measurements and FAB (Fast Atomic Bombardment) mass spectral studies indicated their monomeric nature. 1H and 13C{1H} NMR spectral studies suggested the oximate ligands to be monodentate in solution, which was confirmed by 29Si{1H} NMR signals in the region expected for tetra‐coordinated methylsilicon (IV) derivatives. Thermogravimetric analysis of 1 revealed the complex to be thermally labile, decomposing to a hybrid material of definite composition. Two representative compounds ( 2 and 4 ) were studied as single source molecular precursor for low‐temperature transformation to silica‐based hybrid materials using sol–gel technique. Formation of homogenous methyl‐bonded silica materials (MeSiO3/2) at low sintering temperature was observed. The thermogravimetric analysis of the methylsilica material indicated that silicon‐methyl bond is thermally stable up to a temperature of 400 °C. Reaction of 2 and Al(OPri)3 in equimolar ratio in anhydrous toluene yielded a brown‐colored viscous liquid of the composition [MeSi{ON?C(CH3)C4H3O}3.Al(OPri)3]. Spectroscopic techniques 1H, 13C{1H}, 27Al{1H} and 29Si{1H} NMR spectra of the viscous product indicated the presence of tetracoordination around both silicon and aluminum atoms. On hydrolysis it yielded methylated aluminosilicate material with high specific surface area (464 m2/g). Scanning electron micrography confirmed a regular porous structure with porosity in the nanometric range. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
94.
Periodic orbits belonging to the stromgren families A, B and C around the collinear libration points in the restricted three
body problem have been studied when the smaller primary is a triaxial rigid body and more massive body is a source of radiation
pressure. These families are determined in three different cases: (i) classical case, (ii) when bigger primary is a source
of radiation pressure, (iii) when smaller primary is a triaxial rigid body and bigger primary is a source of radiation pressure.
The Liapunov stability of each periodic solution has also been examined.
相似文献
95.
Birefringent filters can be used for tuning lasers, with some advantages over prisms, gratings and tilted etalons. In this paper the transmission characteristics of a new mixed birefringent filter are investigated. The term ‘mixed’ is used because both circular birefringence and linear birefringence have been utilized in the fabrication of this filter.It has a loss-less core, formed by a cascaded system of alternate rotators and retarders, and a linear polarizer at each end. The performance of this filter is better because of the more effective suppression of side peaks. Unlike previous birefringent filters, this one may be used inside a linear resonator. 相似文献
96.
S. Kapoor C. Gopinathan R. M. Iyer 《Journal of Radioanalytical and Nuclear Chemistry》1989,130(2):409-415
Trapped electron (e
T
–
) reactivity in methanol-isopropanol glasses irradiated at 77 K has been studied as a function of trap-depth, the variation in the trap depth being achieved by varying the methanol:isopropanol ratio. Benzyl chloride and carbon disulfide have been used as scavengers. In the case of the glasses containing benzyl chloride, the observed yield of the benzyl radical has been correlated with the trapping efficiency of the matrix. The data has been interpreted with the aim of assessing the relative importance of tunnelling in the scavenging of electrons in low temperature glassy matrices. 相似文献
97.
Pratibha Srivastava Inder Pal Singh Kapoor Gurdip Singh Roland Fröhlich 《Journal of Thermal Analysis and Calorimetry》2010,100(1):233-238
Phenylenediammonium dibromide (PDADBr) salts have been prepared and characterized by X-ray crystallography. The thermal decomposition
of PDADBr has been studied by thermogravimetry (TG) and differential thermal analysis (DTA). Kinetic parameters have been
evaluated using model fitting and isoconversional methods. The thermolytic pathways have also been suggested which involve
proton transfer as a primary step to regenerate parent amine and HBr. Interaction between amine and HBr at higher temperature
yields gaseous products. 相似文献
98.
Summary Zinc may be determined polarographically in acetate buffered solutions of PH 4 to 5.6.
Zusammenfassung Die polarographische Bestimmung von Zink ist möglich in mit Acetat gepufferten Lösungen vom PH 4 bis 5,6.
Résumé On peut doser le zinc par polarographie dans des solutions de pH 4 à 5,6 tamponnées à l'acétate.相似文献
99.
In line with current efforts to understand the piece-by-piece structure and articulation of children’s mathematical concepts, this case study compares the reversibility schemes of two eighth-grade students. The aim of the study was to identify the mechanism through which students reverse their thought processes in a multiplicative situation. Data collected through clinical interviews depict the precise strategies that the participants used to work back to find the missing values in an inverse proportional task. This study also illustrates how a conceptual template generated by one of the participants afforded him considerable flexibility in the multiplicative task. Another outcome of the study is that it shows how the numerical characteristics of the parameters in the problem affected the students’ ability to reverse their thought processes. We infer that there is a need for further research on how students might represent their reversibility schemes in the form of algebraic equations. 相似文献
100.
Vikas Kumar Mehak Gupta Sumit G. Gandhi Sonali S. Bharate Ajay Kumar Ram A. Vishwakarma Sandip B. Bharate 《Tetrahedron letters》2017,58(42):3974-3978
Herein we report isolation of a new chromone alkaloid chrotacumine K (12) from fruits and a chromone glycoside schumaniofioside A (13) from leaves of Dysoxylum binectariferum Hook f. Schumaniofioside A is reported for the first time from Meliaceae family. Other known alkaloids isolated include rohitukine (1) and chrotacumine E (6). The structure of new alkaloid 12 was elucidated on the basis of extensive 1D and 2D NMR analysis, synthesis and chemical hydrolysis. Chemically, chrotacumine K (12) is a 3′-O-acetyl rohitukine which on chemical or enzymatic hydrolysis produces rohitukine. The new alkaloid 12 is also present in seeds and stem-barks of this plant. The glycoside schumaniofioside A (13) is present only in leaves, and in abundance (~1% w/w of dried leaves). The isolated compounds and extracts were evaluated for in vitro effect on the proinflammatory cytokines (TNF-α and IL-6) in human monocytic THP-1 cells. The alkaloid 12 displayed potent inhibition (57%) of TNF-α at 0.3 µM, and was non-toxic to THP-1 cells up to 40 µM, indicating its excellent therapeutic window. Furthermore, a nitrobenzoyl ester analog 15e showed better inhibition of IL-6 than parent natural product chrotacumine K. 相似文献