General boundary stabilization of memory type in thermoelasticity of type III

In this paper, we consider a multi-dimensional system of thermoelasticity type III with a viscoelastic damping acting on a part of the boundary. We establish a general decay result, from which the usual exponential and polynomial decay rates are only special cases.     

Imidazole-modified porphyrin as a pH-responsive sensitizer for cancer photodynamic therapy

5,10,15,20-Tetrakis(N-(2-(1H-imidazol-4-yl)ethyl)benzamide)porphyrin produced twice as many singlet oxygen ((1)O(2)) molecules at pH 5.0 (quantum yield 0.53 ± 0.01) than at pH 7.4, whereas the (1)O(2) quenching rate was reduced by a factor of 2.5 for a pH change from 7.4 to 5.0.     

An efficient and simple approach for the synthesis of pyranopyrazoles using imidazole (catalytic) in aqueous medium, and the vibrational spectroscopic studies on 6-amino-4-(4'-methoxyphenyl)-5-cyano-3-methyl-1-phenyl-1,4-dihydropyrano[2,3-c]pyrazole using density functional theory

We describe a one-pot four component synthesis of pyranopyroles from aryl aldehydes, ethyl acetoacetate, malononitrile and hydrazine hydrate in the presence of catalytic amounts of an organocatalyst imidazole in water as medium. A plausible mechanism for the formation of imidazole catalyzed pyranopyrazoles has been envisaged. This method is rapid, simple, provides products in good yield, and is eco-friendly. In addition, based on the optimized geometry, the frequency and intensity of the vibrational bands of 6-amino-4-(4'-methoxyphenyl)-5-cyano-3-methyl-1-phenyl-1,4-dihydropyrano[2,3-c]pyrazole were obtained by the density functional theory (DFT) calculations using 6-31G(d,p) basis set. The vibrational frequencies were calculated and the scaled values have been compared with experimental FT-IR and FT-Raman spectra. The observed and the calculated frequencies are found to be in good agreement.     

Simulation in manufacturing and business: A review

This paper reports the results of a review of simulation applications published within peer-reviewed literature between 1997 and 2006 to provide an up-to-date picture of the role of simulation techniques within manufacturing and business. The review is characterised by three factors: wide coverage, broad scope of the simulation techniques, and a focus on real-world applications. A structured methodology was followed to narrow down the search from around 20,000 papers to 281. Results include interesting trends and patterns. For instance, although discrete event simulation is the most popular technique, it has lower stakeholder engagement than other techniques, such as system dynamics or gaming. This is highly correlated with modelling lead time and purpose. Considering application areas, modelling is mostly used in scheduling. Finally, this review shows an increasing interest in hybrid modelling as an approach to cope with complex enterprise-wide systems.     

NHC-Pd complex heterogenized on graphene oxide for cross-coupling reactions and supercapacitor applications

N-heterocyclic carbene (NHC)-palladium(II) complex (GO@NHC-Pd) was synthesized on graphene oxide (GO) support via a simple and cost-effective multistep approach. The spectroscopic, microscopic, thermal, and surface analyses of GO@NHC-Pd confirmed the successful formation of the catalyst. The investigation of catalytic activity showed that GO@NHC-Pd was very effective in Suzuki–Miyaura as well as Hiyama cross-coupling. Being heterogeneous in nature, GO@NHC-Pd was recovered after each reaction cycle easily and reused for up to nine and six cycles in Suzuki–Miyaura and Hiyama cross-coupling, respectively, without significant loss of activity. Further exploration of the supercapacitor performance of GO@NHC-Pd catalyst assembled in a two-electrode cell configuration shown a maximum attained capacitance of 105.26 F/g at a current density of 0.1 A/g with good cycling stability of 96.89% over 2,500 cycles.     

Examination of the role of intestinal fatty acid-binding protein in drug absorption using a parallel artificial membrane permeability assay

Transcellular diffusion across the absorptive epithelial cells (enterocytes) of the small intestine is the main route of absorption for most orally administered drugs. The process by which lipophilic compounds transverse the aqueous environment of the cytoplasm, however, remains poorly defined. In the present study, we have identified a structurally diverse group of lipophilic drugs that display low micromolar binding affinities for a cytosolic lipid-binding protein - intestinal fatty acid-binding protein (I-FABP). Binding to I-FABP significantly enhanced the transport of lipophilic drug molecules across a model membrane, and the degree of transport enhancement was related to both drug lipophilicity and I-FABP binding affinity. These data suggest that intracellular lipid-binding proteins such as I-FABP may enhance the membrane transport of lipophilic xenobiotics and facilitate drug access to the enterocyte cytoplasm and cytoplasmic organelles.     

Investigations of Viscous Dissipation in Stagnation Point Flow Past a Stretchable Riga Wall: Modern Analysis of Heat Transport

This article scrutinizes the features of viscous dissipation in the stagnation point flow past through a linearly stretched Riga wall by implementing Cattaneo-Christov heat flux model. Viscous dissipation is carried out in Cattaneo-Christov diffusion analysis for the first time in this letter. As a result of Cattaneo-Christov model, some extra terms of viscous dissipation are appeared in the energy equation. These extra terms of viscous dissipation are missing in the literature. On the utilization of suitable transformations, the equations governing the problem are reduced under the boundary layer approximation into the non-linear and dimensionless ordinary differential equations. Convergent approach is utilized to solve the dimensionless governing equations. The solution thus acquired is used to highlight the effects of emerging parameters on velocity distribution and fluid's temperature through the graphs. Features of the drag force (or skin friction co-efficient) are graphically interpreted. It is noticed that the presence of modified Hartman number helps to reduce the fluid's temperature but enhances the velocity profile. Further an enlargement in the value of thermal time relaxation parameter helps to decrease the temperature distribution.     

Step-wise laser excitation of the 4snf 3F Rydberg states of neutral zinc

The new experimental results on the effective quantum numbers and term energies of the highly excited odd-parity 4s4d ³D_1,2,3 →4snf ³F_2,3,4 Rydberg transitions of zinc have been presented. The experiment was performed using the three dye lasers simultaneously pumped by the second harmonic (532?nm) of the Q-switched Nd:YAG laser. The new observation includes the 4snf ³F₃ (12?≤n?≤?50) series excited from the 4s4d ³D₂ intermediate level. In addition, the 4snf ³F₂ (12?≤n?≤?28) and 4snf³F₄ (12?≤n?≤?33) series are observed from the thermally populated 4s4d ³D_1,3 fine structure components. The ionization potential of zinc has been determined from the unperturbed 4snf ³F₃ series as 75769.31?±?0.15?cm^?1, which is in excellent agreement with the previously reported value.     

Viscosity Effects on Anisotropic Universe in Curvature-Matter Coupling Gravity

In this paper, we study evolution of the universe in the background of f(R, T) gravity using LRS Bianchi type-Ⅰ model. We discuss scale factors as well as deceleration parameter in dark energy dominated era for different bulk viscosity models. The occurrence of big-rip singularity is also examined. It is concluded that expansion is faster when bulk viscosity is proportional to Hubble parameter as compared to other models.