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101.
Although the synthetic potential of the intramolecular variant of the Diels-Alder reaction has now been fully recognized3, little attention has so far been paid to this type of addition using the furan nucleus as the diene partner4–8. The presence of an oxygenated cyclohexene system in several complex natural products (e.g. gibberellic acid, morphine), the diverse possibilities of the substituted 7-oxabicyclo |2.2.1|-2-heptene system for further transformation9, the expected enhanced reactivity and stereoselectivity of the intramolecular cycloaddition and the availability of a wide variety of commercial furan derivatives make the sequence a → b → c particularly attractive in total synthesis. 相似文献
102.
103.
The first author introduced a Riemannian invariant denoted by δ and proved in [4] that everyn-dimensional submanifold of the complex hyperbolicm-space ℂH
m
(4c) of constant holomorphic sectional curvature 4c<0 satisfies a basic inequality
, whereH
2 denotes the squared mean curvature of the submanifold. The main purpose of this paper is to completely classify properCR-submanifolds of complex hyperbolic spaces which satisfy the equality case of this inequality.
Dedicated to Leopold Verstraelen on his fiftieth birthday 相似文献
104.
Luc Chapleau Jacques-A. Ferland Jean-Marc Rousseau 《European Journal of Operational Research》1985,20(1):48-57
This paper introduces a new approach for generating school bus routes in a dense urban area. First, a districting algorithm is used to determine clusters including appropriate numbers of students. Then, for each cluster, a route and the stops along this route are determined. Numerical results are reported and compared with those obtained previously. Although the algorithm has been developped and tested in a specific context, it could easily be extended to more general vehicle routing problems. 相似文献
105.
106.
Long optically controlled delays in optical fibers 总被引:4,自引:0,他引:4
Optically controlled delay lines in optical fibers are demonstrated by use of the group-velocity control of signal pulses based on stimulated Brillouin scattering. We achieve continuous time delay within the range of 150 ns, much larger than the width of the 40 ns signal pulse, using cascaded fiber segments joined by unidirectional optical attenuators. In the meantime, we also observe a large amount of pulse broadening, which agrees well with a theoretical prediction based on linear theory. 相似文献
107.
We examine the robustness of ultrashort optical vortices propagating freely in the atmosphere. We first approximate the stability regions of femtosecond spinning pulses as a function of their topological charge. Next, we numerically demonstrate that atmospheric optical vortices are capable of conveying high power levels in air over hundreds of meters before they break up into filaments. 相似文献
108.
109.
Vinck E Van Doorslaer S Dewilde S Moens L 《Journal of the American Chemical Society》2004,126(14):4516-4517
Human neuroglobin (hNgb) and human cytoglobin (hCygb), two recently discovered members of the vertebrate globin family, are known to be able to form an intramolecular disulfide bridge. Using electron paramagnetic resonance (EPR), we show that formation of a disulfide bridge in ferric hNgb causes a considerable change in the heme pocket structure, whereas this is not so clear for ferric hCygb. The structural results can be related nicely to earlier histidine and dioxygen affinity studies of the ferrous proteins. 相似文献
110.
Luc Menichi 《K-Theory》2004,32(3):231-251
We show that the Connes–Moscovici negative cyclic cohomology of a Hopf algebra equipped with a character has a Lie bracket of degree -2. More generally, we show that a cyclic operad with multiplication is a cocyclic module whose simplicial cohomology is a Batalin–Vilkovisky algebra and whose negative cyclic cohomology is a graded Lie algebra of degree -2. This generalizes the fact that the Hochschild cohomology algebra of a symmetric algebra is a Batalin–Vilkovisky algebra. 相似文献