全文获取类型
收费全文 | 1536篇 |
免费 | 32篇 |
国内免费 | 8篇 |
专业分类
化学 | 1094篇 |
晶体学 | 13篇 |
力学 | 16篇 |
数学 | 65篇 |
物理学 | 388篇 |
出版年
2023年 | 5篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 15篇 |
2019年 | 16篇 |
2018年 | 8篇 |
2017年 | 12篇 |
2016年 | 26篇 |
2015年 | 23篇 |
2014年 | 46篇 |
2013年 | 44篇 |
2012年 | 77篇 |
2011年 | 98篇 |
2010年 | 51篇 |
2009年 | 49篇 |
2008年 | 106篇 |
2007年 | 112篇 |
2006年 | 113篇 |
2005年 | 102篇 |
2004年 | 102篇 |
2003年 | 71篇 |
2002年 | 91篇 |
2001年 | 33篇 |
2000年 | 17篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 16篇 |
1996年 | 33篇 |
1995年 | 21篇 |
1994年 | 17篇 |
1993年 | 10篇 |
1992年 | 13篇 |
1991年 | 10篇 |
1990年 | 17篇 |
1989年 | 7篇 |
1988年 | 15篇 |
1987年 | 9篇 |
1986年 | 17篇 |
1985年 | 19篇 |
1984年 | 17篇 |
1983年 | 16篇 |
1982年 | 15篇 |
1981年 | 17篇 |
1980年 | 10篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1968年 | 3篇 |
排序方式: 共有1576条查询结果,搜索用时 312 毫秒
161.
Chitrasen Gupta Subedar Prasad Mahendra Sahai Teigo Asai Noriyuki Hara Yoshinori Fujimoto 《Helvetica chimica acta》2010,93(10):1925-1932
Six new lanostane triterpenes, artabotryols A, B, C1, C2, D, and E ( 1, 2, 3a, 3b, 4 , and 5 , resp.) have been isolated from the seeds of Artabotrys odoratissimus (Annonaceae). Their structures have been established as (3α,22S,25R)‐3‐hydroxy‐22,26‐epoxylanost‐8‐en‐26‐one ( 1 ), (3α,22S,25R)‐22,26‐epoxylanost‐8‐ene‐3,26‐diol ( 2 ), (3α,22S,25R,26R)‐26‐methoxy‐22,26‐epoxylanost‐8‐en‐3‐ol ( 3a ), (3α,22S,25R, 26S)‐26‐methoxy‐22,26‐epoxylanost‐8‐en‐3‐ol ( 3b ), (3α,22S,25R)‐3,22‐dihydroxylanost‐8‐en‐26‐oic acid ( 4 ) and (3α,7α,11α,22S,25R)‐3,7,11‐trihydroxy‐22,26‐epoxylanost‐8‐en‐26‐one ( 5 ) by spectroscopic studies and chemical correlations. 相似文献
162.
Fujita S Ninomiya M Efdi M Ohguchi K Nozawa Y Koketsu M 《Natural product research》2010,24(17):1630-1636
Six chemical constituents were isolated from Enicosanthum cupulare (King) Airy-Shaw. The structures of the isolated compounds were determined using 1D, 2D-NMR and were found to be identical to those previously reported for these compounds. Three aporphine alkaloids, O-methylmoschatoline, liriodenine and oxostephanine were isolated from this plant for the first time. In addition, we examined the effects of these compounds on melanogenesis in murine B16 melanoma cells; O-methylmoschatoline increased melanin content in these cells. 相似文献
163.
Okada Y Dhital C Zhou W Huemiller ED Lin H Basak S Bansil A Huang YB Ding H Wang Z Wilson SD Madhavan V 《Physical review letters》2011,106(20):206805
We study interference patterns of a magnetically doped topological insulator Bi(2-x)Fe(x)Te(3+d) by using Fourier transform scanning tunneling spectroscopy and observe several new scattering channels. A comparison with angle-resolved photoemission spectroscopy allows us to unambiguously ascertain the momentum-space origin of distinct dispersing channels along high-symmetry directions and identify those originating from time-reversal symmetry breaking. Our analysis also reveals that the surface state survives far above the energy where angle-resolved photoemission spectroscopy finds the onset of continuum bulk bands. 相似文献
164.
Vossen A Seidl R Adachi I Aihara H Aushev T Balagura V Bartel W Bischofberger M Bondar A Bračko M Browder TE Chang MC Chen A Chen P Cheon BG Cho K Choi Y Eidelman S Feindt M Gaur V Gabyshev N Garmash A Golob B Perdekamp MG Haba J Hayasaka K Horii Y Hoshi Y Hou WS Hyun HJ Inami K Ishikawa A Iwabuchi M Iwasaki Y Iwashita T Joshi NJ Kichimi H Kim HO Kim MJ Ko BR Kumita T Lange JS Lee MJ Lee SH Leitgab M Li Y Liu C Liventsev D Louvot R McOnie S Miyata H Miyazaki Y Mizuk R Mohanty GB Nakano E 《Physical review letters》2011,107(7):072004
The interference fragmentation function translates the fragmentation of a quark with a transverse projection of the spin into an azimuthal asymmetry of two final-state hadrons. In e(+)e(-) annihilation the product of two interference fragmentation functions is measured. We report nonzero asymmetries for pairs of charge-ordered π(+)π(-) pairs, which indicate a significant interference fragmentation function in this channel. The results are obtained from a 672 fb(-1) data sample that contains 711 × 10(6) π(+)π(-) pairs and was collected at and near the Υ(4S) resonance, with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. 相似文献
165.
166.
This paper proposes a method of structuring public policy by incorporating reciprocal expectation analysis. The proposed method is characterized by three components: identification of the problem structure perceived by stakeholders using cognitive maps, policy structuring analysis with a value–driver matrix and a reciprocal expectation matrix, and feasibility analysis of agreements among the stakeholders. The three types of relationship among stakeholders are derived from the feasibility analysis, which are “Dosho-imu”, “Isho-imu”, and “Domu”. Three tests of feasibility to reach the agreement are then proposed: “information-sharing test”, “bargaining test”, and “reframing test”. A case study is presented, applying the method to strategic transportation planning in the Kanto region of Japan. Finally, the potential functions of the proposed method in practice are discussed. 相似文献
167.
168.
Hisatoshi Kura Kan Fujihara Akira Kimura Teruhisa Ohno Michio Matsumura Yoshinori Hirata Tadashi Okada 《Journal of Polymer Science.Polymer Physics》2001,39(23):2937-2946
The anthracene‐sensitized photodecomposition of diphenyliodonium hexafluorophosphate was studied in an epoxy matrix. From steady‐state photolysis, the generation of protons, which are considered to be the actual initiators of the polymerization of epoxides, was confirmed. In addition, 9‐phenylanthracene was detected as a main product from anthracene. From time‐resolved laser‐flash photolysis, a broad absorption band with a peak at about 500 nm was observed that was thought to be due to the precursor of 9‐phenylanthracene. On the basis of these results, we propose electron transfer from anthracene in the excited singlet state to the diphenyliodonium cation as the initial step of photoacid generation. This process is followed by fast chemical reactions, which generate 9‐phenylanthracene and protons, and back electron transfer from the diphenyliodine radical to the anthracene cation radical. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 2937–2946, 2001 相似文献
169.
Shinsaku Dobashi Masaharu Kira Ryuichiro Tanaka Yoshinori Izawa Akihide Wada Michikazu Hara 《Analytical sciences》2006,22(4):603-606
The development of molecular spectroscopy has enabled us to select chlorinated aromatic hydrocarbons very rapidly. In particular, the laser ionization TOFMS (time-of-flight mass spectrometry) method is expected to be useful as an on-line, selective, and sensitive method. In the present work, real-time laser ionization TOFMS measurements were carried out on gaseous chlorinated aromatic hydrocarbons. The laser ionization method used resonance-enhanced two-photon ionization with the direct introduction of gas into the vacuum chamber. This method for analyzing aromatic hydrocarbons was developed using a pulsed supersonic molecular beam method. In the context of developing a highly selective and sensitive method, excitation of monochlorinated benzene at lambda = 263.07 nm was found to be effective in the wavelength region from 263 nm to 265 nm. Also the excitation of polychlorinated biphenyls at lambda = 266 nm was found to be substantially more effective than at lambda = 280, 300 or 320 nm. The achievable sensitivity for real-time (1 min) measurements using the laser ionization TOFMS technique was found to be in the ppbV range. 相似文献
170.
Hideaki Furukawa Tsuyoshi Konishi Yoshinori Oshita Wanji Yu Kazuyoshi Itoh Yoshiki Ichioka 《光学学报》2003,23(Z1)
We demonstrate a suppression effect of a crosstalk among a target and similar header signals using the header recognition filter designed by a design technique of the multiple-object discriminant filter. 相似文献