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We have demonstrated high-energy quasi-phase-matched optical parametric oscillation in a 3-mm-thick periodically poled 5-mol. % MgO-doped LiNbO3 device with a 32.1-microm grating period and a 30-mm length. With a large-spot-size pump laser of 2.2-mm diameter, we obtained a total output pulse energy of 22 mJ for both the signal (wavelength 1.82 microm) and the idler (2.56 microm) waves at an input pump energy of 46 mJ. 相似文献
56.
A modified U-tube conical bubble sonoluminescence device is used to
study the conical bubble photoluminescence. The spectra of conical
bubble sonoluminescence at different concentrations of rhodamine 6G
(Rh6G) solution in 1,2-propanediol have been measured. Results show
that the sonoluminescence from the conical bubbles can directly
excite Rh6G, which in turn can fluoresce. The light emission of this
kind is referred to as conical bubble photoluminescence. The maximum
of fluorescence spectral line intensity in the conical bubble
photoluminescence has a red shift in relative to that of the
standard photo-excited fluorescence, which is due to the higher
self-absorption of Rh6G, and the spectral line of conical bubble
photoluminescence is broadened in width compared with that of
photo-excited fluorescence. 相似文献
57.
Polyaniline/Zn0.5Cu0.5Fe2O4 nanocomposite was synthesized by a simple, general and inexpensive in-situ polymerization method in w/o microemulsion. The
effects of polyaniline coating on the magnetic properties of Zn0.5Cu0.5Fe2O4 nanoparticles were investigated. The structural, morphological and magnetic properties of as-prepared samples were characterized
by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, scanning electron microscopy (SEM) and magnetic measurements.
The morphology analysis confirmed that polyaniline was deposited on the porous surface of magnetic Zn0.5Cu0.5Fe2O4. It was shown that the saturation magnetization and coercivity of Zn0.5Cu0.5Fe2O4 decreased after polyaniline coating, which can be interpreted by the interparticle dipole–dipole interactions that contributed
to magnetic anisotropy and changed the magnetic properties of the nanoparticles.
PACS 74.25.Ha; 81.05.-t; 81.05.Lg 相似文献
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Weihua Zhou Zoukangning Yu Ming Zhang Lifu Zhang Jingping Yin Qingyun Ai Liqiang Huang Feng Liu Jianrong Zeng Yiwang Chen 《Journal of Polymer Science.Polymer Physics》2019,57(14):941-951
In order to explore the role of fluorine atoms on photostability as well as morphology control of active layer in the presence of 1,4‐butanedithiol (BT), the four polymers with or without fluorine atoms in the backbones including polythieno[3,4‐b]thiophene/benzodithiophene, poly[(4,8‐bis‐(2‐ethylhexyloxy)‐benzo(1,2‐b:4,5‐b9)dithiophene)‐2,6‐diyl‐alt‐(4‐(2‐ethylhexanoyl)‐thieno[3,4‐b]thiophene‐)‐2‐6‐diyl)], poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b;4,5‐b′]dithiophene‐2,6‐diyl‐alt‐(4‐(2‐ethylhexyl)‐3‐fluorothieno[3,4‐b]thiophene‐)‐2‐carboxylate‐2‐6‐diyl)], and poly[4,8‐bis‐(2‐ethyl‐hexyl‐thiophene‐5‐yl)‐benzo[1,2‐b:4,5‐b0]dithiophene‐2,6‐diyl]‐alt‐[2‐(20‐ethyl‐hexanoyl)‐thieno [3,4‐b]thiophen‐4,6‐diyl] were selected for comparison. It is found that the specimens containing fluorine atoms in polymer backbones showed of higher stability after illumination for 1 h in the presence of BT additive, contributing to the higher domain purity. The specific interaction between fluorine atoms and thiol groups was demonstrated by the appearance of novel absorption peak at 2663.1 cm?1, in addition to the broadening of peak at 2556.2 cm?1 ascribing to S? H stretching vibration as confirmed by Fourier transform infrared (FTIR) spectroscopy. The finding may guide the accurate use of thiols as effective solvent additive in morphology and stability optimization. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 941–951 相似文献
60.
Lvye Ai Mengzhen Liu Xiaoming Ji Miao Lai Mingqin Zhao Tianbao Ren 《Journal of heterocyclic chemistry》2019,56(9):2389-2397
To expand the library of pyrrole‐containing flavor precursors, two new flavor precursors—methyl N‐benzyl‐2‐methyl‐5‐formylpyrrole‐3‐carboxylate (NBMF) and methyl N‐butyl‐2‐methyl‐5‐formylpyrrole‐3‐carboxylate (NUMF)—were synthesized by cyclization, oxidation, and alkylation reactions. Thermogravimetry (TG), differential scanning calorimeter, and pyrolysis–gas chromatography/mass spectrometry were utilized to analyze the thermal degradation behavior and thermal degradation products of NBMF and NUMF. The TG‐DTG curve indicated that the maximum mass loss rates of NBMF and NUMF appear at 310 and 268°C, respectively. The largest peaks of NBMF and NUMF showed by the differential scanning calorimeter curve were 315 and 274°C, respectively. Pyrolysis–gas chromatography/mass spectrometry detected small molecule fragrance compounds appeared during thermal degradation, such as 2‐methylpyrrole, 1‐methylpyrrole‐2‐carboxylic acid methyl ester, limonene, and methyl formate. Finally, the thermal degradation mechanism of NBMF and NUMF was discussed, which provided a theoretical basis for their application in tobacco flavoring additives. 相似文献