A pressure induced phase transition in pyroxene

Abstract

Two monoclinic pyroxenes of composition Ca(Fe,Mg)Si₂O₆ were studied up to 10 GPa using X-ray powder diffraction and ⁵⁷Fe Mössbauerspectroscopy. The results are indicative of a phase transition at 4 GPa.     

Pressure-induced phase transition in PbSc0.5Ta0.5O3 as a model Pb-based perovksite-type relaxor ferroelectric

We report pressure-induced structural changes in PbSc(0.5)Ta(0.5)O3 studied by single-crystal x-ray diffraction and Raman scattering. The appearance of a soft mode, a change in the volume compressibility, broadening of the diffraction peaks, and suppression of the x-ray diffuse scattering show that a phase transition occurs near pc approximately 1.9 GPa. The critical pressure is associated with a decoupling of the displacements of the B site and Pb cations in the existing polar nanoregions, leading to the suppression of B-cation off-center shifts and enhancement of the ferroic distortion in the Pb-O system.     

Anisotropy of crystal structure distortion in organic molecular crystals of drugs induced by hydrostatic compression

Variation of the unit cell parameters of paracetamol and phenacetin as a function of hydrostatic pressure was studied by X-ray diffractometry in diamond anvils. At elevated pressure (4 GPa), the crystal structures undergo anisotropic distortion. The greatest compression was observed in the directions in which the molecules are linked by van der Waals forces alone. Compressibility of the structures in the direction of hydrogen bonds depends on the presence of other types of interaction and on molecular arrangement in the crystals. In the case of paracetamol, integrated compression of the structure led to its stretching in definite crystallographic directions.     

Effects of pressure on the two polymorphs of [Co(NH3)5NO2]I2: The anisotropy of lattice distortion and a phase transition

Abstract

The effect of pressure on the two polymorphs of [CO(NH₃)₅NO₂]I₂ (phase I-orthorhombic, S.G. Pnma; phase II-monoclinic, S.G. C2/m) was studied by X-ray powder diffraction in a diamond anvil cell (DAC). In the presence of the ethanol-methanol-water mixture used as a pressure-transmitting liquid polymorph I was shown to undergo a phase transition at pressures between 0.45 GPa and 0.65 GPa. The diffraction pattern of the high-pressure phase (phase III) could be indexed as tetragonal with lattice parameters similar to those, which were previously reported for polymorph II in a 'pseudotetragonal setting'. The lattice distortions of phases II and III were studied at pressures up to 3.2 GPa and 3.7 GPa, correspondingly, and were shown to be very similar. Phases II and III were supposed to be very closely related. If poly(chlortrifluorethylen)-oil was used as a pressure-transmitting medium, no phase transitions were observed in phase I of [CO(NH₃)₅NO₂I₂ at least up to 1.8 GPa (the point when poly(chlortrifluorethylen)-oil becomes solid), and the anisotropy of lattice distortion could be measured.     

Single crystal X-ray diffraction study of a mixed-valence gold compound, Cs2AuAuCl6 under high pressures up to 18 GPa: Pressure-induced phase transition coupled with gold valence transition

We performed the single-crystal X-ray diffraction study of a perovskite-type gold mixed-valence compound, Cs₂Au^IAu^IIICl₆, under high pressures up to 18 GPa by using a diamond-anvil-cell with helium gas as an ideal hydrostatic pressure-transmitting medium. The lattice parameters and the variable atomic positional parameters were obtained with reasonable accuracy at various pressures. A structural phase transition at ca. 12.5 GPa from I4/mmm to Pm3m was found. The lattice parameters a₀ and c₀, denoted in the tetragonal cell setting, result in the relationship 2^1/2a₀=c₀, and the superstructure reflections h k l (l is odd), caused by the shift of the Cl ions from the midpoint of the Au ions, disappeared at pressures above the phase transition. Both elongated [Au^IIICl₆] and compressed [Au^ICl₆] octahedra in the low-pressure phase smoothly approach regular octahedra with increasing pressure. Above the structural phase transition at 12.5 GPa, all the [AuCl₆] octahedra are crystallographically equivalent, which shows that the tetragonal-to-cubic phase transition accompanies the valence transition from the Au^I/Au^III mixed-valence state to the Au^II single-valence state.