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71.
A new vic-dioxime ligand, N,N′-bis(aminopyreneglyoxime) (LH2), and its copper(II), nickel(II) and cobalt(II) metal complexes were synthesized and characterized by elemental analyses,
IR, UVVIS and 1H and 13C NMR spectra (for the ligand). Mononuclear complexes were synthesized by a reaction of ligand (LH2) and salts of Co(II), Ni(II), and Cu(II) in ethanol. The complexes have the metal-ligand ratio of 1: 2 and metals are coordinated
by N,N′ atoms of vicinal dioximes. The ligand acts in a polydentate fashion bending through nitrogen atoms in the presence of a base,
as do most vic-dioximes. Detection of a H-bonding in the Co(II), Ni(II), and Cu(II) complexes by IR revealed the square-planar MN4 coordination of mononuclear complexes. Fluorescent properties of the ligand and its complexes arise from pyrene units conjugated
with a vic-dioxime moiety. Fluorescence emission spectra of the ligand showed a drastic decrease in its fluorescence intensity upon
metal binding. The electrochemical properties of the complexes were studied by the cyclic voltammetry technique. The nickel
complex displayed an irreversible oxidation process while the copper complex exhibited a quasi-reversible oxidation and reduction
processes based on the copper Cu(II)/Cu(III) and Cu(II)/Cu(I) couples, respectively. 相似文献
72.
A new N-TEMPO-3,5-di-tert-butylsalicylaldimine radical (1) has been synthesized and characterized by single crystal X-ray diffraction, elemental analysis, IR, UV–vis, and EPR spectroscopy and temperature dependent magnetic susceptibility. X-ray diffraction revealed that H-atoms of γ-CH in TEMPO and CH3 in salicylaldimine moieties, are located in close contact with the neighboring N–O radical group in crystal 1. The temperature dependence of the magnetic susceptibility (χm) of 1 has been fitted by the Curie–Weiss law with θ = −0.3 K within 10–300 K, suggesting the presence of a weak intermolecular antiferromagnetic interaction between radical centers at T < 10 K. It has been demonstrated that radical 1 possesses crystal structure involving co-existence of antiferromagnetic and ferromagnetic interactions through C–H?O–N contacts of γ-CH and tBu groups hydrogen atoms, in which the former path dominates over the latter. 相似文献
73.
We provide an ergodic theorem for certain Banach-space valued functions on structures over , which allow for existence of frequencies of finite patterns. As an application we obtain existence of the integrated density
of states for associated discrete finite-range operators in the sense of convergence of the distributions with respect to
the supremum norm. These results apply to various examples including periodic operators, percolation models and nearest-neighbour
hopping on the set of visible points. Our method gives explicit bounds on the speed of convergence in terms of the speed of
convergence of the underlying frequencies. It uses neither von Neumann algebras nor a framework of random operators on a probability
space.
相似文献
74.
It has long been known that thiol-terminated molecules self-assemble as commensurate monolayers on Au(111) surfaces. By spreading floating octadecanethiol monolayers on aqueous solutions of chloroauric acid (HAuCl4) and using x rays to reduce the gold ions as well as to probe the structure, we have observed the nucleation of (111)-oriented Au nanoparticles at thiol surfaces. This process may be similar to the formation of biogenic gold by bacteria. The thiol monolayer acts as a "soft template," changing its structure as Au crystals form so that there is a sqrt[3]×sqrt[3] commensurate relationship. 相似文献
75.
Ahmet Bulut brahim Uar Okan Zafer Yeilel Hasan budak Halis
lmez Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(10):m526-m528
The title mononuclear [Cu(sq)(phen)2]·3H2O complex [sq is squarate (C4O4) and phen is 1,10‐phenanthroline (C12H8N2)] has been synthesized and the structure consists of a neutral mononuclear [Cu(sq)(phen)2] unit and three solvate water molecules. The CuII ion has distorted square‐pyramidal coordination geometry, comprised of one carboxylate O atom from a monodentate squarate ligand and four N atoms from two chelating phen ligands. An extensive three‐dimensional network of OW—H⋯O/OW hydrogen bonds, face‐to‐face π–π interactions between the 1,10‐phenanthroline aromatic rings and a weak π–ring interaction are responsible for crystal stabilization. 相似文献
76.
Ahmet Karadag Ahmet Bulut Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(8):m402-m404
The crystal structure of the title compound, [Ni(NCS)2(C4H12N2O)2], has two crystallographically independent half‐molecules in the asymmetric unit, with each Ni atom residing on a centre of symmetry. The two molecules exhibit similar coordination geometry but display differences with regard to other structural features. Each NiII centre is octahedrally coordinated by two mutually trans chelating hydroxyethylethylenediamine ligands and two mutually trans isothiocyanate ions. The two independent molecules form chains through different types of non‐covalent interactions. In the case of one of the molecules, only NCS and free OH groups participate in hydrogen bonding, while in the chain based on the second molecule, the NCS, NH, NH2 and free OH groups are involved in intermolecular hydrogen bonding. The two chains interact with one another through hydrogen bonding, forming planar sheets. The third packing direction is mediated only by van der Waals interactions. 相似文献
77.
Ahmet Tekcan 《Results in Mathematics》2004,46(1-2):146-163
The number of representation of positive integers by quadratic forms $ F_{1}=x_{1}^{2}+3x_{1}x_{2}+8x_{2}^{2} $ and $ G_{1}=2x_{1}^{2}+3x_{1}x_{2}+4x_{2}^{2} $ of discriminant —23 are given. Moreover, a basis for the cusp form space S 4(Γ0(23), 1) are constructed. Furthermore, formulas for the representation of positive integers by direct sum of copies of F 1 and G 1, i.e. formulas for $ r(n; F_{4}), r(n; G_{4}), r(n; F_{3} \oplus G_{1}), r(n; F_{2} \oplus G_{2}), {\rm and}\ r(n; F_{1} \oplus G_{3}) $ , are derived using the elements of the space S 4(Γ(23), 1). 相似文献
78.
In this study, we present a bi-objective facility location model that considers both partial coverage and service to uncovered demands. Due to limited number of facilities to be opened, some of the demand nodes may not be within full or partial coverage distance of a facility. However, a demand node that is not within the coverage distance of a facility should get service from the nearest facility within the shortest possible time. In this model, it is assumed that demand nodes within the predefined distance of opened facilities are fully covered, and after that distance the coverage level decreases linearly. The objectives are defined as the maximization of full and partial coverage, and the minimization of the maximum distance between uncovered demand nodes and their nearest facilities. We develop a new multi-objective genetic algorithm (MOGA) called modified SPEA-II (mSPEA-II). In this method, the fitness function of SPEA-II is modified and the crowding distance of NSGA-II is used. The performance of mSPEA-II is tested on randomly generated problems of different sizes. The results are compared with the solutions of the most well-known MOGAs, NSGA-II and SPEA-II. Computational experiments show that mSPEA-II outperforms both NSGA-II and SPEA-II. 相似文献
79.
Liu D Chu XQ Lagi M Zhang Y Fratini E Baglioni P Alatas A Said A Alp E Chen SH 《Physical review letters》2008,101(13):135501
Molecular dynamics simulations and neutron scattering experiments have shown that many hydrated globular proteins exhibit a universal dynamic transition at TD = 220 K, below which the biological activity of a protein sharply diminishes. We studied the phononlike low-energy excitations of two structurally very different proteins, lysozyme and bovine serum albumin, using inelastic x-ray scattering above and below TD. We found that the excitation energies of the high-Q phonons show a marked softening above TD. This suggests that the large amplitude motions of wavelengths corresponding to this specific Q range are intimately correlated with the increase of biological activities of the proteins. 相似文献
80.
Hasan budak Ahmet Bulut Naziye etin Canan Kazak 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(1):m1-m3
The crystal structure of the first acesulfame–metal complex, namely tetraaquabis[6‐methyl‐1,2,3‐oxathiazin‐4(3H)‐onato 2,2‐dioxide‐κN]cobalt(II), [Co(C4H4NO4S)2(H2O)4], is reported. The CoII ion resides on a twofold axis and is coordinated by four aqua ligands defining the basal plane and by two monodentate acesulfamate ligands, via their ring N atoms, in the axial positions. Two intra‐ and three intermolecular hydrogen‐bonding interactions stabilize the crystal structure and form an infinite three‐dimensional lattice. 相似文献