全文获取类型
收费全文 | 754篇 |
免费 | 42篇 |
国内免费 | 8篇 |
专业分类
化学 | 472篇 |
晶体学 | 5篇 |
力学 | 49篇 |
数学 | 115篇 |
物理学 | 163篇 |
出版年
2023年 | 5篇 |
2022年 | 16篇 |
2021年 | 22篇 |
2020年 | 16篇 |
2019年 | 28篇 |
2018年 | 21篇 |
2017年 | 25篇 |
2016年 | 41篇 |
2015年 | 23篇 |
2014年 | 26篇 |
2013年 | 85篇 |
2012年 | 60篇 |
2011年 | 53篇 |
2010年 | 38篇 |
2009年 | 39篇 |
2008年 | 45篇 |
2007年 | 53篇 |
2006年 | 29篇 |
2005年 | 39篇 |
2004年 | 38篇 |
2003年 | 23篇 |
2002年 | 13篇 |
2001年 | 4篇 |
2000年 | 7篇 |
1999年 | 4篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1968年 | 1篇 |
1905年 | 1篇 |
排序方式: 共有804条查询结果,搜索用时 78 毫秒
801.
Ahmet Karadag Ersin Kaygisiz Timur Nikitin Sinan Ongen Gulce Ogruc Ildiz Namik Aysal Ayberk Yilmaz Rui Fausto 《Molecules (Basel, Switzerland)》2022,27(10)
Fulgurites are naturally occurring structures that are formed when lightning discharges reach the ground. In this investigation, the mineralogical compositions of core and shell compartments of a rare, iron-rich fulgurite from the Mongolian Gobi Desert were investigated by X-ray diffraction and micro-Raman spectroscopy. The interpretation of the Raman data was helped by chemometric analysis, using both multivariate curve resolution (MCR) and principal component analysis (PCA), which allowed for the fast identification of the minerals present in each region of the fulgurite. In the core of the fulgurite, quartz, microcline, albite, hematite, and barite were first identified based on the Raman spectroscopy and chemometrics analyses. In contrast, in the shell compartment of the fulgurite, the detected minerals were quartz, a mixture of the K-feldspars orthoclase and microcline, albite, hematite, and goethite. The Raman spectroscopy results were confirmed by X-ray diffraction analysis of powdered samples of the two fulgurite regions, and are consistent with infrared spectroscopy data, being also in agreement with the petrographic analysis of the fulgurite, including scanning electron microscopy with backscattering electrons (SEM-BSE) and scanning electron microscopy with energy dispersive X-ray (SEM-EDX) data. The observed differences in the mineralogical composition of the core and shell regions of the studied fulgurite can be explained by taking into account the effects of both the diffusion of the melted material to the periphery of the fulgurite following the lightning and the faster cooling at the external shell region, together with the differential properties of the various minerals. The heavier materials diffused slower, leading to the concentration in the core of the fulgurite of the iron and barium containing minerals, hematite, and barite. They first underwent subsequent partial transformation into goethite due to meteoric water within the shell of the fulgurite. The faster cooling of the shell region kinetically trapped orthoclase, while the slower cooling in the core area allowed for the extensive formation of microcline, a lower temperature polymorph of orthoclase, thus justifying the prevalence of microcline in the core and a mixture of the two polymorphs in the shell. The total amount of the K-feldspars decreases only slightly in the shell, while quartz and albite appeared in somewhat larger amounts in this compartment of the fulgurite. On the other hand, at the surface of the fulgurite, barite could not be stabilized due to sulfate lost (in the form of SO2 plus O2 gaseous products). The conjugation of the performed Raman spectroscopy experiments with the chemometrics analysis (PCA and, in particular, MCR analyses) was shown to allow for the fast identification of the minerals present in the two compartments (shell and core) of the sample. This way, the XRD experiments could be done while knowing in advance the minerals that were present in the samples, strongly facilitating the data analysis, which for compositionally complex samples, such as that studied in the present investigation, would have been very much challenging, if possible. 相似文献
802.
A general and convenient route for the synthesis of 2,5-di[1-methyl-1-arylcyclobutane-3-yl]- thiophenes 4a–c and bis[1-methyl-1-arylcyclobutane-3-yl]-2-(2-oxyethtylamido)thiazole sulfides 7a–c is reported. The characterization of these compounds was obtained by elemental analyses, IR, 13C, and 1H NMR techniques. © 2003 Wiley Periodicals, Inc. 15:26–31, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/.hc10207 相似文献
803.
804.
Metal and polymer matrix composite materials are preferred in bulletproof applications due to their high-impact resistance and lightness. Personal/demand-specific designs that have become possible with the developing additive manufacturing technologies have brought a new perspective to armor technologies. At the same time, parts with complex structures designed with biomimetic approaches can be easily manufactured with additive manufacturing. In this study, biomimetic armors obtained from standard Carbon fiber reinforced polymer (CFRP) and Inconel 718 materials were compared with traditional armor structures. Within the scope of the study, 9 × 19 mm2 parabellum and 7.62 mm NATO bullets were impacted at 275 m/s and 600 m/s speeds on biomimetic and conventional armor consisting of three and five layers. Bullet velocities during impact, deformation of bullets, deformation of armor, and harmonic behavior are discussed. The results obtained were also used to calculate the damped impact energies. In the study, it was determined that biomimetic plates could absorb 22%–38% more impact energy. It has been determined that CFRP materials can absorb 45% more impact energy compared to Inconel 718. 相似文献