Synthesis of Some New Thiazole,Oxazole, Pyrimidine and Pyridazine Derivatives from 2‐cyano‐N‐octadecyl‐acetamide as Antimicrobial and Surface Active Agents

The motivation behind the present work is to synthesize some nonionic surfactants containing heterocyclic nucleus with intermediate fatty compounds for improving their surfactants properties. 2‐Cyano‐N‐octadecylacetamide was utilized as key intermediate for the synthesis of some new thiazole, pyrazole, oxazole, pyrimidine, 1,3‐dithiolane, thiophene, coumarin, oxazine and pyridazine derivatives. The newly synthesized compounds undergo propoxylation using propylene oxide to afford nonionic surface active agents. The antimicrobial and surface activities were evaluated and characterized through investigations of their spreading behavior in monolayer on water.     

Reactions with Carbo(heterylhydrazonoyl) Halides. I. Chemistry of Carbo(3-phenylpyrazol-5-yl-hydrazonoyl) Chlorides

The Carbo(3-phenylpyrazol-5-yl-hydrazonoyl) halides 1a , b react with active methylene compounds to yield the 1-(3-phenylpyrazol-5-yl)-pyrazole derivatives 2a – k (Scheme 1). The acyclic intermediates 3a , b could be isolated from reaction of 1a , b with acetylacetone, thus establishing the substitution mechanism for these reactions. Compounds 1a , b reacted with carbon disulfide, phenyl isothiocyanate, methyl cyanide, and with p-chlorobenzaldehyde to yield the corresponding heterocyclic derivatives 5 – 8 , respectively (Scheme 2). The behaviour of compounds 2 with hydrazine hydrate is reported.     

Critical Point of the 152Sm, 154Gd,and 156Dy Isotones

Physics of Atomic Nuclei - The even—even rare-earth nuclei in U(5)—SU(3) region at neutron number (N) = 90, have been systematically studied using the Bohr—Mottelson Model (BM),...     

Mass and thermal transport in liquid Cu-Ag alloys

In this paper, the diffusion, thermodynamic and thermotransport properties in Cu–Ag liquid alloys are extensively investigated with molecular dynamics over a wide composition and temperature range. The simulations are performed with the most reliable EAM potential. The Green-Kubo formalism is employed for calculating transport properties. It is found that the reduced heat of transport in Cu–Ag is very small (about 0.10?eV in absolute value) and almost temperature independent. Further it is found that the interdiffusion coefficient together with both self-diffusion coefficients are almost composition independent. In Cu–Ag, the thermodynamic factor is found to be less than unity whereas the Manning factor is greater than unity (with significant composition and temperature dependence) and their product is very close to 1.     

Analytical solution of a three-level atom coupled to four systems of N-two-level atoms

Optical Review - The analytical solution of a three-level atom interacting with four systems of N-two-level atoms is studied. The atomic inversion and the correlation function as applications of...     

Chemically reactive and radiative von Kármán swirling flow due to a rotating disk

A new mathematical model is presented to study the heat and mass transfer characteristics of magnetohydrodynamic (MHD) Maxwell fluid flow over a convectively heated stretchable rotating disk. To regulate the fluid temperature at the surface, a simple isothermal model of homogeneous-heterogeneous reactions is employed. The impact of nonlinear thermal radiative heat flux on thermal transport features is studied. The transformed nonlinear system of ordinary differential equations is solved numerically with an efficient method, namely, the Runge-Kutta-Felberg fourth-order and fifth-order (RKF45) integration scheme using the MAPLE software. Achieved results are validated with previous studies in an excellent way. Major outcomes reveal that the magnetic flux reduces the velocity components in the radial, angular, and axial directions, and enhances the fluid temperature. Also, the presence of radiative heat flux is to raise the temperature of fluid. Further, the strength of homogeneous–heterogeneous reactions is useful to diminish the concentration of reaction.