Synthesis of Some New Thiazole,Oxazole, Pyrimidine and Pyridazine Derivatives from 2‐cyano‐N‐octadecyl‐acetamide as Antimicrobial and Surface Active Agents

The motivation behind the present work is to synthesize some nonionic surfactants containing heterocyclic nucleus with intermediate fatty compounds for improving their surfactants properties. 2‐Cyano‐N‐octadecylacetamide was utilized as key intermediate for the synthesis of some new thiazole, pyrazole, oxazole, pyrimidine, 1,3‐dithiolane, thiophene, coumarin, oxazine and pyridazine derivatives. The newly synthesized compounds undergo propoxylation using propylene oxide to afford nonionic surface active agents. The antimicrobial and surface activities were evaluated and characterized through investigations of their spreading behavior in monolayer on water.     

Color Bricks: Building Highly Organized and Strongly Absorbing Multicomponent Arrays of Terpyridyl Perylenes on Metal Oxide Surfaces

Terpyridine‐substituted perylenes containing cyclic anhydrides in the peri position were synthesized. The anhydride group served as an anchor for assembly of the terpyridyl‐crowned chromophores as monomolecular layers on metal oxide surfaces. Further coordination with Zn²⁺ ions allowed for layer‐by‐layer formation of supramolecular assemblies of perylene imides on the solid substrates. With properly selected anchor and linker molecules it was possible to build high quality structures of greater than ten successive layers by a simple and straightforward procedure. The prepared films were stable and had a broad spectral coverage and high absorbance. To demonstrate their potential use, the synthesized dyes were employed in solid‐state dye‐sensitized solar cells, and electron injection from the perylene antennas to titanium dioxide was observed.     

Effect of Dissolved Oxygen Tension and Agitation Rates on Sulfur-Utilizing Autotrophic Denitrification: Batch Tests

The effect of dissolved oxygen (DO) and agitation rate in open and closed reactors was examined for sulfur-utilizing autotrophic denitrification. The reaction rate constants were determined based on a half-order kinetic model. Declining denitrification rate constants obtained for open reactors those of 8.46, 8.03, and 2.18 for 50 mg NO₃ ^?-N/L, while 11.12, 9.14, and 0.12 mg^1/2/L^1/2?h were for 100 mg NO₃ ^?-N/L at agitation speeds of 0, 100, and 200 rpm. In closed reactors, the ever-increasing denitrification rates were 10.13, 22.56, and 37.03, whereas for the same nitrate concentrations and speeds the rates were 13.17, 15.63, and 26.67 mg^1/2/L^1/2?h. The rate constants correlated well (r ² ?=?0.89–0.99) with a half-order kinetic model. In open reactors, high SO₄ ^2?/N ratios (8.02–75.10) while in closed reactors comparatively low SO₄ ^2?/N ratios (6.10–13.39) were obtained. Sulfur oxidation occurred continuously in the presence of DO, resulting in mixed cultures acclimated to sulfur and nitrate. SO₄ ^2? was produced as an end product, which reduced alkalinity and lowered pH over time. Furthermore, DO inhibited sulfur denitrification in open reactors, while agitation in closed reactors increased the rate of denitrification.     

Analytical study of global bifurcations,stabilization and chaos synchronization of jerk system with multiple attractors

Nonlinear Dynamics - This paper investigates the fixed-time synchronization of complex dynamical networks with nonidentical nodes in the presence of bounded uncertainties and disturbances using...     

Synthesis and Characterization of Carbohydrate-Copolyhydrazides Containing Ether Bonds in the Monomer Unit

Abstract

A series of carbohydrate-containing copolyhyrazides having ether bonds were prepared by low temperature solution polycondensation. 2,3,4,5-tetra-O-acetyl galactaroyl dichloride was polycondensed with hydroquinone-1,4-diacetic acid dihydrazide (1), 2-bromo-,2-chloro, 2-nirohydroquinone-1,4-diacetic acid dihydrazide (2, 3 and 4, respectively) and isophthaloyl dihydrazide (5) in dimethylformamide and produced copolyhydrazides (6-10), respectively. Copoly {1-[2-(2,3,4,5-tetra-O-acetyl-galacto-tetritoldi-1,4-yl)-5-(1,3,4-oxadiazol-di-2,5-yl]-3-[2-(1,3,4-oxadiazole-di-2,5-yl)-benzene]}(11)wassynthesizedbydehydrative cyclisation of the polymer(10) using thionyl chloride. Also, polymer (10), under de-O-acetylation in methanolic ammonia, gave the de-O-acetylated polymer (12). All the present new polymers were characterized by elemental analysis and i.r. and ¹H-NMR spectroscopy. Their solubility, viscosity and physical properties are studied.     

Effect of gemini surfactant additives on pour point depressant of crude oil

Efficiencies of cationic gemini surfactant additives in improving the pour point depressant of crude oil were investigated. The length of alkyl chain is a major factor affecting the improvement of the pour point depression. The adsorption behavior of these gemini surfactants at air/solution and oil/solution interfaces were investigated by measuring the surface tension and interfacial tension as functions of concentration. It is found that there is a good relation between surface properties especially interfacial tension of the gemini surfactants and their efficiency in depressing the pour point. Also, the surface parameters and free energies of micellization and adsorption confirm the decreasing and improving of pour point depression. Crystallization study in crude oil revealed the relationship between the structure and activity of gemini surfactant additives. It is found that the x-ray diffraction patterns of waxes with additives are remarkably different from those without additives. The mechanism of the depressants action has been suggested according the adsorption of each additive. Adsorption of the additive on the surface of the wax particles inhibits their growth and alters the crystal habits through micelle core. Pretreatment of the crude oil with pour point depressants has received the greatest acceptance due to its simplicity and economy.     

Concurrent Covalent and Supramolecular Polymerization

Covalent and supramolecular polymerizations, both of which offer their own unique advantages, have emerged as popular strategies for making artificial materials. Herein, we describe a concurrent covalent and supramolecular polymerization strategy—namely, one which utilizes 1) a bis‐azide‐functionalized diazaperopyrenium dication that undergoes polymeriation covalently with a bis‐alkyne‐functionalized biphenyl derivative in one dimension as a result of a rapid and efficient β‐cyclodextrin(CD)‐accelerated, cucurbit[6]uril(CB)‐templated azide–alkyne cycloaddition, while 2) the aromatic core of the dication is able to dimerize in a criss‐cross fashion by dint of π–π interactions, enabling simultaneous supramolecular assembly, resulting in an extended polymer network in an orthogonal dimension.     

Advances in 1,8-Naphthyridines Chemistry

This review reports a broad overview of the synthetic procedures of 1,8-naphthyridines, dibenzo[b,g][1,8]naphthyridine, dibenzo[c,f][1,8]naphthyridine, 1,8-naphthyridine-3-carboxylic acid, 1,8-naphthyridine-3-carboxamide, and 1,8-naphthyridine-3-carbohydrazide compounds and their reactions. The physical properties, spectral data, and biological importance of naphthyridines are discussed.     

Characterization of an Algerian diatomite by inverse gas chromatography: Specific and non-specific contribution and Lewis acid–base parameters

The fundamental understanding of the behavior of a solid is intimately related to the understanding of the interactions on the surface of the latter, a major challenge in particular if the material is natural and ecological. The infinite dilution-inverse gas chromatography was used to evaluate the surface thermodynamic properties of several phases (grafted and/or coated) diatomite. A series of non- or polar-solute probes were injected at temperatures of 45?°C and 90?°C. The dispersive surface free energies values of the supports decrease with increasing temperature and their active surface is amphoteric with predominantly acidic character.