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991.
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Meccanica - The present research focuses on dynamic flow control management using tiny jets with three combinations; the first one located at 90° intervals of the base, the second one located... 相似文献
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Abdul Q. Ramle Asli Karakas Abdul K. M. Arof Mustafa Karakaya Mehmet Taser Aysun Gozutok Chee Chin Fei Nurhidayatullaili M. Julkapli Wan J. Basirun 《Journal of heterocyclic chemistry》2020,57(10):3566-3573
Two new macrocyclic dibenzotetraaza[14]annulene (DBTAA) compounds with indolenine ( 5 ) and pyridoindolenine ( 6 ) moieties were synthesized and characterized by spectroscopy. Both DBTAAs exhibit strong UV-Vis absorption properties in the Soret band region. The theoretical second-order nonlinear optical property, electric dipole moment (μ), dispersion-free dipole polarizability (α) and first hyper-polarizability values were calculated by density functional theory and time dependent density functional theory. The ab-initio quantum mechanical calculation by time-dependent Hartree-Fock method was utilized to investigate the dynamic dipole polarizabilities, dynamic second-order, static, and dynamic third-order (γ) hyper-polarizabilities of the DBTAAs. The configuration interaction technique of all doubly occupied molecular orbitals possesses theoretically defined single-photon absorption (OPA) specifications for the examined structures. The computed maximum OPA wavelengths on both macrocyclic compounds coincide with the preceding measurement outcomes. 相似文献
994.
Shariq Ali Norah Albekairi Xiao-Ming Wang Svetlana Patrikeeva Tatiana N. Nanovskaya Mahmoud S. Ahmed 《液相色谱法及相关技术杂志》2018,41(5):232-238
Ex vivo placental perfusion experiments are important in understanding the quantity and mechanisms of xenobiotic transport to the fetus during pregnancy. Our study demonstrates that paclitaxel and antipyrine concentrations in placental perfusion medium containing physiological concentrations of human serum albumin during pregnancy (30?mg/mL) can be quantified by RP-HPLC and UV detection. A liquid-liquid extraction method was developed for the quantification of paclitaxel and celecoxib (internal standard) from perfusion medium. Antipyrine, which is a necessary marker in placental perfusions for determining the validity of experiments and calculating the clearance index of xenobiotics, was also analyzed by HPLC and UV detection. Antipyrine concentrations were determined by HPLC after precipitating the perfusion medium in acetonitrile and separating the precipitated proteins by centrifugation. Concentrations were fitted to linear regressions with R2 values approaching 1. Lower limits of detection for paclitaxel and antipyrine were 100?ng/mL and 200?ng/mL, respectively. Both methods demonstrated high intra-day and inter-day precision and trueness. Additionally, the use of these methods was demonstrated in a placental perfusion experiment using Taxol® (paclitaxel dissolved in Cremophor-EL). The fetal transfer rate of Taxol was 6.6% after 1 hour. 相似文献
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Cover Picture: Water Repellency in Hydrophobic Nanocapsules—Molecular View on Dewetting (Chem. Eur. J. 22/2014)
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998.
Ahmed Ashour Yhiya Amen Toshinori Nakagawa Yasuharu Niwa Amira Mira Koichiro Ohnuki 《Natural product research》2020,34(12):1750-1755
AbstractAn aliphatic ester of hydroxysalicylic acid (6), reported for the first time from a natural source in addition to five known compounds were isolated from the fermented Carica papaya L. preparation, a commercialized functional food. The known compounds were identified as 5-hydroxymethylfurfuraldehyde (1), trans-caffeic acid (2), butyl 4-hydroxybenzoate (butylparaben) (3), lycopene (4), benzyl isothiocyanate (5). Compounds 1 and 3 were reported for the first time from Papaya fruits through this study. The new compound showed a moderate antioxidant activity and a potent hair growth stimulating activity in vitro. 相似文献
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Dr. Andrew Ballard Dr. Stefania Narduolo Dr. Hiwa O. Ahmed Nathaniel I. Keymer Dr. Nabil Asaad Dr. David A. Cosgrove Dr. Niklaas J. Buurma Dr. Andrew G. Leach 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(17):3661-3687
The two enantiomers of a compound often have profoundly different biological properties and thus their liability to racemisation in aqueous solutions is an important piece of information. The authors reviewed the available data concerning the process of racemisation in vivo, in the presence of biological molecules (e.g., racemase enzymes, serum albumin, cofactors and derivatives) and under purely chemical but aqueous conditions (acid, base and other aqueous systems). Mechanistic studies are described critically in light of reported kinetic data. The types of experimental measurement that can be used to effectively determine rate constants of racemisation in various conditions are discussed and the data they provide is summarised. The proposed origins of enzymatic racemisation are presented and suggest ways to promote the process that are different from processes taking place in bulk water. Experimental and computational studies that provide understanding and quantitative predictions of racemisation risk are also presented. 相似文献