The yield stress fluids porosimetry method (YSM) was recently presented as a simple and non-toxic potential alternative to the extensively used mercury intrusion porosimetry (MIP). The success of YSM heavily relies on the choice of an appropriate yield stress fluid to be injected through the investigated porous medium. In previous works, xanthan gum aqueous solutions were used due to their ability to exhibit a pseudo-yield stress without substantial levels of unwanted thixotropy or viscoelasticity. Given that YSM is based on the existence of a yield stress, the accuracy of the obtained pore size distribution (PSD) crucially depends on the capacity of the injected fluid to emulate the shear rheology of a yield stress fluid. However, this capacity has still not been fully assessed in the case of xanthan gum solutions. Neither has the robustness of YSM with regard to errors in the determination of the shear-rheology parameters of the injected fluid been analysed. The shear viscosity of polymer solutions is known to be deeply influenced by polymer concentration. For these reasons, a first objective of this work is to evaluate the effect of polymer concentration on the accuracy of PSDs obtained by YSM when using xanthan gum solutions as injected fluids in laboratory experiments. To do so, xanthan gum solutions with different polymer concentrations were injected through analogous samples of a sintered silicate and the obtained PSDs were compared to the results of standard MIP. Moreover, the sensitivity of YSM to errors in the experimental determination of the shear-rheology parameters was also investigated through numerical experiments. The results of the present work permitted to gain further insight into the viability of YSM as an efficient alternative to MIP. 相似文献
We study the influence of the type of loading on the asymptotic behavior of linearly elastic, isotropic and homogeneous slender circular rings. By using formal asymptotic expansions, we obtain three families of models depending on the properties of the loads. If the loads expend work in inextensional displacements, then we find the classical model where the leading term of the energy corresponds to the bending-torsion energy of inextensional displacements. If the loads do no work in inextensional displacements, the model must be refined and we obtain two other types of models. In these other models, which depend on the type of loading, the leading term of the energy contains additional terms such as, for the second class, an extension energy due to the circumferential stretching of the ring, and even, for the third class, specific load-dependent contributions. This classification is illustrated in several examples. 相似文献
We study compact toric strict locally conformally Kähler manifolds. We show that the Kodaira dimension of the underlying complex manifold is \(-\infty \), and that the only compact complex surfaces admitting toric strict locally conformally Kähler metrics are the diagonal Hopf surfaces. We also show that every toric Vaisman manifold has lcK rank 1 and is isomorphic to the mapping torus of an automorphism of a toric compact Sasakian manifold. 相似文献
We study the composition operator \(T_f(g):= f\circ g\) on Besov spaces \(B_{{p},{q}}^{s}(\mathbb{R })\). In case \(1 < p< +\infty ,\, 0< q \le +\infty \) and \(s>1+ (1/p)\), we will prove that the operator \(T_f\) maps \(B_{{p},{q}}^{s}(\mathbb{R })\) to itself if, and only if, \(f(0)=0\) and \(f\) belongs locally to \(B_{{p},{q}}^{s}(\mathbb{R })\). For the case \(p=q\), i.e., in case of Slobodeckij spaces, we can extend our results from the real line to \(\mathbb{R }^n\). 相似文献
We study unmixed and Cohen-Macaulay properties of the binomial edge ideal of some classes of graphs. We compute the depth of the binomial edge ideal of a generalized block graph. We also characterize all generalized block graphs whose binomial edge ideals are Cohen–Macaulay and unmixed. So that we generalize the results of Ene, Herzog, and Hibi on block graphs. Moreover, we study unmixedness and Cohen–Macaulayness of the binomial edge ideal of some graph products such as the join and corona of two graphs with respect to the original graphs. 相似文献
Samples of Co–Ni double substituted bismuth vanadate, BICO0.20?xNIxVOX (Bi4Co0.20???x(III)Nix(II)V1.8O10.8???(x/2)???δ;0?≤?x?≤?0.20) were synthesized by standard solid state reactions. The influence of Ni substitution for Co on phase stabilization and oxide-ion performance have been investigated using X-ray powder diffraction, differential thermal analysis, and AC impedance spectroscopy. The high conducting γ′-phase was effectively stabilized at room temperature for compositions with x?≥?0.13 whose thermal stability increases with Ni content. The complex plane plots of impedance were typically represented at temperatures below 380 °C, suggesting a major contribution of polycrystalline grains to the overall electrical conductivity. The dielectric permittivity measurements revealed the fact that suppression of the ferroelectric transition is compositionally dependent. Interestingly, the maximum ionic conductivity at lower temperatures (~2.56?×?10?4 S cm?1 at 300 °C) was observed for the composition with x?=?0.13. However, a good agreement was generally found between the values of electrical conductivity and corresponding activation energies of conduction. 相似文献
We have used the real-space Migdal-Kadanoff renormalization group technique on d-dimensional hypercubic lattice to study the mixed spin-1/2 and spin-2 Blume-Capel model. First, we indicate a critical dimension dC ≈?2.05, above and below which different topologies of phase diagrams occur. The phase diagrams have been plotted in the (crystal field, temperature) plane around dC, in which there is a second-order phase transition. Moreover, using the variation of the free energy at low temperatures, we have established the ground-state phase diagrams in the (?/J, C/J) plane for d?<?dC and d?≥?dC. In particular, we have seen the appearance of two first-order transitions at very low temperatures by the use of the free energy and its isotherm derivative. A detailed analysis of fixed points and flow diagrams indicates that there is no tricritical point.