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51.
James T. Brewster II Apolonio Aguilar Gonzalo Anguera Hadiqa Zafar Matthew D. Moore 《Journal of Coordination Chemistry》2018,71(11-13):1808-1813
AbstractThe reaction between amethyrin and non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2) under anaerobic conditions affords a bench-stable uranyl complex. UV–vis spectroscopy, cyclic voltammetry, as well as proton NMR spectroscopic analyses provide support for the conclusion that all six pyrrole subunits participate in coordination of the uranyl dication and that, upon complexation, the amethyrin-core undergoes a 2-electron oxidation to yield a formal 22 π-electron aromatic species. 相似文献
52.
53.
54.
R. Salazar Moreno F. Szidarovszky A. Rojano Aguilar I. López Cruz 《Journal of Optimization Theory and Applications》2010,144(3):557-573
A multiobjective optimization model is developed for the Mexican Valley to find optimal water distribution scenarios for three
water users: agriculture, industry and domestic. Surface, ground, treated and imported water supplies are considered. The
model with three objectives and 15 constraints was solved by the distance based method with distance l
1.
Three scenarios and two priorities were analyzed for this problem. In Scenario 1, actual aquifer overexploitation and treated
water usage were allowed. Scenario 2 considered the reduction of water extraction from the aquifer to one billion m3 (59%), and increased usage of treated water in agriculture by 50%. In Scenario 3, we assume aquifer sustainability and increasing
surface water usage by 857 mill m3/year. The last scenario is the best because, in the worst case, the farmers can cover one season and also some crops in the
second season, and the domestic users can get more water than their minimum demand. In addition, aquifer sustainability is
implemented, which can reduce aquifer overexploitation. The waste water disposal problem, which is critical in this area,
also can be reduced. 相似文献
55.
Cristian Carrera‐Figueiras Manuel Aguilar‐Vega 《Journal of Polymer Science.Polymer Physics》2005,43(19):2625-2638
The synthesis, thermal, and gas transport properties of poly(hexafluoroisopropylidene isophthalamide), HFA/ISO homopolymer, and HFA/TERT‐co‐HFA/ISO copolyamides with different poly(hexafluoroisopropilydene‐5‐t‐butylisophthalamide), HFA/TERT, ratios are reported. The results indicate that the glass transition temperatures of the copolyamides increase as the concentration of HFA/TERT in the polyamide increases. The gas permeability coefficients in the polyamides and copolyamides are independent of pressure or decrease slightly particularly with CO2, N2, and CH4. It was seen that HFA/TERT is 2–6 times more permeable than HFA/ISO, depending on the gas being considered. This was assigned to the presence of the bulky lateral substituent, t‐butyl group in HFA/TERT and HFA/TERT‐co‐HFA/ISO copolyamides. This substituent increases fractional free‐volume, as expected. Therefore, the gas permeability and diffusion coefficients generally increase with increasing fractional free‐volume. The experimental results for the gas permeability and permselectivity for the copolyamides was well represented by a logarithmic mixing rule of the homopolyamides permeability coefficients and their volume fraction. The selectivity of gas pairs, such as O2/N2, CO2/CH4, and N2/CH4 decreased slightly with the addition of HFA/TERT. The temperature dependence of permeability for homopolyamides and copolyamides can be described by an Arrhenius type equation. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2625–2638, 2005 相似文献
56.
Antonio F. Aguilera-Carbo Christopher Augur Lilia A. Prado-Barragan Cristóbal N. Aguilar Ernesto Favela-Torres 《Chemical Papers》2008,62(4):440-444
Ellagic acid (EA) was quantified by reversed-phase high-performance liquid chromatography (RPHPLC) coupled with photodiode
array detection (DAD) in five fine-powdered plants collected from the semiarid region of Mexico. Samples analysed included
Jatropha dioica branches (Dragon’s blood), Euphorbia antisyphyllitica branches (Candelilla), Turnera diffusa Willd leaves (Damiana), Flourensia cernua leaves (hojasén) and Punica granatum husk (pomegranate) at two maturity stages (“turning” or intermediate and maturated fruit, considered as positive controls).
The results demonstrated high EA concentrations in all tested samples which are novel sources of this natural antioxidant.
The method developed for the EA analysis is fast and it showed an excellent linearity range, repeatability, intra-and inter-day
precision and accuracy with respect to the methods reported for the EA analysis. 相似文献
57.
Eduardo Rodríguez de San Miguel Anel V. Garduño-García María E. Núñez-Gaytán Julio C. Aguilar Josefina de Gyves 《Journal of membrane science》2008
An organic–inorganic hybrid membrane was synthesized and evaluated for gold(III) transport from concentrated hydrochloric acid medium. The membrane was prepared by crosslinking of hydroxy terminated poly(dimethylsiloxane) with (3-aminopropyl) triethoxysilane in the presence of the commercial extractant Kelex 100. An optimization of the transport conditions was performed and selectivity with respect to copper(II) and zinc(II) determined. Around 70% of Au(III) was transported from an initially 10 ppm aqueous solution under optimized conditions with high selectivity towards 50 ppm of Cu(II) or 100 ppm of Zn(II) in 6 h. In addition the membrane extraction equilibrium reaction and its corresponding extraction equilibrium constant were evaluated and compared to those obtained in liquid–liquid solvent extraction. Membrane characterization was attained by ATR-FTIR spectroscopy. 相似文献
58.
A. Frei Yu. Sobolev I. Altarev K. Eberhardt A. Gschrey E. Gutsmiedl R. Hackl G. Hampel F. J. Hartmann W. Heil J. V. Kratz Th. Lauer A. Liźon Aguilar A. R. Müller S. Paul Yu. Pokotilovski W. Schmid L. Tassini D. Tortorella N. Trautmann U. Trinks N. Wiehl 《The European Physical Journal A - Hadrons and Nuclei》2007,34(2):119-127
The production rates of ultracold neutrons (UCN) with a solid deuterium converter have been measured at the pulsed reactor
TRIGA Mainz. Exposed to a thermal neutron fluence of
n·cm^-2·pulse^-1, the number of detected very cold and ultracold neutrons ranges up to 200 000 at 7mol of solid deuterium
(sD2) in combination with a pre-moderator (mesitylene). About 50% of the measured neutrons can be assigned to UCN with energies
E of
where V
F(sD
2) = 105 neV and V
F(guide) = 190 neV are the Fermi potentials of the sD2 converter and our stainless steel neutron guides, respectively. Thermal cycling of solid deuterium, which was frozen out
from the gas phase, considerably improved the UCN yield, in particular at higher amounts of sD2. 相似文献
59.
Maria Jesus Jimnez‐Come Ignacio J. Turias Juan Jesus Ruiz‐Aguilar Francisco J. Trujillo 《Journal of Chemometrics》2014,28(3):181-191
The breakdown potential is a crucial factor in the study of pitting corrosion resistance of stainless steel. This work aims to demonstrate the advantage of different chemometric techniques to estimate the breakdown potential of austenitic stainless steel. In order to predict pitting corrosion behaviour of stainless steel, a total of 60 samples of this alloy were subjected to electrochemical tests varying chloride ion concentration, pH and temperature. The experimental values of the breakdown potential, in addition to the tested environmental factors, were used to construct the predictive models based on support vector machines and artificial neural networks. A multiple‐comparison study based on statistic tests was applied to determine the optimal configuration for each technique. According to the results, support vector machines became a suitable and reliable technique to be applied in the modelling of the breakdown potential of austenitic stainless steels. This technique outperformed the models based on artificial neural networks and provided a useful tool to compare the pitting corrosion resistance of stainless steel in different environmental conditions without recourse to polarization tests. Therefore, this model presented a relevant meaning in science and engineering applications. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
60.
Zhai J Waddington L Wooster TJ Aguilar MI Boyd BJ 《Langmuir : the ACS journal of surfaces and colloids》2011,27(24):14757-14766
Lipid liquid crystalline nanoparticles such as cubosomes and hexosomes have unique internal nanostructures that have shown great potential in drug and nutrient delivery applications. The triblock copolymer, Pluronic F127, is usually employed as a steric stabilizer in dispersions of lipid nanostructured particles. In this study, we investigated the formation, colloidal stability and internal nanostructure and morphology of glyceryl monooleate (GMO) and phytantriol (PHYT) cubosome dispersions on substituting β-casein with F127 in increasing proportion as the stabilizer. Internal structure and particle morphology were evaluated using small-angle X-ray scattering (SAXS) and cryo-transmission electron microscopy (cryo-TEM), while protein secondary structure was studied using synchrotron radiation circular dichroism (SRCD). The GMO cubosome dispersion stabilized by β-casein alone displayed a V(2) (Pn3m) phase structure and a V(2) to H(2) phase transition at 60 °C. In comparison, F127-stabilized GMO dispersion had a V(2) (Im3m) phase structure and the H(2) phase only appeared at higher temperature, that is, 70 °C. In the case of PHYT dispersions, only the V(2) (Pn3m) phase structure was observed irrespective of the type and concentration of stabilizers. However, β-casein-stabilized PHYT dispersion displayed a V(2) to H(2) to L(2) transition behavior upon heating, whereas F127-stabilized PHYT dispersion displayed only a direct V(2) to L(2) transition. The protein secondary structure was not disturbed by interaction with GMO or PHYT cubosomes. The results demonstrate that β-casein provides steric stabilization to dispersions of lipid nanostructured particles and avoids the transition to Im3m structure in GMO cubosomes, but also favors the formation of the H(2) phase, which has implications in drug formulation and delivery applications. 相似文献