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51.
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The complex product of (non-empty) subalgebras of a given algebra from a variety \(\mathcal{V}\) is again a subalgebra if and only if the variety \(\mathcal{V}\) has the so-called generalized entropic property. This paper is devoted to algebras with a neutral element or with a semigroup operation. We investigate relationships between the generalized entropic property and the commutativity of the fundamental operations of the algebra. In particular, we characterize the algebras with a neutral element that have the generalized entropic property. Furthermore, we show that, similarly as for n-monoids and n-groups, for inverse semigroups, the generalized entropic property is equivalent to commutativity. 相似文献
53.
Phenanthriporphyrin: An Antiaromatic Aceneporphyrinoid as a Ligand for a Hypervalent Organophosphorus(V) Moiety 下载免费PDF全文
Dr. Bartosz Szyszko Dr. Agata Białońska Dr. Ludmiła Szterenberg Prof. Dr. Lechosław Latos‐Grażyński 《Angewandte Chemie (International ed. in English)》2015,54(16):4932-4936
The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative. 相似文献
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55.
Agata Krakowska Witold Reczyński Włodzimierz Opoka Waldemar Turski 《International journal of environmental analytical chemistry》2015,95(9):855-866
Honey is a sweet product made by bees using nectar from flowers. Concentrations of Ca, K, Mg, Fe, Zn, Mn, Cu, Pb and Cd were determined in 13 honey samples from the selected regions around the world. Levels of Ca, Mg, Cu, Fe, Zn and Mn were measured using flame atomic absorption spectrometry (FAAS). Potassium concentration was determined via flame photometry. Concentrations of Cd and Pb were determined using the electrothermal technique (ETAAS). It was estimated that the examined samples of honey from Greece, Turkey, Spain, Poland, Mexico, Argentina and Italy were of good quality in terms of metal concentrations (compliant with the norms referring to food products – WHO, Fifty-third Report of the joint FAO/WHO Expert Committee on Food Additives; Technical Report Series 776, Geneva), although the analysed samples were not free of heavy metals. The concentrations of the elements in the honey samples ranged from 2.38 to 9.31 μg · g?1 for Zn, from 3.86 to 35.10 μg · g?1 for Fe, from 0.19 to 21.64 μg · g?1 for Mn, from 49.53 to 1006.90 μg · g?1 for Ca, from 388.25 to 4761.50 μg · g?1 for K and from 0.20 to 1.53 μg · g?1 for Cu and regarding heavy metals from 0.11 to 2.78 μg · g?1 for Pb and from 0.02 to 0.44 μg · g?1 for Cd. According to these results it was found that the concentrations of heavy metals in the honey samples (except for alfalfa honey and eucalyptus honey from Italy) were under the acceptable limits for foods set out by the FAO/WHO. It was confirmed that the application of chemometric tools supports the extraction of significant information from analytical data, even though the availability of samples is not fully sufficient (this problem is often encountered in environmental analyses). 相似文献
56.
Alina Sionkowska Sławomir Skrzyński Krzysztof Śmiechowski Agata Kołodziejczak 《先进技术聚合物》2017,28(1):4-9
This review reports recent advances in the versatile application of collagen. Collagen materials have attracted great attention because they exhibit properties required in cosmetic preparations, in the biomedical field, and in the tanning industry leading to leather production. Herein, the structure and application of collagen are discussed in general, and detailed examples are also drawn from scientific literature and practical work. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
57.
Agata Górska Karolina Szulc Ewa Ostrowska-Ligęza Joanna Bryś Magdalena Wirkowska-Wojdyła 《Journal of Thermal Analysis and Calorimetry》2017,128(1):177-183
Epoxy-based nanocomposites containing different concentrations (0–3%) of surface-modified graphene nanosheets (GNS) with 3-aminopropyltriethoxysilane were prepared and their thermal and mechanical properties including dynamic mechanical analysis, tensile strength, hardness, and abrasion tests were evaluated in order to have a database for thermo-mechanical properties of epoxy nanocomposites. The main aim of this study was to understand the optimum percentage of GNS which would perform the best reinforcing influence on mechanical and physical performance of an epoxy nanocomposite. The results explain how applying the analysis of variance (ANOVA) method as a useful tool in optimization of GNS concentration in preparation of high-performance epoxy-based nanocomposites. 相似文献
58.
Agata Smoktunowicz 《Israel Journal of Mathematics》2017,219(2):555-608
A well-known theorem by S. A. Amitsur shows that the Jacobson radical of the polynomial ring R[x] equals I[x] for some nil ideal I of R. In this paper, however, we show that this is not the case for differential polynomial rings, by proving that there is a ring R which is not nil and a derivation D on R such that the differential polynomial ring R[x;D] is Jacobson radical. We also show that, on the other hand, the Amitsur theorem holds for a differential polynomial ring R[x;D], provided that D is a locally nilpotent derivation and R is an algebra over a field of characteristic p > 0. The main idea of the proof introduces a new way of embedding differential polynomial rings into bigger rings, which we name platinum rings, plus a key part of the proof involves the solution of matrix theory-based problems. 相似文献
59.
PMB ethers of alcohols are obtained in good yields and under mild conditions using the 4-methoxybenzyl N-allyl thiocarbamate and N-bromosuccinimide (NBS)/TfOH as the catalyst. The present method is very fast, simple, and efficient. 相似文献
60.
Renata ?yszczek Zofia Rz?czyńskaAlina Kula Agnieszka G?adysz-P?aska 《Journal of Analytical and Applied Pyrolysis》2011,92(2):347-354
The lanthanide 2,6-naphthalenedicarboxylates series of the formulas Ln2(ndc)3·nH2O, where Ln = lanthanides from La(III) to Lu(III); ndc - C10H6(COO)22−; n = 4, 4.5 or 5 have been prepared by the precipitation method. All obtained products were examined and characterized by elemental analysis, FTIR spectroscopy, simultaneous thermal analyses TG-DSC and TG-FTIR, X-Ray diffraction patterns as well as luminescence measurements. The crystalline compounds form three isostructural groups: Ce-Sm; La and Eu-Dy; Ho-Lu. In all complexes, the ndc2− ligand appears in the deprotonated form. Heating of the complexes resulted in the multi-steps decomposition process. The dehydration process leads to the formation of stable crystalline Ln2ndc3 compounds which further decompose to the corresponding lanthanide oxides (air atmosphere). In argon atmosphere they decompose with releasing of water, carbon oxides and naphthalene molecules. The luminescence properties of Eu(III), Nd(III), Tb(III) and Er(III) complexes were investigated. The complexes of Eu(III) and Tb(III) emitted red and green light when excited by ultraviolet light whereas Nd(III) and Er(III) display emissions in the NIR region. 相似文献