全文获取类型
收费全文 | 765篇 |
免费 | 25篇 |
国内免费 | 2篇 |
专业分类
化学 | 567篇 |
晶体学 | 4篇 |
力学 | 9篇 |
数学 | 79篇 |
物理学 | 133篇 |
出版年
2023年 | 5篇 |
2022年 | 53篇 |
2021年 | 58篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 14篇 |
2017年 | 20篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 45篇 |
2013年 | 47篇 |
2012年 | 49篇 |
2011年 | 49篇 |
2010年 | 51篇 |
2009年 | 34篇 |
2008年 | 40篇 |
2007年 | 41篇 |
2006年 | 35篇 |
2005年 | 35篇 |
2004年 | 17篇 |
2003年 | 11篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 6篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有792条查询结果,搜索用时 46 毫秒
61.
P. Kowalczyk Z. Klusek W. Kozlowski P. Byszewski W. Olejniczak 《Applied Physics A: Materials Science & Processing》2007,87(1):37-40
In this paper we present scanning tunneling microscopy/spectroscopy investigations of multiwall carbon nanotube junctions.
We concentrated on bent and narrowing junctions, which my be formed by introducing pentagon–heptagon defects into a hexagonal
network of a carbon nanotube. It was expected that the defects introduced to the nanotube could cause changes in the local
density of states. The scanning tunneling spectroscopy results were used to search for and identify these defects. We also
discuss a hypothesis for a combination of a telescope junction and a pentagon–heptagon induced junction.
PACS 68.37.Ef; 73.22.–f; 61.46.Fg; 71.20.Tx 相似文献
62.
While typically cyclodehydration of thiosemicarbazides in acidic media leads to 1,3,4‐thiadiazoles, we have recently shown that under reflux conditions in anhydrous acetic acid the cyclization yields an imidazolidine derivative. The mechanism of this reaction has been characterized theoretically. Calculations indicate that this direction, facilitated by the presence of the ? CH2CO2? moiety in the N4 substituent is favored over the direction leading toward the thiadiazole product. Formation of the C? N bond that closes the five‐member ring appears to be concerted with the departure of ethanol molecule, although the proton transfer from the nitrogen atom to oxygen atom is much more advanced in the transition state. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
63.
Z. Klusek A. Busiakiewicz R. Schmidt P. Kowalczyk W. Olejniczak 《Surface science》2007,601(6):1513-1520
High-temperature scanning tunnelling microscopy, scanning tunnelling spectroscopy and current imaging tunnelling spectroscopy (HT-STM/STS/CITS) were used to study the topographic and electronic structures changes due to surface modifications of the TiO2(1 1 0) surface caused by the STM tip. In situ high-temperature STM results showed that the created modifications were stable even at elevated temperatures. The STS/CITS results showed the presence of energy gap below the Fermi level on the untreated regions. The disappearance of energy gap below the Fermi level on the modifications created by the tip was observed. It is assumed that the presence of the tip can change the chemical stoichiometry of the surface from TiO2−x towards Ti2O3. 相似文献
64.
The aim of the study was to assess the antioxidant potential of goat’s milk and whey from goat’s milk fermented with selected bacteria strains from kefir grain (L. plantarum, L. fermentum, L. rhamnosus and L. acidophilus) with regard to fermented cow’s milk with the same bacteria strains. The assessment of antioxidant potential was made by ABTS, DPPH, TPC and FRAP methods. The work also assessed metabolic activity of tested lactic acid bacteria using measurement of electrical impedance changes in the growing medium. The highest values describing the antioxidant potential were found for fermented milk by L. acidophilus. It was also found that the time of cooling storage causes significantly increasing the antioxidant potential of most analyzed samples. Metabolic activity of tested lactic acid bacteria was the highest for cow’s milk. The course of curves for goat’s milk and whey from goat’s milk was similar, which confirms the differences between cow and goat milk. 相似文献
65.
Agata Biaoska Zbigniew Ciunik 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(12):o853-o855
The crystal structures of brucine (2,3‐dimethoxystrychnidin‐10‐one), C23H26N2O4, brucine acetone solvate, C23H26N2O4·C3H6O, and brucine 2‐propanol solvate dihydrate, C23H26N2O4·C3H7O·2H2O, have been determined. Crystals of brucine and its 2‐propanol solvate dihydrate exhibit similar monolayer sheet packing, whereas crystals of the acetone solvate adopt a different mode of packing, as brucine pillars. The solvent appears to control the brucine self‐assembly on the basis of common donor–acceptor properties of the surfaces. 相似文献
66.
67.
We consider a subclass of the class of close-to-convex functions. We show the relationship between our class and the appropriate subordination. Moreover, we give the coefficient estimates and a sufficient condition for functions to belong to the class investigated. Finally, we obtain the distortion and the growth theorems. The results presented are a generalization of the results obtained by Gao and Zhou. 相似文献
68.
This paper describes a new approach to the problem of computing spherical expansions of zonal functions on Euclidean spheres.
We derive an explicit formula for the coefficients of the expansion expressing them in terms of the Taylor coefficients of
the profile function rather than (as done usually) in terms of its integrals against Gegenbauer polynomials. Our proof of
this result is based on a polynomial identity equivalent to the canonical decomposition of homogeneous polynomials and uses
only basic properties of this decomposition together with simple facts concerning zonal harmonic polynomials. As corollaries,
we obtain direct and apparently new derivations of the so-called plane wave expansion and of the expansion of the Poisson
kernel for the unit ball.
Received: 26 January 2007 相似文献
69.
Metal(II) Ion Complexes with 5‐(Pyrazin‐2‐yl)‐2,4‐dihydro‐3H‐1,2,4‐triazole‐3‐thione; Synthesis,Structural Characterization,Acid‐base,and Complexing Properties in Solution
下载免费PDF全文
![点击此处可从《无机化学与普通化学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Aleksander Kufelnicki Jolanta Jaciubek‐Rosińska Marta Sobiesiak Agata Paneth Julia Jezierska Elzbieta Budzisz 《无机化学与普通化学杂志》2017,643(16):1067-1074
The study reports the synthesis of complexes Co(HL)Cl2 ( 1 ), Ni(HL)Cl2 ( 2 ), Cu(HL)Cl2 ( 3 ), and Zn(HL)3Cl2 ( 4 ) with the title ligand, 5‐(pyrazin‐2‐yl)‐1,2,4‐triazole‐5‐thione (HL), and their characterization by elemental analyses, ESI‐MS (m/z), FT‐IR and UV/Vis spectroscopy, as well as EPR in the case of the CuII complex. The comparative analysis of IR spectra of the metal ion complexes with HL and HL alone indicated that the metal ions in 1 , 2 , and 3 are chelated by two nitrogen atoms, N(4) of pyrazine and N(5) of triazole in the thiol tautomeric form, whereas the ZnII ion in 4 is coordinated by the non‐protonated N(2) nitrogen atom of triazole in the thione form. pH potentiometry and UV/Vis spectroscopy were used to examine CoII, NiII, and ZnII complexes in 10/90 (v/v) DMSO/water solution, whereas the CuII complex was examined in 40/60 (v/v) DMSO/water solution. Monodeprotonation of the thione triazole in solution enables the formation of the L:M = 1:1 species with CoII, NiII and ZnII, the 2:1 species with CoII and ZnII, and the 3:1 species with ZnII. A distorted tetrahedral arrangement of the CuII complex was suggested on the basis of EPR and Vis/NIR spectra. 相似文献
70.
The objective of this paper is to provide information about application of solid-phase extraction (SPE) for isolation of nine high-intensity sweeteners (acesulfame-K, alitame, aspartame, cyclamate, dulcin, neotame, saccharin, sucralose and neohesperidin dihydrochalcone) from aqueous solutions. The influence of several types of LC-MS compatible buffers (different pH values and compositions) on their recovery has been studied and discussed. A number of commercially available SPE cartridges, such as Chromabond C18ec, Strata-X RP, Bakerbond Octadecyl, Bakerbond SDB-1, Bakerbond SPE Phenyl, Oasis HLB, LiChrolut RP-18, Supelclean LC-18, Discovery DSC-18 and Zorbax C18 were tested in order to evaluate their applicability for the isolation of analytes. Very high recoveries (better than 92%) of all studied compounds were obtained using formic acid-N,N-diisopropylethylamine buffer adjusted to pH 4.5 and C18-bonded silica sorbents. Behaviour of polymeric sorbents strongly depends on their structure. Strata-X RP behaves much like a C18-bonded silica sorbent. Recoveries obtained using Oasis HLB were comparable with those observed for silica-based sorbents. The only compound less efficiently (83%) retained by this sorbent was cyclamate. Bakerbond SDB-1 shows unusual selectivity towards aspartame and alitame. Recoveries of these two sweeteners were very low (26 and 42%, respectively). It was also found that aspartame and alitame can be selectively separated from the mixture of sweeteners using formic acid-triethylamine buffer at pH 3.5. 相似文献